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Citation: HU Zhi-Li, LI Chang-Sheng, TANG Hua, LI Hong-Ping, LIANG Jia-Qing, ZHANG Yi, CHEN Shuai. Investigation of W Doped NbSe2 and Tribology Characteristic of Its Correlated Copper Base Composites[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 767-773. doi: 10.3969/j.issn.1001-4861.2013.00.101 shu

Investigation of W Doped NbSe2 and Tribology Characteristic of Its Correlated Copper Base Composites

  • 1.

    1 School of Mechanical Engineering, Jiangsu University, Key Laboratory of Tribology of Jiangsu Province, Zhenjiang, Jiangsu 212013, China;

  • Received Date: 4 October 2012
    Available Online: 18 November 2012

    Fund Project: 江苏省自然科学基金(No.BK2011534) (No.BK2011534)兰州化学物理所固体润滑国家重点实验室开放基金(No.20101008) (No.20101008)江苏省摩擦学重点实验室开放 基金(No.kjsmcx1005) (No.kjsmcx1005)江苏大学高级人才启动基金(No.09JDG009)资助项目。 (No.09JDG009)

  • In this paper, W doped NbSe2 was prepared by solid phase synthesis method. Then Nb1-xWxSe2 copper base composites were synthesized by powder metallurgy method with a series of Nb1 -xWxSe2 concentration, using Nb1-xWxSe2 as solid lubrication phase and Cu as matrix phase. Phase identification and microstructure analysis of the resultant samples were carried out by XRD, SEM and TEM. The electrical resistance, hardness, and density of the block samples was measured with resistivity detector, electronic material testing machine and drainage method, respectively. The friction and wear performance was evaluated with friction and wear testing machine. It is found that the microstructure of Nb1-xWxSe2 changes from micron hexagonal sheet to the mixed of nanometer sheet and nanobelts with increasing W doping ratio. Whereas, there is nearly no influence on the resistance. Further, the resistivity of Nb1-xWxSe2/Cu base composites gradually becomes stronger as increasing the concentration of Nb1-xWxSe2, however, the friction coefficient exhibits different values. When x=0 and the percentage of Nb1-x WxSe2 is 10%, the NbSe2/Cu base composite presents the best friction and wear properties, i.e., the friction coefficient is 0.15 and wear scar is smooth and narrow. When x=3% and the percentage of Nb1-xWxSe2 is 5%, the Nb0.97W0.03Se2/Cu base composite presents the best friction and wear properties, i.e., the friction coefficient is 0.17 and wear scar is smoother and shallow. Since both nanobelts and nanosheet are existed in Nb0.97W0.03Se2 and they are intertwined, in the composites the nanosheets play an important role in the lubrication film and the winding nanobelts, which similar to the grass and branches of bird′s nest, enhance its toughening effect. Hence, both the mechanical and tribological properties of the composites are improved.
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    1. [1]

      [1] Tenne R, Margulis L, Genut M, et al. Nature, 1992,360:444 -446

    2. [2]

      [2] Rothschild A, Sloan J, Tenne R. J. Am. Chem. Soc., 2000, 122:5169-5179

    3. [3]

      [3] Feldman Y, Wasserman E, Srolovitz D J, et al. Science, 1995, 267:222-225

    4. [4]

      [4] Bilas P, Romana L Bade F, et al. Tribol. Lett., 2009,34(1): 41-48

    5. [5]

      [5] Li C S, Hao M D, Liu Y Q, et al. 2008 3rd Ieee Int. Confer. Nano/Micro Eng. Mol. Sys., 2008,1-3:324-328

    6. [6]

      [6] Suderow H, Tissen V G, Brison J P, et al. Phys. Rev. Lett., 2005,95(11):117006-117006

    7. [7]

      [7] Rapoport L, Fleischer N, Tenne R. Adv. Mater., 2003,15: 651-655

    8. [8]

      [8] Papoport L, Lvovsky M,Lapsker I, et al. Adv. Eng. Mater., 2001,3:71-75

    9. [9]

      [9] CHEN Wei-Xiang(陈卫祥), TU Jiang-Ping(涂江平), MA Xiao -Chun(马晓春). Chin. J. Tribol.(Mocaxue Xuebao), 2003,23 (1):76-80

    10. [10]

      [10] CAO Ke-Sheng(曹可生), LI Chang-Sheng(李长生), LI Song-Tian(李松田), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,11(27):2150-2156

