Citation: FENG Guo-Dong, JIANG Luan, YANG De-Suo, CHEN Qiang, WANG Min-Juan, LUO Xiao-Lin, ZHAO Wei-Xing, LI Zong-Xiao. Synthesis, Structure, and Luminescent Property of a Cobalt (Ⅱ) Compound with a 1D Double-Zigzag Chain Structure Using Rigid Aromatic Dicarboxylate Acids and Flexible Bis(2-benzimidazolyl)alkanes Linkers[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 831-837. doi: 10.3969/j.issn.1001-4861.2013.00.116 shu

Synthesis, Structure, and Luminescent Property of a Cobalt (Ⅱ) Compound with a 1D Double-Zigzag Chain Structure Using Rigid Aromatic Dicarboxylate Acids and Flexible Bis(2-benzimidazolyl)alkanes Linkers

1.
1 Key Laboratory of Functional Coordination Compounds, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, Baoji, Shaanxi 721013, China;

Received Date: 2 May 2012
Available Online: 23 November 2012
Fund Project: 陕西省重点实验室项目(No.11JS006, 11JS007)陕西省教育厅项目(No.11JK0603)吉林大学无机合成与制备国家重点实验室开放基金 (2013-08)资助项目。 (No.11JS006, 11JS007)陕西省教育厅项目(No.11JK0603)吉林大学无机合成与制备国家重点实验室开放基金 (2013-08)

By using the bis(2-benzimidazolyl)alkanes as the N-donor ligand and 1,4-benzenedicarboxylic acid as the second metal linker, a novel cobalt(Ⅱ) compound with a 1D double-zigzag chain structure, namely, [Co(BDC)(H₂C₃PIm)(H₂O)]_n (1) (H₂C₃PIm=2,2-(1,3-propanediyl)-bis(1H-benzimidazole), BDC=1,4-benzenedicarboxylic acid) has been synthesized under hydrothermal conditions and characterized by elemental analysis, thermal analysis, X-ray single-crystal diffraction. The crystal belongs to the orthorhombic system, space group Pca2₁ with a=1.488 6(5) nm, b=1.791 7(5) nm, c=1.894 3(5) nm, V=5.052(3) nm³, D_c=1.360 g·cm^-3, Z=8, F(000)=2 136, Goof=0.986, R₁=0.042 5, wR₂=0.068 7. In compound 1, the distorted tetrahedral Co(Ⅱ) ion is bridged by the carboxylic oxygen atoms of the BDC ligand and chelated by the nitrogen atoms of the H₂C₃PIm ligand. Owning to the different of the distorted angles from the BDC ligand, the compound units are linked into 1D double-zigzag chain structure (mode A; mode B) via the C-H…π interactions and N-H…O, O-H…O hydrogen bonding between uncoordinated carboxylate and the nitrogen atoms of H₂C₂EIm as well as the free water molecules and further extended into a 3D supramolecular structure through the intermolecular hydrogen bonds between the adjacent A and the adjacent B zigzag chains. The luminescent property of compound 1 has also been studied. CCDC: 839239.
- cobalt(Ⅱ) compound;double-zigzag chain structure;1,4-benzenedicarboxylic acid;bis(¹H-benzimidazole);luminescence
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