Citation: LI Jie, YAN Biao, MA Hai-Xia, HUANG Ting, SONG Ji-Rong. Synthesis, Molecular Structure and Biological Activities on Ag(Ⅰ) Complex of Tebuconazole[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 697-700. doi: 10.3969/j.issn.1001-4861.2013.00.128 shu

Synthesis, Molecular Structure and Biological Activities on Ag(Ⅰ) Complex of Tebuconazole

LI Jie ¹ ,
YAN Biao ^1,2 ,
MA Hai-Xia ¹ ,
HUANG Ting ¹ ,
SONG Ji-Rong ^1,3

1.
1 School of Chemical Engineering, Northwest University/Shanxi Key Laboratory of Physico-Inorganic Chemistry, Xi′an 710069, China;

Received Date: 9 July 2012
Available Online: 21 November 2012
Fund Project: 国家自然科学基金(No.21073141) (No.21073141)陕西省教育厅基金(No.11JK0564和11JK0582)资助项目。 (No.11JK0564和11JK0582)

The Ag(Ⅰ) complex of tebuconazole [AgL₂]NO₃(L=(RS)-1-(4-chloro-phenyl)-4,4-dimethyl-3-(1,2,4-triazole-1-ylmethyl)pentan-3-ol), tebuconazole) was synthesized and characterized by elemental analysis, IR, single crystal X-ray diffraction. The crystal is in the monoclinic system, space group C2/c, with cell parameters: a=3.698 9(7) nm, b=0.902 8(2) nm, c=1.122 8(2) nm, β=103.66(13)°, V=3.643 3(13) nm³, D_c=1.432 g·cm^-3, Z=4, F(000)=1 624, μ=0.748 mm^-1. The metal atoms are bridged by L to form coordination chains, which are linked by O-H…N hydrogen bonds to form a two-dimensional structure. The sterilization/disinfectant effect of tebuconazole and its silver complex to the Gibberella nicotiancola and Apple black fruit rot and the regulatory role to wheat growth were studied. The results show that [AgL₂]NO₃ is ineffective to the germination and growth on wheat, while it is active to inhibit Gibberella nicotiancola and Apple black fruit rot. CCDC: 917713.
- tebuconazole;silver(Ⅰ) complex;crystal structure;biological activity
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