Citation: LI Peng, DING Xin-Geng, YANG Hui, SU Wei, DOU Tian-Jun. Effect of Mass Fraction of CeO2 on Leaching Behavior of Aluminoborosilicate Glass[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 709-714. doi: 10.3969/j.issn.1001-4861.2013.00.110
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Phase change in aluminoborosilicate glass and effect on leaching behavior were studied with different mass fraction of CeO2 via characterization methods of XRD, XPS, SEM and ICP-MS. The results showed that: In glass network structure the molar ratio of quadrivalence Ce and trivalent Ce was 9.25:1. And when mass fraction of CeO2 met or exceeded 7%, the cerianite began to be precipitated in glass. With mass fraction of CeO2 increasing, rCe of glass decreased at first and then increased in 1 day, and showed trend to decrease in 28 day. However, in the same mass fraction of CeO2, rCe gradually decreased with the prolongation of leaching time. And rCe of the glass sample bE stabilized lower than 4×10-6 g·m-2·d-1 after 7 day with 9wt% CeO2. The leaching behavior was excellent. Hence, controlling CeO2 precipitated within a certain range could be superior to completely dissolving one in glass on leaching behavior.
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Keywords:
- CeO2;leaching behavior;vitrification
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