Citation: LIU Jian-Hua, MA Yu-Xiao, YU Mei, AN Jun-Wei, LI Song-Mei. Preparation and Capacitance Properties of Graphene-Polypyrrole Nanotube Hybrid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 929-935. doi: 10.3969/j.issn.1001-4861.2013.00.126 shu

Preparation and Capacitance Properties of Graphene-Polypyrrole Nanotube Hybrid

1.
School of Material Science and Engineering, Beihang University, Beijing 100191, China

Corresponding author: YU Mei,
Received Date: 29 October 2012
Available Online: 10 December 2012
Fund Project: 国家自然科学基金(No.51001007)资助项目。 (No.51001007)

A graphene-polypyrrole nanotube hybrid is fabricated by chemical hybridization method. Scanning electron microscopy, transmission electron microscopy, fourier-transmission infrared spectroscopy, X-ray photoelectron spectroscopy and electrochemical workstation are used out to characterize the morphology, structure and properties of graphene-polypyrrole nanotube hybrid. The electron microscopy images show that graphene sheets and polypyrrole nanotubes distribute well in the hybrid. The results of spectroscopy analysis confirm the existence of amide group which connects graphene and polypyrrole nanotube in the hybrid. The specific capacitance of the hybrid is 1368 F·g^-1 at a current density of 0.3 A·g^-1 as well as the specific capacitance of 759 F·g^-1 at a current density of 1.5 A·g^-1. In long-term cyclic voltammetry tests, after 1000 cycles, the preserved specific capacitance of the hybrid is 85.5% of its initial specific capacitance, demonstrating a good electrochemical stability. The Nyquist plot of the graphene-polypyrrole nanotube hybrid reveals its good pseudo-capacitance performance.
- graphene;polypyrrole nanotubes;nanomaterial;covalent connection;capacitance properties
1. [1]
  [1] Arabale G, Wagh D, Kulkarni M, et al. Chem. Phys. Lett., 2003,376(1/2):207-213
2. [2]
  [2] Fan Z, Yan J, Zhi L, et al. Adv. Mater., 2010,22(33):3723- 3728
3. [3]
  [3] SHEN Chen-Fei(沈辰飞), ZHENG Ming-Bo(郑明波), XUE Lu-Ping(薛露平), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(3):585-589
4. [4]
  [4] SI Wei-Jiang(司维江), WU Xiao-Zhong(吴小中), XING Wei (邢伟), et al. J. Inorg. Mater. (Wuji Cailiao Xuebao), 2011,26 (1):107-112
5. [5]
  [5] Biswas S, Drzal L. Nano Lett., 2008,9:167-172
6. [6]
  [6] Huang Y, Liang J, Chen Y. Small, 2012,8(12):1805-1834
7. [7]
  [7] Kanazawa K, Diaz A, Gill W, et al. Synthetic Met., 1980,1 (3):329-336
8. [8]
  [8] Biswas S, Drzal L. Chem. Mater., 2010,22(20):5667-5671
9. [9]
  [9] Zhang K, Zhang L, Zhao X, et al. Chem. Mater., 2010,22(4): 1392-1401
10. [10]
  [10] Wu Q, Xu Y, Yao Z, et al. Acs Nano 2010,4(4):1963-1970
11. [11]
  [11] Liu J, An J, Ma Y, et al. Eur. Phys. J.: Appl. Phys. 2012, 57(44)
12. [12]
  [12] JIN Li(金莉), SUN dong(孙东), ZHANG Jian-Rong(张剑荣). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6): 1084-1090
13. [13]
  [13] ZHANG Hai-Ying(张海英), HU Zhong-Ai(胡中爱), ZHANG Fu-Hai(张富海), et al. Chinese J. Appl. Chem.(Yingyong Huaxue), 2012,29(6):674-681
14. [14]
  [14] MA Yan-Wen(马延文), XIONG Chuan-Yin(熊传银), HUANG Wen(黄雯), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(3):546-550
15. [15]
  [15] Frackowiaka E, Jurewicza K, Delpeuxb S, et al. J. Power Sources, 2001,97-98:822-825
16. [16]
  [16] HAN Dan-Dan(韩丹丹), JING Xiao-Yan(景晓燕), WANG Jun(王君), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(8):1547-1554
17. [17]
  [17] LU Xiang-Jun(卢向军), DOU Hui(窦辉), YANG Su-Dong (杨苏东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(10):2333-2339
18. [18]
  [18] Liu J, An J, Zhou Y, et al. ACS Appl. Mater. Interfaces, 2012,4(6):2870-2876
19. [19]
  [19] Liu J, An J, Ma Y, et al. J. Electrochem. Soc., 2012,159(6): A828-A833
20. [20]
  [20] Yang X, Zhu Z, Dai T, et al. Macromol. Rapid Comm., 2005,26(21):1736-1740
21. [21]
  [21] Lim M, Anuar K, Mahmud H, et al. Malaysian J. Anal. Sci., 2007,11(1):133-138
22. [22]
  [22] XIE Hai-Ming(谢海明), HAN Ming-Juan(韩明娟),YU Hai- Ying(于海英), et al. Chem. J. Chinese Univ.(Gaodeng Xuexiao Huaxue Xuebao), 2007,28(1):109-112
23. [23]
  [23] GENG Li-Na(耿丽娜), WANG Shu-Rong(王淑荣), LI Peng (李鹏), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(7):977-981
24. [24]
  [24] CHEN He-Sheng(陈和生), SHAO Jing-Chang(邵景昌). Chin. Anal. Instrum.(Fenxi Yiqi), 2011(3):36-40
25. [25]
  [25] Street G, Clarke T, Geiss R, et al. J. Phys., 1983,44:599
26. [26]
  [26] REN Li(任丽), ZHANG Xue-Feng(张雪峰), WANG Li-Xin (王立新), et al. Chinese J. Semicond.(Bandaoti Xuebao), 2007,27(9):1396-1401
27. [27]
  [27] WAN Qun-Yi(万群义), FAN Shuan-Shi(樊栓狮), YUE Xian-Jun(岳羡君), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2010,26(11):2951-2956
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沈阳化工大学材料科学与工程学院沈阳 110142