Citation: CAI Shu-Lan, XIE Bin, WANG Yan-Mei, WANG Jun, ZOU Li-Ke, CHENG Jie, ZHU Sha-Sha, LAI Chuan, ZENG Ni. Synthesis, Crystal Structure, Thermal Stability Property and Antibactericidal Activity of Binuclear Lead Complex of O,O′-Di(p-tert-butylphenyl)dithiophosphate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 779-785. doi: 10.3969/j.issn.1001-4861.2013.00.113 shu

Synthesis, Crystal Structure, Thermal Stability Property and Antibactericidal Activity of Binuclear Lead Complex of O,O′-Di(p-tert-butylphenyl)dithiophosphate

CAI Shu-Lan ¹ ,
XIE Bin ^1,2 ,
WANG Yan-Mei ³ ,
WANG Jun ¹ ,
ZOU Li-Ke ¹ ,
CHENG Jie ¹ ,
ZHU Sha-Sha ³ ,
LAI Chuan ^3,4 ,
ZENG Ni ³

1.
1 Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong, Sichuan 643000, China;

Received Date: 5 June 2012
Available Online: 25 December 2012
Fund Project: 材料腐蚀与防护四川省重点实验室开放基金项目(No.2011CL03) (No.2011CL03)四川理工学院培育项目(No.2012PY14) (No.2012PY14)四川理工学院研究生创新基金(No.y2011015和No.y2011019)资助项目。 (No.y2011015和No.y2011019)

A new binuclear lead complex [Pb₂(S₂P(OR¹)₂)₂(μ-S₂P(OR¹)₂)₂] (R1 is p-tert-butylphenyl group) was synthesized and characterized by elemental analysis, IR, UV-Vis, TG-DSC, and single crystal X-ray diffraction analysis. The crystal structure study shows that the title complex is dinuclear structure which form an chair conformation of eight-membered ring [Pb₂S₄P₂], and the lead atom is in a distorted ψ-pentagonal bipyramidal coordination environment Pb(S₅ArE) by means of the weak π coordination from an aryl group of the bridging (R¹O)₂PS₂-ligand to lead atom and a lone pair of stereochemically active electrons originating from the lead atom. The antibacterial activities of the raw material (R¹O)₂PS₂NH₂Et₂ and complex were studied against E. Coli, B. Subtilis, and S. Aureus. The bioactivity test shows that both the raw material and complex can inhibit three kinds of bacteria, and the complex has higher antibacterial activity being compared with the raw material against E. Coli and B. Subtilis. CCDC: 870009.
- O,O′-Dialkyldithiophosphate;Pb complex;synthesis;crystal structure;thermal stable property;antibacterial activity
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