Citation: JIANG Li-Hui, MA De-Yun. Synthesis, Structure and Photoluminescence of One Neodymium(Ⅲ) Coordination Polymer Based on 2,4-Dichlorophenoxyacetate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 883-888. doi: 10.3969/j.issn.1001-4861.2013.00.124 shu

Synthesis, Structure and Photoluminescence of One Neodymium(Ⅲ) Coordination Polymer Based on 2,4-Dichlorophenoxyacetate

JIANG Li-Hui ¹ ,
MA De-Yun ²

1.
1 College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;

Received Date: 3 August 2012
Available Online: 27 November 2012
Fund Project: 中南大学粉末冶金国家重点实验室基金、中南大学中央高校基本科研业务费青年助推(No.201012200191)资助项目。 (No.201012200191)

The self-assembly of 2,4-dichlorophenoxyacetic acid (Hdcp), 4,4′-bipyridine (bpy) and Nd(NO₃)₃·6H₂O under hydrothermal condition gave one new 1D neodymium coordination polymer, {[Nd(dcp)₃(H₂O)₂]·1.5bpy·2H₂O}_n (1) (dcp=2,4-dichlorophenoxyacetate, bpy=4,4′-bipyridine) which has been characterized by elemental analysis, IR, TGA, PXRD, UV-Vis and single-crystal X-ray diffraction. The dcp ligands linked the Nd(Ⅲ) ions to form an infinite linear chain with a {Nd₂(dcp)₆(H₂O)4} repeat units. Neighboring chains are bridged into a layer structure through O-H…O and O-H…N hydrogen bonds involving the coordinated water molecules, free water molecules and free bpy ligands. The photoluminescence and lifetime of complex 1 in the solid state at room temperature have been studied. CCDC: 894242.
- neodymium(Ⅲ) coordination polymer;crystal structure;2,4-dichlorophenoxyacetate;4,4′-bipyridine;luminescent
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