Citation: FENG Guo-Dong, JIANG Luan, YANG De-Suo, CHEN Qiang, WANG Min-Juan, LUO Xiao-Lin, ZHAO Wei-Xing, LI Zong-Xiao. Synthesis, Structure, and Luminescent Property of a Cobalt (Ⅱ) Compound with a 1D Double-Zigzag Chain Structure Using Rigid Aromatic Dicarboxylate Acids and Flexible Bis(2-benzimidazolyl)alkanes Linkers[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 831-837. doi: 10.3969/j.issn.1001-4861.2013.00.116 shu

Synthesis, Structure, and Luminescent Property of a Cobalt (Ⅱ) Compound with a 1D Double-Zigzag Chain Structure Using Rigid Aromatic Dicarboxylate Acids and Flexible Bis(2-benzimidazolyl)alkanes Linkers

1.
1 Key Laboratory of Functional Coordination Compounds, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, Baoji, Shaanxi 721013, China;

Received Date: 2 May 2012
Available Online: 23 November 2012
Fund Project: 陕西省重点实验室项目(No.11JS006, 11JS007)陕西省教育厅项目(No.11JK0603)吉林大学无机合成与制备国家重点实验室开放基金 (2013-08)资助项目。 (No.11JS006, 11JS007)陕西省教育厅项目(No.11JK0603)吉林大学无机合成与制备国家重点实验室开放基金 (2013-08)

