Citation: LI Peng, DING Xin-Geng, YANG Hui, SU Wei, DOU Tian-Jun. Effect of Mass Fraction of CeO₂ on Leaching Behavior of Aluminoborosilicate Glass[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 709-714. doi: 10.3969/j.issn.1001-4861.2013.00.110 shu

Effect of Mass Fraction of CeO₂ on Leaching Behavior of Aluminoborosilicate Glass

LI Peng ¹ ,
DING Xin-Geng ^1,2 ,
YANG Hui ^1,2 ,
SU Wei ³ ,
DOU Tian-Jun ³

1.
1 State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China;

Received Date: 20 October 2012
Available Online: 5 December 2012
Fund Project: 浙江省重点科技创新团队资金(No.2009R50010)资助项目。 (No.2009R50010)

Phase change in aluminoborosilicate glass and effect on leaching behavior were studied with different mass fraction of CeO₂ via characterization methods of XRD, XPS, SEM and ICP-MS. The results showed that: In glass network structure the molar ratio of quadrivalence Ce and trivalent Ce was 9.25:1. And when mass fraction of CeO₂ met or exceeded 7%, the cerianite began to be precipitated in glass. With mass fraction of CeO₂ increasing, r_Ce of glass decreased at first and then increased in 1 day, and showed trend to decrease in 28 day. However, in the same mass fraction of CeO₂, r_Ce gradually decreased with the prolongation of leaching time. And r_Ce of the glass sample bE stabilized lower than 4×10^-6 g·m^-2·d^-1 after 7 day with 9wt% CeO₂. The leaching behavior was excellent. Hence, controlling CeO₂ precipitated within a certain range could be superior to completely dissolving one in glass on leaching behavior.
- CeO₂;leaching behavior;vitrification
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Mass Fraction of CeO2 on Leaching Behavior of Aluminoborosilicate Glass

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通讯作者: 陈斌, bchen63@163.com

Effect of Mass Fraction of CeO₂ on Leaching Behavior of Aluminoborosilicate Glass