Citation: YANG Li-Guo, ZHANG Dao-Peng, LI Da-Cheng, DOU Jian-Min. Synthesis, Spectra Characterization and Crystal Structure of Three Nickle(Ⅱ) Complexes Containing Nido-carborane Disphosphine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 875-882. doi: 10.3969/j.issn.1001-4861.2013.00.114 shu

Synthesis, Spectra Characterization and Crystal Structure of Three Nickle(Ⅱ) Complexes Containing Nido-carborane Disphosphine Ligand

1.
1 Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China;

Received Date: 26 February 2012
Available Online: 22 November 2012
Fund Project: 国家自然科学基金(No.20971063) (No.20971063)

Three nickel carborane disphosphine complexes [NiCl(Py){7, 8-(PPh₂)₂-7,8-C₂B₉H₁₀}]CH₂Cl₂(1), [Ni{7, 8-(PPh₂)₂-7, 8-C₂B₉H₁₀}₂](2) and [Ni{7, 8-(OPPh₂)-7, 8-C₂B₉H₁₀}{7, 8-(PPh₂)-7, 8-C₂B₉H₁₀}](3) have been synthesized and characterized by elemental analysis, FTIR, ¹H and ¹³C NMR spectroscopy and X-ray structure determination. Single crystal analysis shows that the coordination environment of the Ni atom is a slightly distorted square-planar in the complexes 1~3, in which the four positions are occupied by two P atoms, one Cl atom and one N atom of pyridine in 1, four P atoms in 2 and two P atoms and two O atoms in 3, respectively. One dimensional chain structure can be formed depending on C-H…Cl or dihydrogen bonding interactions in these three complexes. CCDC: 749848, 1; 749846, 2; 799937, 3.
- synthesis and characterization;crystal structure;nickel(Ⅱ) carborane complexes
1. [1]
  [1] Wiesboeck R A, Hawthorne M F. J. Am. Chem. Soc., 1964, 86:1642-1643
2. [2]
  [2] (a) Soloway A H, Tjarks W, Barnum B A, et al. Chem. Rev., 1998,98:1515-1562
3. [3]
  (b) Valliant J F, Guenther K J, King A S, et al. Coord. Chem. Rev., 2002,232:173-230
4. [4]
  (c) Hawthorne M F, Maderna A. Chem. Rev., 1999,99:3421- 3434
5. [5]
  [3] (a) Korshak V V, Teplyakov M M, Khotina I A, et al. Acta Polym., 1988,39:440-445
6. [6]
  (b) Douglass A G, Czuprynski K. Mierzwa M. et al. J. Mater. Chem., 1998,8:2391-2398
7. [7]
  (c) Douglass A G, Czuprynski K, Mierzwa M, et al. Chem. Mater., 1998,10:2399-2402
8. [8]
  [4] (a) Plešek J. Chem. Rev., 1992,92:269-278
9. [9]
  (b) Grimes R N. J. Chem. Edu., 2004,81:657-672
10. [10]
  [5] (a) Andrews P C, Raston C L. J. Organomet. Chem., 2000, 600:174-185
11. [11]
  (b) Hardie M J, Raston C L. Chem. Commun., 1999:1153- 1163
12. [12]
  [6] Teixidor F, Vias C, Abad M M, et al. Organometallics, 1993,12:3766-3768
13. [13]
  [7] Nuñez R, Viñas C, Teixidor F, et al. Appl. Organomet. Chem., 2003,17:509-517
14. [14]
  [8] Bembenek E, Crespo O, Gimeno M C, et al. Chem. Ber., 1994,127:835-840
15. [15]
  [9] Crespo O, Gimeno M C, Jones P G, et al. J. Chem. Soc., Dalton Trans., 1996:458-464
16. [16]
  [10] Teixidor F, Vias C, Abad M M, et al. J. Organomet. Chem., 1996,509:139-150
17. [17]
  [11] Crespo O, Gimeno M C, Laguna A, et al. J. Chem. Soc., Dalton Trans., 1992:1601-1605
18. [18]
  [12] Crespo O, Gimeno M C, Jones P G, et al. J. Chem. Soc., Chem. Commun., 1993:1696-1699
19. [19]
  [13] Crespo O, Gimeno M C, Jones P G, et al. Inorg. Chem., 1994,33:6128-6131
20. [20]
  [14] Crespo O, Gimeno M C, Jones P G, et al. Inorg. Chem., 1996,35:1361-1366
21. [21]
  [15] Calhorda M J, Crespo O, Gimeno M C, et al. Inorg. Chem., 2000,39:4280-4285
22. [22]
  [16] Crespo O, Gimeno M C, Jones P G, et al. Angew. Chem. Int. Ed. Engl., 1997,36:993-996
23. [23]
  [17] Vias C, Abad M M, Teixidor F, et al. J. Organomet. Chem., 1998,555:17-23
24. [24]
  [18] Paavola S, Kivekäs R, Teixidor F, et al. J. Organomet. Chem., 2000,606:183-187
25. [25]
  [19] Paavola S, Teixidor F, Viñas C, et al. J. Organomet. Chem., 2000,645:39-46
26. [26]
  [20] Paavola S, Teixidor F, Vias C, et al. J. Organomet. Chem., 2000,657:187-193
27. [27]
  [21] Teixidor F, Vias C, Abad M M, et al. Organometallics, 1996,15:3154-3160
28. [28]
  [22] Zhang D P, Dou J M, Gong S W, et al. et al. Appl. Organomet. Chem., 2006,20:632-637
29. [29]
  [23] Dou J M, Zhang D P, Li D C, et al. J. Organomet. Chem., 2006,691:5673-5679
30. [30]
  [24] Dou J M, Zhang D P, Li D C, et al. Eur. J. Inorg. Chem., 2007,53-59
31. [31]
  [25] Zhang D P, Dou J M, Li D C, et al. Inorg. Chim. Acta, 2006,359:4243-4249
32. [32]
  [26] Vias C, Nuez R, Rojo I, et al. Inorg. Chem., 2001,40:3259-3260
33. [33]
  [27] Teixidor F, Viñas C, Abad M M, et al. J. Organomet. Chem., 1995,503:193-203
34. [34]
  [28] Sheldrick G M. SHELXTL 5.10 for Windows NT: Structure Determination Software Programs, Bruker Analytical X-ray Systems, Madison, WI, 1997.
35. [35]
  [29] (a) Kazuo N, Translated by HUANG De-Ru (黄德如). Infrared and Raman Spectra of Inorganic and Coordination Compounds (无机和配位化合物的红外和拉曼光谱). Beijing: Chemical Industry Press, 1986:175
36. [36]
  (b) Crook J E, Greenwood N N, Kennedy J D. J. Chem. Soc. Dalton Trans., 1972.171
37. [37]
  [30] Balema V P, Pink M, Sieler J, et al. Polyhedron, 1998,17: 2087-2093
38. [38]
  [31] Sundberg M R, Paavola S, Viñas C, et al. Inorg. Chim. Acta, 2005,358:2107-2111
39. [39]
  [32] Vergadou V, Pistolis G, Michaelides A, et al. Cryst. Growth Des., 2006,6:2486-2492
40. [40]
  [33] Desiraju G R. Crystal Engineering: The Design of Organic Solids. Amsterdam: Elsevier, 1989.
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