Citation: YANG Li-Guo, ZHANG Dao-Peng, LI Da-Cheng, DOU Jian-Min. Synthesis, Spectra Characterization and Crystal Structure of Three Nickle(Ⅱ) Complexes Containing Nido-carborane Disphosphine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 875-882. doi: 10.3969/j.issn.1001-4861.2013.00.114 shu

Synthesis, Spectra Characterization and Crystal Structure of Three Nickle(Ⅱ) Complexes Containing Nido-carborane Disphosphine Ligand

1.
1 Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China;

Received Date: 26 February 2012
Available Online: 22 November 2012
Fund Project: 国家自然科学基金(No.20971063) (No.20971063)

Three nickel carborane disphosphine complexes [NiCl(Py){7, 8-(PPh₂)₂-7,8-C₂B₉H₁₀}]CH₂Cl₂(1), [Ni{7, 8-(PPh₂)₂-7, 8-C₂B₉H₁₀}₂](2) and [Ni{7, 8-(OPPh₂)-7, 8-C₂B₉H₁₀}{7, 8-(PPh₂)-7, 8-C₂B₉H₁₀}](3) have been synthesized and characterized by elemental analysis, FTIR, ¹H and ¹³C NMR spectroscopy and X-ray structure determination. Single crystal analysis shows that the coordination environment of the Ni atom is a slightly distorted square-planar in the complexes 1~3, in which the four positions are occupied by two P atoms, one Cl atom and one N atom of pyridine in 1, four P atoms in 2 and two P atoms and two O atoms in 3, respectively. One dimensional chain structure can be formed depending on C-H…Cl or dihydrogen bonding interactions in these three complexes. CCDC: 749848, 1; 749846, 2; 799937, 3.
- synthesis and characterization;crystal structure;nickel(Ⅱ) carborane complexes
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