Citation: ZHANG Fu-Xing, WANG Jian-Qiu, KUANG Dai-Zhi, FENG Yong-Lan, XU Zhi-Feng, YU Jiang-Xi. Synthesis, Crystal Structure and Properties of Novel Dicyclohexyltin Quinoline-2-Carboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 537-543. doi: 10.3969/j.issn.1001-4861.2013.00.100 shu

Synthesis, Crystal Structure and Properties of Novel Dicyclohexyltin Quinoline-2-Carboxylate

1.
Department of Chemistry and Material Science, Hengyang Normal University; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province; Hengyang, Hunan 421008, China

Received Date: 14 May 2012
Available Online: 8 October 2012
Fund Project: 湖南省高校创新平台开放基金项目(12K124) (12K124)湖南省教育厅重点项目(10K010) (10K010)湖南省自然科学基金项目(11JJ3021) (11JJ3021)

Dicyclohexyltin quinoline-2-carboxylate [Cy₄Sn₂(μ-OH)₂(C₉NH₆CO₂)₂]·2[Cy₂Sn(C₉NH₆CO₂)₂]·2H₂O was synthesised by the reaction of tricyclohexyltin hydroxide with quinolinecarboxylic acid. The crystal structures have been determined by X-ray diffraction. It belongs to triclinic system, space group P1. In the unit cell, there are two different kinds of composition and structure of the dicyclohexyltin quinoline-2-carboxylate complex molecules. some of the tin atoms are five-coordination distorted tigonal bipyramidal structure, others are six coordinated distorted octahedron. The study on the title complex has been performed with quantum chemistry calculation. The stabilities, the orbital energies and composition characteristics of some frontier molecular orbitals of the complex have been investigated.The thermal stability,electrochemical properties and, photoluminescent property of complexes have been investigated. CCDC: 865659.
- dicyclohexyltin quinoline-2-carboxylate;crystal structure;synthesis;quantum chemistry
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沈阳化工大学材料科学与工程学院沈阳 110142