Advanced Search

Citation: HU Zhi-Li, LI Chang-Sheng, TANG Hua, LI Hong-Ping, LIANG Jia-Qing, ZHANG Yi, CHEN Shuai. Investigation of W Doped NbSe2 and Tribology Characteristic of Its Correlated Copper Base Composites[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 767-773. doi: 10.3969/j.issn.1001-4861.2013.00.101 shu

Investigation of W Doped NbSe2 and Tribology Characteristic of Its Correlated Copper Base Composites

  • 1.

    1 School of Mechanical Engineering, Jiangsu University, Key Laboratory of Tribology of Jiangsu Province, Zhenjiang, Jiangsu 212013, China;

  • Received Date: 4 October 2012
    Available Online: 18 November 2012

    Fund Project: 江苏省自然科学基金(No.BK2011534) (No.BK2011534)兰州化学物理所固体润滑国家重点实验室开放基金(No.20101008) (No.20101008)江苏省摩擦学重点实验室开放 基金(No.kjsmcx1005) (No.kjsmcx1005)江苏大学高级人才启动基金(No.09JDG009)资助项目。 (No.09JDG009)

  • In this paper, W doped NbSe2 was prepared by solid phase synthesis method. Then Nb1-xWxSe2 copper base composites were synthesized by powder metallurgy method with a series of Nb1 -xWxSe2 concentration, using Nb1-xWxSe2 as solid lubrication phase and Cu as matrix phase. Phase identification and microstructure analysis of the resultant samples were carried out by XRD, SEM and TEM. The electrical resistance, hardness, and density of the block samples was measured with resistivity detector, electronic material testing machine and drainage method, respectively. The friction and wear performance was evaluated with friction and wear testing machine. It is found that the microstructure of Nb1-xWxSe2 changes from micron hexagonal sheet to the mixed of nanometer sheet and nanobelts with increasing W doping ratio. Whereas, there is nearly no influence on the resistance. Further, the resistivity of Nb1-xWxSe2/Cu base composites gradually becomes stronger as increasing the concentration of Nb1-xWxSe2, however, the friction coefficient exhibits different values. When x=0 and the percentage of Nb1-x WxSe2 is 10%, the NbSe2/Cu base composite presents the best friction and wear properties, i.e., the friction coefficient is 0.15 and wear scar is smooth and narrow. When x=3% and the percentage of Nb1-xWxSe2 is 5%, the Nb0.97W0.03Se2/Cu base composite presents the best friction and wear properties, i.e., the friction coefficient is 0.17 and wear scar is smoother and shallow. Since both nanobelts and nanosheet are existed in Nb0.97W0.03Se2 and they are intertwined, in the composites the nanosheets play an important role in the lubrication film and the winding nanobelts, which similar to the grass and branches of bird′s nest, enhance its toughening effect. Hence, both the mechanical and tribological properties of the composites are improved.
  • 加载中
    1. [1]

      [1] Tenne R, Margulis L, Genut M, et al. Nature, 1992,360:444 -446

    2. [2]

      [2] Rothschild A, Sloan J, Tenne R. J. Am. Chem. Soc., 2000, 122:5169-5179

    3. [3]

      [3] Feldman Y, Wasserman E, Srolovitz D J, et al. Science, 1995, 267:222-225

    4. [4]

      [4] Bilas P, Romana L Bade F, et al. Tribol. Lett., 2009,34(1): 41-48

    5. [5]

      [5] Li C S, Hao M D, Liu Y Q, et al. 2008 3rd Ieee Int. Confer. Nano/Micro Eng. Mol. Sys., 2008,1-3:324-328

    6. [6]

      [6] Suderow H, Tissen V G, Brison J P, et al. Phys. Rev. Lett., 2005,95(11):117006-117006

    7. [7]

      [7] Rapoport L, Fleischer N, Tenne R. Adv. Mater., 2003,15: 651-655

    8. [8]

      [8] Papoport L, Lvovsky M,Lapsker I, et al. Adv. Eng. Mater., 2001,3:71-75

    9. [9]

      [9] CHEN Wei-Xiang(陈卫祥), TU Jiang-Ping(涂江平), MA Xiao -Chun(马晓春). Chin. J. Tribol.(Mocaxue Xuebao), 2003,23 (1):76-80

    10. [10]

      [10] CAO Ke-Sheng(曹可生), LI Chang-Sheng(李长生), LI Song-Tian(李松田), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,11(27):2150-2156

    11. [11]

      [11] Pol S V, Pol V G, Moreno G, et al. J. Phys. Chem. C, 2008, 112:5356-5360

    12. [12]

      [12] Parilla P, Dillon A C, Parkinson B, et al. J. Phys. Chem. B, 2004,08:197-207

    13. [13]

      [13] TANG Guo-Gang(唐国钢), LI Chang-Sheng(李长生), TANG Hua(唐华), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(7):1368-1372

    14. [14]

      [14] JIN Yue(晋跃), LI Chang-Sheng(李长生), WANG Mu-Ju(王 木菊), et al. Chin. J. Vacauum Sci. Technol.(Zhenkong Kexue Yu Jishu Xuebao), 2011,31(5):646-651