    11. [11]

      [11] Pol S V, Pol V G, Moreno G, et al. J. Phys. Chem. C, 2008, 112:5356-5360

    12. [12]

      [12] Parilla P, Dillon A C, Parkinson B, et al. J. Phys. Chem. B, 2004,08:197-207

    13. [13]

      [13] TANG Guo-Gang(唐国钢), LI Chang-Sheng(李长生), TANG Hua(唐华), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(7):1368-1372

    14. [14]

      [14] JIN Yue(晋跃), LI Chang-Sheng(李长生), WANG Mu-Ju(王 木菊), et al. Chin. J. Vacauum Sci. Technol.(Zhenkong Kexue Yu Jishu Xuebao), 2011,31(5):646-651

    15. [15]

      [15] LI Guo-Wei(李国伟), JIN Yue(晋跃), LI Chang-Sheng(李长 生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(8):1472-1476

    16. [16]

      [16] Prabu M, Selvasekarapandian S, Kulkarni A R, et al. Trans. Nonferrous Met. Soc. China, 2012(22):342-347

    17. [17]

      [17] YANG Meng-Meng(杨萌萌), TU Hai-Lin(屠海令), ZHANG Xin-Qiang(张心强), et al. Chin. J. Rare Metals(Xiyou Jinshu Xuebao), 2012,36(2):292-296

    18. [18]

      [18] Chung S Y, Bloking J T, Chiang Y M. Nature Mater., 2002, 1:123-128

    19. [19]

      [19] Ni J F, Zhou H H, Chen J T, et al. Mater. Lett., 2002,59: 2361-2365

    20. [20]

      [20] Shi S Q, Liu L J, Ouyang C Y, et al. Phys. Rev. B, 2003,68: 195108-195112

    21. [21]

      [21] FENG Liang-Rong(冯良荣), LÜ Shao-Jie(吕绍洁), QIU Fa-Li(邱发礼). Acta Chim. Sin.(Huaxue Xuebao), 2002,60(3): 463-467

    22. [22]

      [22] Choi W, Termin A, Hoffmann M R. J. Phys. Chem., 1994, 98:13669-13679

    23. [23]

      [23] Iwasaki M, Hara M, Kawada H, et al. J. Colloid Interface Sci., 2000,224(1):202-204

    24. [24]

      [24] YUE Lin-Hai(岳林海), SHUI Miao(水淼), XU Zhu-De(徐铸 德), et al. J. Zhejiang Univ.: Sci. Ed.(Zhejiang Daxue Xuebao: Lixueban), 2000,27(1):69-74

    25. [25]

      [25] Michael Gratzel, Russell F Howe. J. Phys. Chem., 1990,94: 2566-2572

    26. [26]

      [26] PENG Zhi-Jian(彭志坚), YANG Yi-Yong(杨义勇), WANG Cheng-Biao(王成彪), et al. Acta Metellu. Sin.(Jinshu Xuebao), 2008,44(10):1265-1270

    27. [27]

      [27] Balzer B, Hagemeister M, Kocher P, et al. J. Am. Ceram. Soc., 2004,87:1932-1938

    28. [28]

      [28] Begum S, Hashmi M S J. J. Mater. Process Technol., 2005, 167:542-548

    29. [29]

      [29] WANG Qing-Feng(万庆峰), WANG De-Zhi(王德志), ZHAO Bing(赵兵), et al. Transact. Meterals Heat Treat.(Cailiao Rechuli Xuebao), 2009,30(1):80-83

    30. [30]

      [30] He D H, Manory R. Wear, 2001,249:626-636

    31. [31]

      [31] Kato H, Takama M, Iwai Y. Wear, 2003,255:573-578

    32. [32]

      [32] Rajora O S, Curzon A E. Phys. Status Solidi (A), 1986,97:65 -76

    33. [33]

      [33] Voorhoeve-Van D B J M. J. Less-common Metals, 1972,26: 399-402

    34. [34]

      [34] Freund J, Wortmann G, Paulus W, et al. J. Alloys Compd., 1992,187:157-169

    35. [35]

      [35] Tang H, Cao K S, Wu Q, et al. Cryst. Res. Technol., 2011, 46(2):195-200

    36. [36]

      [36] LI Wen-Jing(李文静), LEI Lei(雷蕾), LUO Cong(罗聪), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012, 28(8):1587-1592

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