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Citation: SUN Zhen, GUO Jia, YU Jian-Guo, HUANG Hua, CHEN Juan, LI Guo-Dong, ZHAO Yong-Nan. Preparation and Photoluminescence Properties of Perovskite BaZr1-xAlxO3 (x=0～0.08) Hollow Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 936-940. doi: 10.3969/j.issn.1001-4861.2013.00.131 shu

Preparation and Photoluminescence Properties of Perovskite BaZr1-xAlxO3 (x=0～0.08) Hollow Microspheres

  • 1.

    1. Tianjin Key Laboratory of Fiber Modification and Functional Fiber, School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China;

  • Corresponding author: ZHAO Yong-Nan, 
  • Received Date: 7 October 2012
    Available Online: 27 November 2012

    Fund Project: 国家自然科学基金(No.21271138) (No.21271138)天津市自然科学基金(No.10JCZDJC21500) (No.10JCZDJC21500)吉林大学无机合成与制备国家重点实验室开放课题 (No.2012-20)资助项目。 (No.2012-20)

  • BaZr1-xAlxO3 (x=0～0.08) hollow microspheres with different Al contents were synthesized by hydrothermal method. The samples were characterized by XRD, SEM, TEM, PL, FTIR. XRD data indicated that Al3+ was successfully introduced into the lattice and replaced the Zr4+ cation at B position. Replacing Zr4+ by Al3+ aroused the decrease of cell parameters. TEM observations confirmed the hollow feature and gave a mean particle size of 150 nm. When excited by 355 nm laser, all of the hollow microspheres emitted 423 nm violet light at room temperature. Compared with that of pure BaZrO3, the cell shrinkage that stemmed from Al3+ doping directed to weakened photoluminescence. The non-equivalent doping also led to the variation of oxygen vacancies, which directed to a slightly enhanced photoluminescence with Al3+ doping contents in the range of 1% to 2%.
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