Citation: LIU Jian-Hua, MA Yu-Xiao, YU Mei, AN Jun-Wei, LI Song-Mei. Preparation and Capacitance Properties of Graphene-Polypyrrole Nanotube Hybrid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 929-935. doi: 10.3969/j.issn.1001-4861.2013.00.126 shu

Preparation and Capacitance Properties of Graphene-Polypyrrole Nanotube Hybrid

1.
School of Material Science and Engineering, Beihang University, Beijing 100191, China

Corresponding author: YU Mei,
Received Date: 29 October 2012
Available Online: 10 December 2012
Fund Project: 国家自然科学基金(No.51001007)资助项目。 (No.51001007)

A graphene-polypyrrole nanotube hybrid is fabricated by chemical hybridization method. Scanning electron microscopy, transmission electron microscopy, fourier-transmission infrared spectroscopy, X-ray photoelectron spectroscopy and electrochemical workstation are used out to characterize the morphology, structure and properties of graphene-polypyrrole nanotube hybrid. The electron microscopy images show that graphene sheets and polypyrrole nanotubes distribute well in the hybrid. The results of spectroscopy analysis confirm the existence of amide group which connects graphene and polypyrrole nanotube in the hybrid. The specific capacitance of the hybrid is 1368 F·g^-1 at a current density of 0.3 A·g^-1 as well as the specific capacitance of 759 F·g^-1 at a current density of 1.5 A·g^-1. In long-term cyclic voltammetry tests, after 1000 cycles, the preserved specific capacitance of the hybrid is 85.5% of its initial specific capacitance, demonstrating a good electrochemical stability. The Nyquist plot of the graphene-polypyrrole nanotube hybrid reveals its good pseudo-capacitance performance.
- graphene;polypyrrole nanotubes;nanomaterial;covalent connection;capacitance properties
1. [1]
  [1] Arabale G, Wagh D, Kulkarni M, et al. Chem. Phys. Lett., 2003,376(1/2):207-213
2. [2]
  [2] Fan Z, Yan J, Zhi L, et al. Adv. Mater., 2010,22(33):3723- 3728
3. [3]
  [3] SHEN Chen-Fei(沈辰飞), ZHENG Ming-Bo(郑明波), XUE Lu-Ping(薛露平), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(3):585-589
4. [4]
  [4] SI Wei-Jiang(司维江), WU Xiao-Zhong(吴小中), XING Wei (邢伟), et al. J. Inorg. Mater. (Wuji Cailiao Xuebao), 2011,26 (1):107-112
5. [5]
  [5] Biswas S, Drzal L. Nano Lett., 2008,9:167-172
6. [6]
  [6] Huang Y, Liang J, Chen Y. Small, 2012,8(12):1805-1834
7. [7]
  [7] Kanazawa K, Diaz A, Gill W, et al. Synthetic Met., 1980,1 (3):329-336
8. [8]
  [8] Biswas S, Drzal L. Chem. Mater., 2010,22(20):5667-5671
9. [9]
  [9] Zhang K, Zhang L, Zhao X, et al. Chem. Mater., 2010,22(4): 1392-1401
10. [10]
  [10] Wu Q, Xu Y, Yao Z, et al. Acs Nano 2010,4(4):1963-1970
11. [11]
  [11] Liu J, An J, Ma Y, et al. Eur. Phys. J.: Appl. Phys. 2012, 57(44)
12. [12]
  [12] JIN Li(金莉), SUN dong(孙东), ZHANG Jian-Rong(张剑荣). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6): 1084-1090
13. [13]
  [13] ZHANG Hai-Ying(张海英), HU Zhong-Ai(胡中爱), ZHANG Fu-Hai(张富海), et al. Chinese J. Appl. Chem.(Yingyong Huaxue), 2012,29(6):674-681
14. [14]
  [14] MA Yan-Wen(马延文), XIONG Chuan-Yin(熊传银), HUANG Wen(黄雯), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(3):546-550
15. [15]
  [15] Frackowiaka E, Jurewicza K, Delpeuxb S, et al. J. Power Sources, 2001,97-98:822-825
16. [16]
  [16] HAN Dan-Dan(韩丹丹), JING Xiao-Yan(景晓燕), WANG Jun(王君), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(8):1547-1554
17. [17]
