Citation: LI Peng, DING Xin-Geng, YANG Hui, SU Wei, DOU Tian-Jun. Effect of Mass Fraction of CeO₂ on Leaching Behavior of Aluminoborosilicate Glass[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 709-714. doi: 10.3969/j.issn.1001-4861.2013.00.110 shu

Effect of Mass Fraction of CeO₂ on Leaching Behavior of Aluminoborosilicate Glass

LI Peng ¹ ,
DING Xin-Geng ^1,2 ,
YANG Hui ^1,2 ,
SU Wei ³ ,
DOU Tian-Jun ³

1.
1 State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China;

Received Date: 20 October 2012
Available Online: 5 December 2012
Fund Project: 浙江省重点科技创新团队资金(No.2009R50010)资助项目。 (No.2009R50010)

Phase change in aluminoborosilicate glass and effect on leaching behavior were studied with different mass fraction of CeO₂ via characterization methods of XRD, XPS, SEM and ICP-MS. The results showed that: In glass network structure the molar ratio of quadrivalence Ce and trivalent Ce was 9.25:1. And when mass fraction of CeO₂ met or exceeded 7%, the cerianite began to be precipitated in glass. With mass fraction of CeO₂ increasing, r_Ce of glass decreased at first and then increased in 1 day, and showed trend to decrease in 28 day. However, in the same mass fraction of CeO₂, r_Ce gradually decreased with the prolongation of leaching time. And r_Ce of the glass sample bE stabilized lower than 4×10^-6 g·m^-2·d^-1 after 7 day with 9wt% CeO₂. The leaching behavior was excellent. Hence, controlling CeO₂ precipitated within a certain range could be superior to completely dissolving one in glass on leaching behavior.
- CeO₂;leaching behavior;vitrification
1. [1]
  [1] PENG Lin(彭琳), ZHAO Gao-Ling(赵高凌), YING Hao(应浩), et al. J. Chin. Ceram. Soc.(Guisuanyan Xuebao), 2007, 35(7):856-865
2. [2]
  [2] SONG Guo-Hua(宋国华), MIAO Jian-Wen(缪建文), WANG Miao(王淼), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(11):1975-1980
3. [3]
  [3] LU Xiao-Jun(陆晓军), XIAO Zhi-Yi(肖志义), ZHANG Xi-Yan(张希艳), et al. Chin. J. Lumines.(Faguang Xuebao), 2005,26(6):819-822
4. [4]
  [4] FU Zhen-Xiao(付振晓), ZHANG Qi-Tu(张其土), XU Zhong-Zi(许仲梓). J. Chin. Rare Earth Soc.(Zhongguo Xitu Xuebao), 2003,21(2):196-199
5. [5]
  [5] Lutze W, Ewing R C. Radioactive Wasteforms for the Future. North-Holland: Amsterdam, 1988:4
6. [6]
  [6] Ojovan M I, Lee W E. An Introduction to Nuclear Waste Immobilisation. Amsterdam: Elsevier, 1995:215
7. [7]
  [7] Bingham P A, Hand R J, Stennett M C, et al. Mater. Res. Soc. Symp. Proc. Sci., 2008,1107:421-428
8. [8]
  [8] Li H, Hrma P, Vienna J D, et al. J. Non-Cryst. Solids, 2003, 331:202-216
9. [9]
  [9] ZU Cheng-Kui(祖成奎), WANG Yan-Hang(王衍行), CHEN Jiang(陈江), et al. Bull. Chin. Ceram. Soc.(Guisuanyan Tongbao), 2004(4): 29-43
10. [10]
  [10] Frugier P, Chave T, Gin S, et al. J. Nucl. Mater., 2009,392: 552-567
11. [11]
  [11] Advocat T, Jollivet P, Crovisier J L, et al. J. Nucl. Mater., 2001,298:55-62
12. [12]
  [12] Munier I, Crovisier J L, Grambow B, et al. J. Nucl. Mater., 2004,324:97-115
13. [13]
  [13] LIANG Xiao-Feng(梁晓峰), LAI Yuan-Ming(赖元明), YING Guang-Fu(尹光福), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(1):35-39
14. [14]
  [14] LAI Yuan-Min(赖元明), LIANG Xiao-Feng(梁晓峰), QIAN Bin(钱斌), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(4):721-726
15. [15]
  [15] LIAO Qi-Long(廖其龙), WANG Fu(王辅), PAN She-Qi(潘社奇), et al. J. Nucl. Radiochem.(He Huaxue Yu Fangshe Huaxue), 2010,32(6):336-341
16. [16]
  [16] Yang G, Stuart C, Russell J, et al. J. Eur. Ceram. Soc., 2010,30:831-838
17. [17]
  [17] ASTM c 1285-02. United States: ASTM International, 2002: 1-22
18. [18]
  [18] Rygel J L, Chen Y S, Pantano C G, et al. J. Am. Ceram. Soc., 2011,94:2442-2451
19. [19]
  [19] Yang H M, Tao Q F. J. Am. Ceram. Soc., 2010,93:1056-1061
20. [20]
  [20] Cailleteau C, Angeli F, Devreux F, et al. Nature Mater., 2008,7:978-983
