Citation: ZHAO Fu-Zhen, ZENG Peng-Hui, JI Sheng-Fu. Preparation, Characterization and CO Catalytic Oxidation Performance of Cu_xCe_1-xO_2-x/SBA-15/Cordierite Monolithic Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 753-759. doi: 10.3969/j.issn.1001-4861.2013.00.122 shu

Preparation, Characterization and CO Catalytic Oxidation Performance of Cu_xCe_1-xO_2-x/SBA-15/Cordierite Monolithic Catalysts

1.
1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China;

Received Date: 16 March 2012
Available Online: 26 April 2012
Fund Project: 国家自然科学基金(No.20473009)资助项目。 (No.20473009)

Cu_0.5Ce_0.5O_1.5/SBA-15/cordierite monolithic catalysts with the Cu_0.5Ce_0.5O_1.5 content from 10% to 60% and 50%Cu_xCe_1-xO_2-x/SBA-15/cordierite (x=0~1) monolithic catalysts were prepared using the cordierite as the support and the Cu_xCe_1-xO_2-x/SBA-15 as the catalytic component. The catalysts were characterized using Low Temperature Nitrogen Adsorption-Desorption, XRD, XPS and H₂-TPR. The catalytic activity of the catalysts for the oxidation of CO was evaluated. The results indicate that the mesoporous structure of SBA-15 is retained in the monolithic catalysts. There are the CuO and CeO₂ phases in addition to the cordierite phase. On the surface of the catalyst Cu exists as Cu²⁺ and Cu⁺ species and Ce is as Ce⁴⁺ species. The redox performance of the monolithic catalysts is related with the Cu_0.5Ce_0.5O_1.5 content and the ratio of the Cu and Ce in the Cu_xCe_1-xO_2-x/SBA-15. 50%Cu_0.5Ce_0.5O_1.5/SBA-15/cordierite monolithic catalyst exhibits the best catalytic activity. CO can be completely oxidized at 140℃.
- Cordierite;Monolithic catalysts;Cu_xCe_1-xO_2-x;CO oxidation
1. [1]
  [1] Laguna O H, Centeno M A, Arzamendi G, et al. Catal. Today, 2010,157:155-159
2. [2]
  [2] Liu J, Zhao Z, Xu C, et al. Rare Earths, 2010,28:198-204
3. [3]
  [3] Zheng X C, Wang S P, Wang S R, et al. Mater. Sci. Eng., 2005,25:516-520
4. [4]
  [4] Avgouropoulos G, Ioannides T, Matralis H K, et al. Catal. Lett., 2001,73:33-40
5. [5]
  [5] Derekaya F B, Kutar C, Guldurb C. Mater. Chem. Phys., 2009,115:496-501
6. [6]
  [6] Roy S, Heibel A K, Liu W, et al. Chem. Eng. Sci., 2004,59: 957-966
7. [7]
  [7] ZHAO Fu-Zhen(赵福真), ZENG Peng-Hui(曾鹏晖), ZHANG Guang-Hong(张广宏), et al. Chinese J. Catal.(Cuihua Xuebao), 2010,31:335-342
8. [8]
  [8] Li L, Xue B, Chen J, et al. Appl. Catal., 2005,292:312-321
9. [9]
  [9] Zou H, Dong X, Lin W. Appl. Surf. Sci., 2006,253:2893-2898
10. [10]
  [10] Zheng X, Zhang X, Wang X, et al. Appl. Catal., 2005,295: 142-149
11. [11]
  [11] Águila G, Gracia F, Cortés J, et al. Appl. Catal., 2008,77: 325-338
12. [12]
  [12] Avgouropoulos G, Ioannides T, Matralis H. Appl. Catal., 2005,56:87-93
13. [13]
  [13] Zhu H, Shen M, Kong Y, et al. J. Mol. Catal. A: Chem., 2004,219:155-164
14. [14]
  [14] Liu W, Flytzani-Stephanopoulos M. J. Catal., 1995,153:317-332
15. [15]
  [15] Zhu P, Li J, Zuo S, et al. Appl. Surf. Sci. 2008,255:2903-2909
16. [16]
  [16] Wang S, Zheng X, Wang X, et al. Catal. Lett., 2005,105: 163-168
17. [17]
  [17] Boaro M, Vicario M, Leitenburg C, et al. Catal. Today, 2003,77:407-417
18. [18]
  [18] Gomez-Cortes A, Marquez Y, Arenas-Alatorre J, et al. Catal. Today, 2008,133-135:743-749
19. [19]
  [19] Aguila G, Gracia F, Araya P. Appl. Catal., 2008,343:16-24
20. [20]
  [20] Marino F, Schonbrod B, Moreno M, et al. Catal. Today, 2008,133-135:735-742
21. [21]
  [21] Jia A P, Jiang S Y, Lu J Q, et al. J. Phys. Chem. C, 2010, 114:21605-21610
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation, Characterization and CO Catalytic Oxidation Performance of CuxCe1-xO2-x/SBA-15/Cordierite Monolithic Catalysts

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通讯作者: 陈斌, bchen63@163.com

Preparation, Characterization and CO Catalytic Oxidation Performance of Cu_xCe_1-xO_2-x/SBA-15/Cordierite Monolithic Catalysts