    15. [15]

      [15] LI Guo-Wei(李国伟), JIN Yue(晋跃), LI Chang-Sheng(李长 生), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(8):1472-1476

    16. [16]

      [16] Prabu M, Selvasekarapandian S, Kulkarni A R, et al. Trans. Nonferrous Met. Soc. China, 2012(22):342-347

    17. [17]

      [17] YANG Meng-Meng(杨萌萌), TU Hai-Lin(屠海令), ZHANG Xin-Qiang(张心强), et al. Chin. J. Rare Metals(Xiyou Jinshu Xuebao), 2012,36(2):292-296

    18. [18]

      [18] Chung S Y, Bloking J T, Chiang Y M. Nature Mater., 2002, 1:123-128

    19. [19]

      [19] Ni J F, Zhou H H, Chen J T, et al. Mater. Lett., 2002,59: 2361-2365

    20. [20]

      [20] Shi S Q, Liu L J, Ouyang C Y, et al. Phys. Rev. B, 2003,68: 195108-195112

    21. [21]

      [21] FENG Liang-Rong(冯良荣), LÜ Shao-Jie(吕绍洁), QIU Fa-Li(邱发礼). Acta Chim. Sin.(Huaxue Xuebao), 2002,60(3): 463-467

    22. [22]

      [22] Choi W, Termin A, Hoffmann M R. J. Phys. Chem., 1994, 98:13669-13679

    23. [23]

      [23] Iwasaki M, Hara M, Kawada H, et al. J. Colloid Interface Sci., 2000,224(1):202-204

    24. [24]

      [24] YUE Lin-Hai(岳林海), SHUI Miao(水淼), XU Zhu-De(徐铸 德), et al. J. Zhejiang Univ.: Sci. Ed.(Zhejiang Daxue Xuebao: Lixueban), 2000,27(1):69-74

    25. [25]

      [25] Michael Gratzel, Russell F Howe. J. Phys. Chem., 1990,94: 2566-2572

    26. [26]

      [26] PENG Zhi-Jian(彭志坚), YANG Yi-Yong(杨义勇), WANG Cheng-Biao(王成彪), et al. Acta Metellu. Sin.(Jinshu Xuebao), 2008,44(10):1265-1270

    27. [27]

      [27] Balzer B, Hagemeister M, Kocher P, et al. J. Am. Ceram. Soc., 2004,87:1932-1938

    28. [28]

      [28] Begum S, Hashmi M S J. J. Mater. Process Technol., 2005, 167:542-548

    29. [29]

      [29] WANG Qing-Feng(万庆峰), WANG De-Zhi(王德志), ZHAO Bing(赵兵), et al. Transact. Meterals Heat Treat.(Cailiao Rechuli Xuebao), 2009,30(1):80-83

    30. [30]

      [30] He D H, Manory R. Wear, 2001,249:626-636

    31. [31]

      [31] Kato H, Takama M, Iwai Y. Wear, 2003,255:573-578

    32. [32]

      [32] Rajora O S, Curzon A E. Phys. Status Solidi (A), 1986,97:65 -76

    33. [33]

      [33] Voorhoeve-Van D B J M. J. Less-common Metals, 1972,26: 399-402

    34. [34]

      [34] Freund J, Wortmann G, Paulus W, et al. J. Alloys Compd., 1992,187:157-169

    35. [35]

      [35] Tang H, Cao K S, Wu Q, et al. Cryst. Res. Technol., 2011, 46(2):195-200

    36. [36]

      [36] LI Wen-Jing(李文静), LEI Lei(雷蕾), LUO Cong(罗聪), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012, 28(8):1587-1592

  • 加载中
    1. [1]

      Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342

    2. [2]

      Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS2 nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065

    3. [3]

      Xin Zhou ,  Zhi Zhang ,  Yun Yang ,  Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi2MoO6 Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008

    4. [4]

      Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253

    5. [5]

      Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    6. [6]

      Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

    7. [7]

      Jinyi Sun ,  Lin Ma ,  Yanjie Xi ,  Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094

    8. [8]

      Meng Lin ,  Hanrui Chen ,  Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117

    9. [9]

      Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO2 cycloaddition over W18O49/NH2-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349

    10. [10]

      Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs2W3O10. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957

    11. [11]

      Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404

    12. [12]

      Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108

    13. [13]

      Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473

    14. [14]

      Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

    15. [15]

      Doudou Qin ,  Junyang Ding ,  Chu Liang ,  Qian Liu ,  Ligang Feng ,  Yang Luo ,  Guangzhi Hu ,  Jun Luo ,  Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034

    16. [16]

      Qin Hu ,  Liuyun Chen ,  Xinling Xie ,  Zuzeng Qin ,  Hongbing Ji ,  Tongming Su . Ni掺杂构建电子桥及激活MoS2惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024

    17. [17]

      Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    18. [18]

      Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu2O/Bi2MoO6 Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435

    19. [19]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    20. [20]

      Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

Get Citation
PDF
XML
Metrics
  • PDF Downloads(347)
  • Abstract views(752)
  • HTML views(71)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return