Citation: QIU Li-Gan, WANG Mao-Yuan, SUN Yu-Feng. Ionic Conduction in Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α Ceramic[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 838-844. doi: 10.3969/j.issn.1001-4861.2013.00.117 shu

Ionic Conduction in Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α Ceramic

1.
School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng, Jiangsu 224051, China

Received Date: 20 October 2012
Available Online: 19 November 2012
Fund Project: 江苏省高校“青蓝工程”和江苏省高校自然科学基金(No.07KJB150126)资助项目。 (No.07KJB150126)

Proton-conducting Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α ceramic was prepared by high temperature solid-state reaction. X-ray powder diffraction pattern (XRD) shows that the material is of a single orthorhombic phase of perovskite-type BaCeO₃. Ionic conduction in the material under different gas atmospheres was studied by using gas concentration cell and ac impendence spectroscopy methods in the temperature range of 500~900℃, respectively, and compared with that of Ba_0.9Ca0.1Ce_0.9Nd_0.1O_3-α. The results indicate that Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α is a pure protonic conductor with the protonic transport number of 1 in wet hydrogen in the range 500~900℃. In dry air, Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α is a mixed conductor of oxide ion and electronic hole. The oxide ionic transport numbers are 0.295~0.081. The oxide ionic conductivity of the material is higher than that of Ba_0.9Ca0.1Ce_0.9Nd_0.1O_3-α. In wet air, Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α is a mixed conductor of proton, oxide ion and electronic hole. The protonic transport numbers are 0.151~0.009, and the oxide ionic transport numbers are 0.300~0.107. The protonic conductivity of the material is lower than that of Ba_0.9Ca0.1Ce_0.9Nd_0.1O_3-α. In hydrogen-air fuel cell, Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α is a mixed conductor of proton, oxide ion and electron. The ionic transport numbers are 0.964~0.853. The ionic conductivity of the material is close to that of Ba_0.9Ca0.1Ce_0.9Nd_0.1O_3-α.
- Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α;gas concentration cell;ac impedance;ionic conduction
1. [1]
  [1] Iwahara H. Solid State Ionics, 1996,86-88:9-15
2. [2]
  [2] Peng R R, Wu Y, Yang L Z, et al. Solid State Ionics, 2006, 177:389-393
3. [3]
  [3] Cai M Y, Liu S, Efimov K, et al. J. Membr. Sci., 2009,343: 90-96
4. [4]
  [4] Lee D W, Won J H, Shim K B. Mater. Lett., 2003,57:3346-3351
5. [5]
  [5] Wu J, Davies R A, Islam M S, et al. Chem. Mater., 2005,17: 846-851
6. [6]
  [6] Kreuer K D, Schnherr E, Maier J. Solid State Ionics, 1994, 70/71:278-284
7. [7]
  [7] Ma G L, Shimura T, Iwahara H. Solid State Ionics, 1998, 110:103-110
8. [8]
  [8] LIU Rui-Quan(刘瑞泉), SU Xin-Tai(宿新泰), WANG Ji-De (王吉德), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2004,20(1):57-60
9. [9]
  [9] Iwahara H, Shimura T, Matsumoto H. Electrochemistry, 2000,68(3):154-160
10. [10]
  [10] Yajima T, Iwahara H. Solid State Ionics, 1991,47:117-124
11. [11]
  [11] Ma G L, Shimura T, Iwahara H. Solid State Ionics, 1999, 120:51-60
12. [12]
  [12] Qiu L G, Ma G L, Wen D J. Solid State Ionics, 2004,166: 69-75
13. [13]
  [13] Iwahara H, Uchida H, Ono K, et al. J. Electrochem. Soc., 1988,135:529-533
14. [14]
  [14] Wang M Y, Qiu L G, Zhang T. Chin. J. Chem., 2010,28(2): 1121-1125
15. [15]
  [15] Bonanos N. Solid State Ionics, 1992,53-56:967-974
16. [16]
  [16] MA Gui-Lin(马桂林), QIU Li-Gan(仇立干), CHEN Rong(陈蓉). Acta Chim. Sin.(Huaxue Xuebao), 2002,60(12):2135-2140
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ionic Conduction in Ba0.9La0.1Ce0.9Nd0.1O3-α Ceramic

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通讯作者: 陈斌, bchen63@163.com

Ionic Conduction in Ba_0.9La_0.1Ce_0.9Nd_0.1O_3-α Ceramic