Citation: ZHOU Yong-Hui, LI Jun, WANG Zheng-Mei, WANG Cheng-Cheng, LI Tian-Yi, ZHANG Song, YU Ming-Bo, SUN Peng, WANG Li-Li, ZHENG You-Xuan. Synthesis and Photoluminescence Properties of Europium(Ⅲ) Complexes Based on 2, 2′:6′, 2″-Terpyridine Derivatives with Hole Transport Moieties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 701-708. doi: 10.3969/j.issn.1001-4861.2013.00.135 shu

Synthesis and Photoluminescence Properties of Europium(Ⅲ) Complexes Based on 2, 2′:6′, 2″-Terpyridine Derivatives with Hole Transport Moieties

1.
1 Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, College of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China;

Received Date: 19 October 2012
Available Online: 12 December 2012
Fund Project: 国家自然科学基金面上项目(20971067) (20971067) 南京信息工程大学基金预研项目(S8111107001) (S8111107001)南京信息工程大学教改提升工程-大学生创新训练项目(N1885012158)资助项目。 (N1885012158)

Based on 2, 2′:6′, 2″-terpyridine (L1), five N,N,N-tridentate ligands, namely 4′-carbazol-9-yl-2,2′:6′,2″-terpyridine (L2), 4′-diphenylamino-2,2′:6′,2″-terpyridine (L3), 4′-bis(4-tert-butylphenyl)-amino-2,2′:6′,2″-terpyridine (L4), 4′-(1-naphthalenyl-N-phenyl)amino-2,2′:6′,2″-terpyridine (L5), 4′-(2-naphthalenyl-N-phenyl)amino-2,2′:6′,2″-terpyridine (L6), have been successfully synthesized. Employing 2-thenoyltrifluoroacetone (HTTA) and L1-L6 as the sensitizing ligands, a series of europium (Ⅲ) complexes (Eu(TTA)₃L1-Eu(TTA)₃L6) have been obtained. All the europium (Ⅲ) complexes show red characteristic emission of Eu(Ⅲ) ⁵D₀-⁷F_J(J=0,1,2,3,4). The introduction of hole transport moieties improves the UV-Vis absorption and luminescence intensities of the europium(Ⅲ) complexes, and the carbazole containing complex Eu(TTA)₃L₂ exhibits the highest intensity and longest lifetime.
- europium complex;hole transport moiety;luminescence, lifetime
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