Citation: XU Min, ZHOU Ai-Jü, LI Dong-Xiang, HUANG Hui-Yi, XIE Guo-Biao, DONG Wen. Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[Mn^ⅡMn₆^Ⅲ(teaH)₃(tea)₃(NCS)₆]}_n[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 826-830. doi: 10.3969/j.issn.1001-4861.2013.00.109 shu

Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[Mn^ⅡMn₆^Ⅲ(teaH)₃(tea)₃(NCS)₆]}_n

1.
School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China

Received Date: 11 September 2012
Available Online: 1 December 2012
Fund Project: 国家自然科学基金(No.21001032)资助项目。 (No.21001032)

A mixed-valence heptanuclear manganese complex {K[Mn^ⅡMn₆^Ⅲ(teaH)₃(tea)₃(NCS)₆]}_n (1) (teaH₃=triethanolamine) has been synthesized by the reaction of MnCl₂ (or Mn(NO₃)₂) with mixed ligands of teaH₃ and KSCN and structurally characterized by IR, elemental analysis, single crystal X-ray diffraction. The anion of 1 consists of a Mn7 unit and compose wheel structure, in which a central Mn^Ⅱ ion surrounded by six Mn^Ⅲ ions. The result based on direct current magnetic susceptibility showed 1 a spin ground state S=29/2. The magnetic behavior of 1 indicates a ferromagnetic interaction between the high-spin Mn^Ⅱ and Mn^Ⅲ ions. CCDC: 843079.
- manganese complex;triethanolamine;crystal structure;mangetic property
1. [1]
  [1] Ruiz E, Cauchy T, Cano J, et al. J. Am. Chem. Soc., 2008, 130:7420-7426
2. [2]
  [2] Wittick L M, Jones L F, Jensen P. Dalton Trans., 2006, 1534-1543
3. [3]
  [3] Murugesu M, Wernsdorfer W, Abboud K A, et al. Polyhedron, 2005,24:2894-2899
4. [4]
  [4] Stamatatos T C, Abboud K A, Wernsdorfer W, et al. Polyhedron, 2007,26:2095-2100
5. [5]
  [5] Ge C H, Ni Z H, Liu C M, et al. Inorg. Chem. Commun., 2008,11:675-677
6. [6]
  [6] Masello A, Murugesu M, Abboud K A, et al. Polyhedron, 2007,26:2276-2280
7. [7]
  [7] Khanna S N, Rao B K, Jena P, et al. Chem. Phy. Lett., 2003,378:374-379
8. [8]
  [8] Abbati G L, Cornia A, Fabretti A C, et al. Inorg. Chem., 1998,37:3759-3766
9. [9]
  [9] Murugesu M, Mishra A, Wernsdorfer W, et al. Polyhedron, 2006,25:613-625
10. [10]
  [10] Saalfrank R W, Nakajima T, Mooren N, et al. Eur. J. Inorg. Chem., 2005,1149-1153
11. [11]
  [11] Pilawa B, Kelemen M T, Wanka S. Europhys. Lett., 1998,43: 7-12
12. [12]
  [12] Koizumi S, Nihei M, Oshio H. Inorg. Chem., 2005,44:1208-1210
13. [13]
  [13] Bolcar M A, Aubin S M J, Folting K, et al. Chem. Commun., 1997,1485-1486
14. [14]
  [14] Abbati G L, Cornia A, Fabretti A C, et al. Inorg. Chem., 1998,37:1430-1431
15. [15]
  [15] Murugesu M, Habrych M, Wernsdorfer W, et al. J. Am. Chem. Soc., 2004,126:4766-4767
16. [16]
  [16] Stamatatos T C, Foguet-Albiol D, Poole K M, et al. Inorg. Chem., 2009,48:9831-9845
17. [17]
  [17] Stamatatos T C, Poole K M, Foguet-Albiol D, et al. Inorg. Chem., 2008,47:6593-6595
18. [18]
  [18] Lu Z L, Fan C H. Inorg. Chem. Commun., 2011,14:1329-1332
19. [19]
  [19] Sheldrick G M. SADABS 2.05, University of Gottingen, 2000.
20. [20]
  [20] SHELXTL 6.10, Bruker Analytical Instrumentation, Madison, Wisconsin, USA, 2000.
21. [21]
  [21] Liu W, Thorp H H. Inorg. Chem., 1993,32:4102-4105
22. [22]
  [22] Brown I D, Altermatt D. Acta. Crystallogr., Sect. B, 1985, 41:244-247
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
3. [3]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
6. [6]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
7. [7]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
8. [8]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
9. [9]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
10. [10]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
11. [11]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
12. [12]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
13. [13]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
14. [14]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
15. [15]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
16. [16]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
17. [17]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
18. [18]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
19. [19]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
20. [20]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(456)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[MnⅡMn6Ⅲ(teaH)3(tea)3(NCS)6]}n

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[Mn^ⅡMn₆^Ⅲ(teaH)₃(tea)₃(NCS)₆]}_n