21. [21]
  [21] Ojovan M I, Pankov A, Lee W E, et al. J. Nucl. Mater., 2006,358:57-68
1. [1]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
2. [2]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
3. [3]
  Peng Li , Yuanying Cui , Zhongliao Wang , Graham Dawson , Chunfeng Shao , Kai Dai . Efficient interfacial charge transfer of CeO₂/Bi₁₉Br₃S₂₇ S-scheme heterojunction for boosted photocatalytic CO₂ reduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100065-0. doi: 10.1016/j.actphy.2025.100065
4. [4]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
5. [5]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
6. [6]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
7. [7]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
8. [8]
  Simin Wei , Yaqing Yang , Junjie Li , Jialin Wang , Jinlu Tang , Ningning Wang , Zhaohui Li . The Mn/Yb/Er triple-doped CeO₂ nanozyme with enhanced oxidase-like activity for highly sensitive ratiometric detection of nitrite. Chinese Chemical Letters, 2024, 35(6): 109114-. doi: 10.1016/j.cclet.2023.109114
9. [9]
  Xiangyang Ji , Yishuang Chen , Peng Zhang , Shaojia Song , Jian Liu , Weiyu Song . Boosting the first C–H bond activation of propane on rod-like V/CeO₂ catalyst by photo-assisted thermal catalysis. Chinese Chemical Letters, 2025, 36(5): 110719-. doi: 10.1016/j.cclet.2024.110719
10. [10]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
11. [11]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
12. [12]
  Hongwei Ding , Jingjing Yang , Yongchen Shuai , Di Wei , Xueliang Liu , Guiying Li , Lin Jin , Jianliang Shen . In situ preparation of tannin-mediated CeO₂@CuS nanocomposites for multimodal wound therapy. Chinese Chemical Letters, 2025, 36(6): 110286-. doi: 10.1016/j.cclet.2024.110286
13. [13]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
14. [14]
  Peng Zhang , Yitao Yang , Tian Qin , Xueqiu Wu , Yuechang Wei , Jing Xiong , Xi Liu , Yu Wang , Zhen Zhao , Jinqing Jiao , Liwei Chen . Interface engineering of Pt/CeO₂-{100} catalysts for enhancing catalytic activity in auto-exhaust carbon particles oxidation. Chinese Chemical Letters, 2025, 36(2): 110396-. doi: 10.1016/j.cclet.2024.110396
15. [15]
  Ling Zhang , Jing Kang . Turn Waste into Valuable: Preparation of High-Strength Water-Based Adhesives from Polymethylmethacrylate Wastes: a Comprehensive Chemical Experiments. University Chemistry, 2024, 39(2): 221-226. doi: 10.3866/PKU.DXHX202306075
16. [16]
  Naiying Fan , Chuanli Qin , Guo Zhang , Bin Wang , Yan Wang , Bing Zheng , Yichun Qu , Zhiyao Sun , Guanghui An . Case Design of Course Ideological and Political Education in Chemical Experiment Safety: the Safe Use of Common Laboratory Instruments and Glassware. University Chemistry, 2024, 39(2): 242-247. doi: 10.3866/PKU.DXHX202309061
17. [17]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
18. [18]
  Ziliang KANG , Jiamin ZHANG , Hong AN , Xiaohua LIU , Yang CHEN , Jinping LI , Libo LI . Preparation and water adsorption properties of CaCl₂@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282
19. [19]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . Insights into the greatly improved catalytic performance of N-doped BiOBr for CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-0. doi: 10.1016/j.actphy.2025.100055
20. [20]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435

Get Citation

PDF

XML

Metrics

PDF Downloads(189)
Abstract views(727)
HTML views(47)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Mass Fraction of CeO2 on Leaching Behavior of Aluminoborosilicate Glass

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Mass Fraction of CeO₂ on Leaching Behavior of Aluminoborosilicate Glass