Citation: DU Bo, HE Fu-Ming, WANG Xiao-Xiang. Synthesis and Properties of the Thorned Hydroxyapatite Rods Prepared with Electrochemical Method[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 973-978. doi: 10.3969/j.issn.1001-4861.2013.00.127 shu

Synthesis and Properties of the Thorned Hydroxyapatite Rods Prepared with Electrochemical Method

1.
1. Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China;

Corresponding author: WANG Xiao-Xiang,
Received Date: 3 November 2012
Available Online: 12 December 2012
Fund Project: 国家自然科学基金(No.50571088) (No.50571088)浙江省杰出青年科学计划(R2110374)资助项目。 (R2110374)

Thorned hydroxyapatite rods (THA) were synthesized on surface of commercially pure titanium specimens by two-step electrochemical method successively in electrolytes with lower and higher Ca²⁺ and PO₄^3- ion concentration. The microstructural analysis showed that the main rod (100～200 nm in diameter) of the THA is of HA single crystal, while the thorn (10～50 nm in diameter) consisted of HA nanocrystals. The THAs constitute uniform micro-nano porous coating on the titanium surface. The solubility and contact angle measurement showed that, compared to the bare HA rod coating, the THA coating exhibited higher releasing rate of Ca²⁺ in phosphate buffered saline (PBS) and higher wettability.
- electrochemical depositions;hydroxyapatite;coating;solubility;wettability
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