Citation: HU Wei-Ji, WU Xiao-Yong, LIU Jian-Feng, ZHAO Guo-Liang. Synthesis, Crystal Structure and Biological Activity of Lanthanum(Ⅲ) Coordination Polymer Constructed with p-Hydroxyphenylacetic Acid Anion[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 861-866. doi: 10.3969/j.issn.1001-4861.2013.00.134 shu

Synthesis, Crystal Structure and Biological Activity of Lanthanum(Ⅲ) Coordination Polymer Constructed with p-Hydroxyphenylacetic Acid Anion

1.
1 Zhejiang Normal University Xingzhi College, Jinhua, Zhejiang 321004, China;

Received Date: 8 September 2012
Available Online: 22 November 2012
Fund Project: 浙江省自然科学基金(No.Y4080256)资助项目。 (No.Y4080256)

A coordination polymer of {[La(HPAA)₃(H₂O)₂]·2(bipy)·H₂O}_n (1) (HHPAA=p-hydroxyphenylacetic acid, bipy=4,4′-bipyridine) was synthesized and characterized by elemental analysis, IR and TG-DTG. Its crystal structure was determined by single crystal X-ray diffraction method. The complex crystallizes in triclinic with space group P1, cell parameters: a=0.910 52(2) nm, b=1.284 78(3) nm, c=1.958 69(4) nm, α=78.586 0(1)°, β=76.656 0(1)°, γ=73.097 0(1)°, cell volume: V=2.111 98(8) nm³, number of molecules inside the cell: Z=2, relative molecular mass: M_r=958.73. The La(Ⅲ) cation is coordination with oxygen atoms from p-hydroxyphenylacetic acid anions and water molecules, forming a distorted two-capped square antiprism coordination geometry. The adjacent La(Ⅲ) clusters linked by carboxylic groups are connected by HPAA^- to form a 1D chain, and the bipyridine is uncoordinated to La(Ⅲ) center. Moreover, the interaction of complex with DNA was also studied by ethidium bromide (EB) fluorescence spectroscopy. CCDC: 900442.
- La(Ⅲ) complex;p-hydroxyphenylacetic acid;crystal structure;DNA
1. [1]
  [1] Sun X L, Wang Z J, Zang S Q, et al. Cryst. Growth Des., 2012,12(9):4431-4440
2. [2]
  [2] Bradshaw D, Prior T J, Cussen E J, et al. J. Am. Chem. Soc., 2004,126(19):6106-6114
3. [3]
  [3] Biswas R, Mukherjee S, Ghosh A, et al. Inorg. Chem., 2012, 51(15):8150-8160
4. [4]
  [4] Mukherjee G, Singh P, Butcher R J, et al. Inorg. Chem., 2012,51(15):8128-8140
5. [5]
  [5] HU Zong-Zhi(胡宗智), ZHAO Jun(赵君), LI Dong-Sheng(李东升), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:184-188
6. [6]
  [6] Kim D W, Song X K, Yoon J H, et al. Cryst. Growth Des., 2012,12(8):4186-4193
7. [7]
  [7] Li H J, Zhao B, Hou H W, et al. Cryst. Growth Des., 2012, 12(8):4170-4179
8. [8]
  [8] Hu J S, Yao X Q, Xue Z L, et al. Cryst. Growth Des., 2012, 12(7):3426-3435
9. [9]
  [9] Morris W, Cascio D, Yaghi M, et al. Inorg. Chem., 2012,51 (12):6643-6445
10. [10]
  [10] LI Rong-Qing(李荣清), ZHANG Yu(张宇), ZHAO Zhen(赵振), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(5):1025-1030
11. [11]
  [11] WANG Hui(王慧), GAN Guo-Qing(甘国庆), QU Yang(瞿阳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1217-1221
12. [12]
  [12] Hudej R, Kljun J, Turel I, et al. Organometallics, 2012,31 (16):5867-5874
13. [13]
  [13] Chen Z F, Shi Y F, Liang H, et al. Inorg. Chem., 2012,51 (4):1998-2009
14. [14]
  [14] Xue L, Li G P, Jiang H, et al. Inorg. Chem., 2011,50(8): 3680-3690
15. [15]
  [15] OU Zhi-Bin(区志镔), HUANG Shan-Hua(黄山华), LE Xue-Yi(乐学义). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(8):1580-1586
16. [16]
  [16] Sheldrick G M. SHELXS 97, Program for the Solution of Crystal Structure, University of Göttingen, Gttingen, Germany, 1997.
17. [17]
  [17] Sheldrick G M. SHELXS 97, Program for the Refinement of Crystal Structure, University of Göttingen, Gttingen, Germany, 1997.
18. [18]
  [18] Hou H W, Wei Y L, Zhu Y, et al. Inorg. Chem., 2004,43(4): 1323-1327
19. [19]
  [19] Delangle P, Husson C, Lebrun C, et al. Inorg. Chem., 2001, 40(13):2953-2962
20. [20]
  [20] Lakowicz J R, Weber G. Biochem., 1973,12(21):4161-4170
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沈阳化工大学材料科学与工程学院沈阳 110142