  [17] LU Xiang-Jun(卢向军), DOU Hui(窦辉), YANG Su-Dong (杨苏东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(10):2333-2339
18. [18]
  [18] Liu J, An J, Zhou Y, et al. ACS Appl. Mater. Interfaces, 2012,4(6):2870-2876
19. [19]
  [19] Liu J, An J, Ma Y, et al. J. Electrochem. Soc., 2012,159(6): A828-A833
20. [20]
  [20] Yang X, Zhu Z, Dai T, et al. Macromol. Rapid Comm., 2005,26(21):1736-1740
21. [21]
  [21] Lim M, Anuar K, Mahmud H, et al. Malaysian J. Anal. Sci., 2007,11(1):133-138
22. [22]
  [22] XIE Hai-Ming(谢海明), HAN Ming-Juan(韩明娟),YU Hai- Ying(于海英), et al. Chem. J. Chinese Univ.(Gaodeng Xuexiao Huaxue Xuebao), 2007,28(1):109-112
23. [23]
  [23] GENG Li-Na(耿丽娜), WANG Shu-Rong(王淑荣), LI Peng (李鹏), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(7):977-981
24. [24]
  [24] CHEN He-Sheng(陈和生), SHAO Jing-Chang(邵景昌). Chin. Anal. Instrum.(Fenxi Yiqi), 2011(3):36-40
25. [25]
  [25] Street G, Clarke T, Geiss R, et al. J. Phys., 1983,44:599
26. [26]
  [26] REN Li(任丽), ZHANG Xue-Feng(张雪峰), WANG Li-Xin (王立新), et al. Chinese J. Semicond.(Bandaoti Xuebao), 2007,27(9):1396-1401
27. [27]
  [27] WAN Qun-Yi(万群义), FAN Shuan-Shi(樊栓狮), YUE Xian-Jun(岳羡君), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2010,26(11):2951-2956
1. [1]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
2. [2]
  Zunyuan Xie , Lijin Yang , Zixiao Wan , Xiaoyu Liu , Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137
3. [3]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
4. [4]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
6. [6]
  Anbang Du , Yuanfan Wang , Zhihong Wei , Dongxu Zhang , Li Li , Weiqing Yang , Qianlu Sun , Lili Zhao , Weigao Xu , Yuxi Tian . Photothermal Microscopy of Graphene Flakes with Different Thicknesses. Acta Physico-Chimica Sinica, 2024, 40(5): 2304027-0. doi: 10.3866/PKU.WHXB202304027
7. [7]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
8. [8]
  Tao Xu , Wei Sun , Tianci Kong , Jie Zhou , Yitai Qian . Stable Graphite Interface for Potassium Ion Battery Achieving Ultralong Cycling Performance. Acta Physico-Chimica Sinica, 2024, 40(2): 2303021-0. doi: 10.3866/PKU.WHXB202303021
9. [9]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
10. [10]
  Shasha SUN , Weichun HUANG , Mengke WANG . Research progress of interface regulation strategies and applications of two‑dimensional MXenes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1465-1482. doi: 10.11862/CJIC.20240430
11. [11]
  Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V₂O₃@Pourous Carbon Nanosheets Derived from V₂CF_x MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020
12. [12]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
13. [13]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
14. [14]
  Huimin Liu , Kezhi Li , Xin Zhang , Xuemin Yin , Qiangang Fu , Hejun Li . SiC Nanomaterials and Their Derived Carbons for High-Performance Supercapacitors. Acta Physico-Chimica Sinica, 2024, 40(2): 2304026-0. doi: 10.3866/PKU.WHXB202304026
15. [15]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
16. [16]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
17. [17]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
18. [18]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
19. [19]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
20. [20]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050

Get Citation

PDF

XML

Metrics

PDF Downloads(438)
Abstract views(666)
HTML views(59)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142