Citation: JIN Jing, LIU Yong-Hua, LIU Jia-Cao, NIU Shu-Yun. Synthesis, Structure and Comparison of Photo-electric Properties of Co(Ⅱ) Complexes with Benzoic Derivatives Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 455-464. doi: 10.3969/j.issn.1001-4861.2013.00.108 shu

Synthesis, Structure and Comparison of Photo-electric Properties of Co(Ⅱ) Complexes with Benzoic Derivatives Ligand

1.
School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Received Date: 21 June 2012
Available Online: 22 November 2012
Fund Project: 国家自然科学基金(No.21133005) (No.21133005)辽宁省教育厅项目(No.2011193)资助项目。 (No.2011193)

Four Co(Ⅱ) complexes [Co(btec)_0.5(pz)₂]_n (1), [Co(btec)_0.5(pz)₃]_n (2), [Co(phen)(Hbtc)(H₃btc) (H₂O)₂]·3H₂O (3), [Co(Imh)₂(anis)₂(H₂O)] (4), (H₄btec=1,2,4,5-benzenetetracarboxylic acid, pz=pyrazole, H₃btc=1,3,5-benzene-tricarboxylic acid, phen=1,10-phenanthroline, Imh=imidazole, Hanis=p-anisic acid) were synthesized by hydrothermal method. They were characterized by X-ray single crystal diffraction, IR, elemental analysis, UV-Vis-NIR diffuse reflection spectrum and surface photovoltage spectroscopy (SPS). The structural analyses indicate that 1 is a Co(Ⅱ) polymer with 2D structure. The Co(Ⅱ) ion is four-coordinate in 1; the ones in 2～4 are both six-coordinate. 2 possesses 1D structure, connected by hydrogen bonds into 2D layer. 3 and 4 are molecular complexes, which are networked into 3D and 2D structures by hydrogen bonds, respectively. Four complexes all exhibit obvious surface photovoltage responses within 300～600 nm in SPS, which indicates that they possess certain photo-electric conversion properties. The influences of structure, dimension of complex and coordination micro-environment of center metal ion on the SPS were discussed emphatically. The energy band theory of semiconductor and crystal field theory are combined to analyze and assign SPS response bands. CCDC: 883535, 1; 883536, 2; 883537, 3; 883538, 4.
- Co(Ⅱ) complexe;synthesis;crystal structure;hydrogen bond;surface photoelectric property
1. [1]
  [1] Ma L F, Wang L Y, Lu D H, et al. Cryst. Growth Des., 2009, 9:1741-1749
2. [2]
  [2] Jia H P, Li W, Ju Z F, et al. J. Inorg. Chem. Commun., 2007, 10:265-68
3. [3]
  [3] Fabelo O, Pasán J, Caadillas-Delgado L, et al. Inorg. Chem., 2008,47:8053-8061
4. [4]
  [4] Wang R, Zhang J, Li L. Inorg. Chem., 2009,48:7194-7200
5. [5]
  [5] Shandhya R D, Anantha L P V, Kamala P V, et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1245-1250
6. [6]
  [6] TANG Yun-Zhi(唐云志), YANG Yan-Ming(杨燕明), CAO Zan(曹赞), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1265-1270
7. [7]
  [7] Ingleson M, Fan H, Pink M, et al. J. Am. Chem. Soc., 2006, 128:1804-1805
8. [8]
  [8] Vimal K P M, Radhakrishnan P K. Polyhedron, 2010,29: 2335-2344
9. [9]
  [9] Cao R, Müller P, Lippard S J. J. Am. Chem. Soc., 2010,132: 17366-17369
10. [10]
  [10] Ma L F, Wang L Y, Wang Y Y, et al. Inorg. Chem., 2009, 48:915-924
11. [11]
  [11] Hao X, Parkin S, Brock C P. Acta Cryst., 2005,B61:675-688
12. [12]
  [12] Li J M, Li J Z, Zhang H Q, et al. Inorg. Chem. Commun., 2010,13:573-576
13. [13]
  [13] Sun W H, Hao P, Zhang S, et al. Organometallics, 2007,26: 2720-2734
14. [14]
  [14] Thomas R M, Widger P C B, Ahmed S M, et al. J. Am. Chem. Soc., 2010,132:16520-16525
15. [15]
  [15] Manna S C, Zangrando E, Ribas J, et al. Inorg. Chem. Acta, 2008,361:411-416
16. [16]
  [16] Zhuang R R, Jian F F, Wang K F. J. Mol. Struct., 2009,938: 254-258
17. [17]
  [17] Yang P, Yang Y, Zhang C, et al. Inorg. Chim. Acta, 2009, 362:89-96
18. [18]
  [18] Liu Y J, Huang J S, Chui S S Y, et al. Inorg. Chem., 2008, 47:11514-11518
19. [19]
  [19] Miodragovic D U, Mitic D M, Miodragovic Z M, et al. Inorg. Chim. Acta, 2008,361:86-94
20. [20]
  [20] Zhang L, Niu S Y, Jin J, et al. Inorg. Chim. Acta, 2009,362: 1448-1454
21. [21]
  [21] Li L, Niu S Y, Li D, et al. Inorg. Chem. Commun., 2011,14: 993-996
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
4. [4]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
8. [8]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
9. [9]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
10. [10]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
11. [11]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
12. [12]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
13. [13]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
14. [14]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
15. [15]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
16. [16]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
17. [17]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
18. [18]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
19. [19]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
20. [20]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003

Get Citation

PDF

XML

Metrics

PDF Downloads(509)
Abstract views(633)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142