Citation: HU Jin-Song, LIU Xi-Hui, SHI Jian-Jun, XING Hong-Long, HE Jie. Structure and Fluorescence Property of 2D Bilayer Zn(Ⅱ) Coordination Polymer Induced by H-Bonding and π-π Interaction[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 444-448. doi: 10.3969/j.issn.1001-4861.2013.00.130 shu

Structure and Fluorescence Property of 2D Bilayer Zn(Ⅱ) Coordination Polymer Induced by H-Bonding and π-π Interaction

1.
School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China

Received Date: 5 September 2012
Available Online: 21 November 2012
Fund Project: 国家自然科学基金(No.21271008,51173002) (No.21271008,51173002)安徽理工大学博士启动和青年基金(No.11227,2012QNZ08) (No.11227,2012QNZ08)江苏省新型环保重点实验室开放课题基金(No.AE201107)资助项目。 (No.AE201107)

Solvothermal reaction of 1,3-dipyridyl benzene (1,3-dpb) with 4,4'-oxybis(benzoic acid) (H₂oba) produced a two dimensional (2D) zinc(Ⅱ) coordination polymer {[Zn(oba)(dpb)]·H₂O}_n (1). The complex was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It crystallizes in the monoclinic system, space group C2/c. The neighboring Zn(Ⅱ) ions are linked by oba^2- anions and 1,3-dpb to form infinitely 2D sheet, two 2D sheets are interlocked each other to form 2D→2D structure, and these two 2D sheets were linked each other by H-bonding. Two groups of interlocked structures further linked to form bilayer 2D supermolecule network by π-π interaction. In addition, the fluorescence property of 1 was also studied. CCDC: 917714.
- coordination polymer;H-bonding;π-π interaction;fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142