Citation: CAI Shu-Lan, XIE Bin, WANG Yan-Mei, WANG Jun, ZOU Li-Ke, CHENG Jie, ZHU Sha-Sha, LAI Chuan, ZENG Ni. Synthesis, Crystal Structure, Thermal Stability Property and Antibactericidal Activity of Binuclear Lead Complex of O,O′-Di(p-tert-butylphenyl)dithiophosphate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 779-785. doi: 10.3969/j.issn.1001-4861.2013.00.113 shu

Synthesis, Crystal Structure, Thermal Stability Property and Antibactericidal Activity of Binuclear Lead Complex of O,O′-Di(p-tert-butylphenyl)dithiophosphate

CAI Shu-Lan ¹ ,
XIE Bin ^1,2 ,
WANG Yan-Mei ³ ,
WANG Jun ¹ ,
ZOU Li-Ke ¹ ,
CHENG Jie ¹ ,
ZHU Sha-Sha ³ ,
LAI Chuan ^3,4 ,
ZENG Ni ³

1.
1 Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong, Sichuan 643000, China;

Received Date: 5 June 2012
Available Online: 25 December 2012
Fund Project: 材料腐蚀与防护四川省重点实验室开放基金项目(No.2011CL03) (No.2011CL03)四川理工学院培育项目(No.2012PY14) (No.2012PY14)四川理工学院研究生创新基金(No.y2011015和No.y2011019)资助项目。 (No.y2011015和No.y2011019)

A new binuclear lead complex [Pb₂(S₂P(OR¹)₂)₂(μ-S₂P(OR¹)₂)₂] (R1 is p-tert-butylphenyl group) was synthesized and characterized by elemental analysis, IR, UV-Vis, TG-DSC, and single crystal X-ray diffraction analysis. The crystal structure study shows that the title complex is dinuclear structure which form an chair conformation of eight-membered ring [Pb₂S₄P₂], and the lead atom is in a distorted ψ-pentagonal bipyramidal coordination environment Pb(S₅ArE) by means of the weak π coordination from an aryl group of the bridging (R¹O)₂PS₂-ligand to lead atom and a lone pair of stereochemically active electrons originating from the lead atom. The antibacterial activities of the raw material (R¹O)₂PS₂NH₂Et₂ and complex were studied against E. Coli, B. Subtilis, and S. Aureus. The bioactivity test shows that both the raw material and complex can inhibit three kinds of bacteria, and the complex has higher antibacterial activity being compared with the raw material against E. Coli and B. Subtilis. CCDC: 870009.
- O,O′-Dialkyldithiophosphate;Pb complex;synthesis;crystal structure;thermal stable property;antibacterial activity
1. [1]
  [1] XIANGYang-Guang(相阳光). Master Degree Thesis of Sichuan University of Science & Engineering(四川理工学院硕士论文). 2011.
2. [2]
  [2] Rusanova D, Pike K J, Persson I, et al. Polyhedron, 2006,25 (18):3569-3580
3. [3]
  [3] Biricik N, Gümgüm B. Thermochim. Acta, 2004,417(2):43-45
4. [4]
  [4] XIE Bin(谢斌), WU Shi-Ye(吴士业). Chem. J. Chinese Univ.(Gaodeng Xuexiao Huaxue Xuebao), 1998,19(1):74-77
5. [5]
  [5] Ivanov A V, Gerasimenko A V, Antzutkin O N, et al. Inorg. Chim. Acta, 2005,358(9):2585-2594
6. [6]
  [6] Larsson A C, Ivanov A V, Forsling W, et al. J. Am. Chem. Soc., 2005,127(9):2218-2230
7. [7]
  [7] Jain P U, Munshi P, Walawalkar M G, et al. Polyhedron, 2000,19(7):801-808
8. [8]
  [8] Bajia S, Mishra A, Butcher R, et al. India J. Coord. Chem., 2010,63(24):4271-4279
9. [9]
  [9] Ta M, Yagan M, Bat H, et al. Phosphorus, Sulfur Silicon Relat. Elem., 2010,185(1):242-248
10. [10]
  [10] XIE Bin(谢斌), XIANG Yang-Guang(相阳光), LAI Chuan (赖川), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(5):886-890
11. [11]
  [11] Addison A W, Rao T N, Reedijik J, et al. J. Chem. Soc., Dalton Trans., 1984,7:1349-1356
12. [12]
  [12] Sharma P K, Singh Y. Phosphorus, Sulfur Silicon Relat. Elem., 2007,182(6):1183-1190
13. [13]
  [13] Gupta A, Sharma R K, Bohra R, et al. J. Organomet. Chem., 2003,678(1-2):122-127
14. [14]
  [14] Maltez H F, Borges D L G, Carasek E, et al. Talanta, 2008, 74(4):800-805
15. [15]
  [15] Harrison P G, Steel A, Pelizzi G, et al. Main Group Met. Chem., 1988,11(4):181-204
16. [16]
  [16] Harrison P G, Kikabhai T. Wear, 1987,116(1):25-31
17. [17]
  [17] Ito T. Acta Crystallogr., Sect. B, 1972,28:1034
18. [18]
  [18] Lawton S L, Kokotailo G T. Inorg. Chem., 1972,11(1):363-368
19. [19]
  [19] Larsson A C, Ivanov A V, Antzutkin O N, et al. Inorg. Chim. Acta, 2004,357(9):2510-2518
20. [20]
  [20] Harrison P G, Begley M G, Kikabhai T, et al. J. Chem. Soc., Dalton Trans., 1989(12):2443-2448
21. [21]
  [21] Larsson A C, Ivanov A V, Pike K J, et al. J. Magn. Reson., 2005,177(1):56-66
22. [22]
  [22] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, Germany, University of Göttingen, 1997.
23. [23]
  [23] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, Germany, University of Göttingen, 1997
24. [24]
  [24] HU Cheng-zhi(胡盛志), ZHOU Chao-Hui(周朝晖), CAI Qi-Duan(蔡启端). Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2003,19(11):1073-1077
25. [25]
  [25] Silvestru C, Haiduc I, Cea-Olivares R, et al. Inorg. Chim. Acta, 1995,233(1/2):151-154
26. [26]
  [26] Gillespie R J, Nyholm R S. Quart. Rev. Chem. Soc., 1957, 11:339-380
27. [27]
  [27] Maheshwari S, Drake J E, Kori K, et al. Polyhedron, 2009, 28(4):689-694
28. [28]
  [28] XIE Bin(谢斌), LAI Chuan(赖川), XIANG Yang-Guang(相阳光), et al. Chinese J. Appl. Chem.(Yingyong Huaxue), 2012,29(2):200-208
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