Citation: XU Min, ZHOU Ai-Jü, LI Dong-Xiang, HUANG Hui-Yi, XIE Guo-Biao, DONG Wen. Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[Mn^ⅡMn₆^Ⅲ(teaH)₃(tea)₃(NCS)₆]}_n[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 826-830. doi: 10.3969/j.issn.1001-4861.2013.00.109 shu

Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[Mn^ⅡMn₆^Ⅲ(teaH)₃(tea)₃(NCS)₆]}_n

1.
School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China

Received Date: 11 September 2012
Available Online: 1 December 2012
Fund Project: 国家自然科学基金(No.21001032)资助项目。 (No.21001032)

A mixed-valence heptanuclear manganese complex {K[Mn^ⅡMn₆^Ⅲ(teaH)₃(tea)₃(NCS)₆]}_n (1) (teaH₃=triethanolamine) has been synthesized by the reaction of MnCl₂ (or Mn(NO₃)₂) with mixed ligands of teaH₃ and KSCN and structurally characterized by IR, elemental analysis, single crystal X-ray diffraction. The anion of 1 consists of a Mn7 unit and compose wheel structure, in which a central Mn^Ⅱ ion surrounded by six Mn^Ⅲ ions. The result based on direct current magnetic susceptibility showed 1 a spin ground state S=29/2. The magnetic behavior of 1 indicates a ferromagnetic interaction between the high-spin Mn^Ⅱ and Mn^Ⅲ ions. CCDC: 843079.
- manganese complex;triethanolamine;crystal structure;mangetic property
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[MnⅡMn6Ⅲ(teaH)3(tea)3(NCS)6]}n

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Complex with Triethanolamine and Thiocyanate {K[Mn^ⅡMn₆^Ⅲ(teaH)₃(tea)₃(NCS)₆]}_n