By using the bis(2-benzimidazolyl)alkanes as the N-donor ligand and 1,4-benzenedicarboxylic acid as the second metal linker, a novel cobalt(Ⅱ) compound with a 1D double-zigzag chain structure, namely, [Co(BDC)(H₂C₃PIm)(H₂O)]_n (1) (H₂C₃PIm=2,2-(1,3-propanediyl)-bis(1H-benzimidazole), BDC=1,4-benzenedicarboxylic acid) has been synthesized under hydrothermal conditions and characterized by elemental analysis, thermal analysis, X-ray single-crystal diffraction. The crystal belongs to the orthorhombic system, space group Pca2₁ with a=1.488 6(5) nm, b=1.791 7(5) nm, c=1.894 3(5) nm, V=5.052(3) nm³, D_c=1.360 g·cm^-3, Z=8, F(000)=2 136, Goof=0.986, R₁=0.042 5, wR₂=0.068 7. In compound 1, the distorted tetrahedral Co(Ⅱ) ion is bridged by the carboxylic oxygen atoms of the BDC ligand and chelated by the nitrogen atoms of the H₂C₃PIm ligand. Owning to the different of the distorted angles from the BDC ligand, the compound units are linked into 1D double-zigzag chain structure (mode A; mode B) via the C-H…π interactions and N-H…O, O-H…O hydrogen bonding between uncoordinated carboxylate and the nitrogen atoms of H₂C₂EIm as well as the free water molecules and further extended into a 3D supramolecular structure through the intermolecular hydrogen bonds between the adjacent A and the adjacent B zigzag chains. The luminescent property of compound 1 has also been studied. CCDC: 839239.
- cobalt(Ⅱ) compound;double-zigzag chain structure;1,4-benzenedicarboxylic acid;bis(¹H-benzimidazole);luminescence
1. [1]
  [1] Henninger S K, Habib H A, Janiak C. J. Am. Chem. Soc., 2009,131:2776-2777
2. [2]
  [2] Habib H A, Hoffmann A, Hoppe H A, et al. Dalton Trans., 2009:1742-1751
3. [3]
  [3] Habib H A, Sanchiz J, Janiak C. Dalton Trans., 2008:4877-4884
4. [4]
  [4] Janiak C. Dalton Trans., 2003:2781-2804
5. [5]
  [5] Higuchi M, Tanaka D, Horike S, et al. J. Am. Chem. Soc., 2009,131:10336-10337
6. [6]
  [6] Tsai M R, Wu J Y, Lai L L. Eur. J. Inorg. Chem., 2011:2172 -2178
7. [7]
  [7] Paz F A A, Klinowski J. Inorg. Chem., 2004,43:3882-3893
8. [8]
  [8] FENG Guo-Dong(冯国栋), JIANG Luan(姜娈), LI Zong-Xiao (李宗孝). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:1664-1668
9. [9]
  [9] Feng G D, Jiang L, Su Z M. Z. Anorg. Allg. Chem., 2011, 637:2211-2214
10. [10]
  [10] Wang Y, Shao K Z, Su Z M, et al. Inorg. Chem. Commun., 2006,9:1207-1211
11. [11]
  [11] Hoorn H J, de Joode P, Dijkstra D J, et al. J. Mater. Chem., 1997,7:1747-1752
12. [12]
  [12] Koolhaas G J A A, van Berkel P M, van der Slot S C, et al. Inorg. Chem., 1996,35:3525-3529
13. [13]
  [13] Salunke N M, Revankar V K, Mahale V B. Trans. Metal Chem., 1994,19:53-61
14. [14]
  [14] Bouwman E, Driessen W L, Reedijk J. Coord. Chem. Rev., 1990,104:143-149
15. [15]
  [15] Du M, Jiang X J, Zhao X J. Inorg. Chem., 2006,45:3998-4006
16. [16]
  [16] Jiang L, Feng G D, Su Z M. Inorg. Chem. Commun., 2011, 14:1077-1081
17. [17]
  [17] Arora V, Gupta M, Mathur P. Indian J. Chem., 1999,38: 1219-1224
18. [18]
  [18] Liu S G, Zuo J L, Li Y Z. J. Mol. Struct., 2004,705:153-157
19. [19]
  [19] De Santis G, Fabbrizzi L, Licchelli M, et al. Inorg. Chem., 1995,34:3581-3589
20. [20]
  [20] Lilian L Y W, Madeleine M J. J. Am. Chem. Soc., 1957,79: 5706-5708
21. [21]
  [21] Higashi T. Program for Absorption Correction, Rigaku Corporation, Tokyo, Japan, 1995.
22. [22]
  [22] SHELXTL, Version 5.1, Siemens Industrial Automation, Inc., 1997.
23. [23]
  [23] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany, 1997.
24. [24]
  [24] Wang X L, Zhang J X. J. Solid State Chem., 2011,184:280-288
25. [25]
  [25] Wu J, Huang C, Fu L X. Inorg. Chem. Commun., 2012,19: 23-26
26. [26]
  [26] Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3889
27. [27]
  [27] Staszczuk P, Jaroniec M, Gilpin R K. Anal. Chim. Acta, 1992,269:157-163
28. [28]
  [28] Cordes M M, Walter J L. Spectrochim. Acta A, 1968,24: 1421-1435
29. [29]
  [29] Bellam Y L J. The Infrared Spectra of Complex Molecules: Vol.Ⅰ, Vol.Ⅱ. London: Chapman and Hall, 1980.
30. [30]
  [30] Bellamy L J. The Infrared Spectra of Complex Molecules. New York: Wiley, 1958.
31. [31]
  [31] Shi W, Chen X Y, Zhao B, et al. Inorg. Chem., 2006,45: 3949-3952
32. [32]
  [32] Zhou Z Y, Liu C B, Guo H X, et al. Chem. J. Internet., 2006,10:65-69
33. [33]
  [33] McGarrah J E, Kim Y J, Hissler M, et al. Inorg. Chem., 2001,40:4510-4511
34. [34]
  [34] Wu Q G, Esteghamatian M, Zoran P, et al. Chem. Mater., 2000,12:79-83
35. [35]
  [35] Tao J, Tong M L, Chen X M, et al. Chem. Commun., 2000, 20:2043-2044
36. [36]
  [36] Yan Y, Wu C D, Lu C Z. Z. Anorg. Allg. Chem., 2003,629: 1991-1996
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