Citation: ZHANG Fu-Xing, WANG Jian-Qiu, KUANG Dai-Zhi, FENG Yong-Lan, XU Zhi-Feng, YU Jiang-Xi. Synthesis, Crystal Structure and Properties of Novel Dicyclohexyltin Quinoline-2-Carboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 537-543. doi: 10.3969/j.issn.1001-4861.2013.00.100 shu

Synthesis, Crystal Structure and Properties of Novel Dicyclohexyltin Quinoline-2-Carboxylate

1.
Department of Chemistry and Material Science, Hengyang Normal University; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province; Hengyang, Hunan 421008, China

Received Date: 14 May 2012
Available Online: 8 October 2012
Fund Project: 湖南省高校创新平台开放基金项目(12K124) (12K124)湖南省教育厅重点项目(10K010) (10K010)湖南省自然科学基金项目(11JJ3021) (11JJ3021)

Dicyclohexyltin quinoline-2-carboxylate [Cy₄Sn₂(μ-OH)₂(C₉NH₆CO₂)₂]·2[Cy₂Sn(C₉NH₆CO₂)₂]·2H₂O was synthesised by the reaction of tricyclohexyltin hydroxide with quinolinecarboxylic acid. The crystal structures have been determined by X-ray diffraction. It belongs to triclinic system, space group P1. In the unit cell, there are two different kinds of composition and structure of the dicyclohexyltin quinoline-2-carboxylate complex molecules. some of the tin atoms are five-coordination distorted tigonal bipyramidal structure, others are six coordinated distorted octahedron. The study on the title complex has been performed with quantum chemistry calculation. The stabilities, the orbital energies and composition characteristics of some frontier molecular orbitals of the complex have been investigated.The thermal stability,electrochemical properties and, photoluminescent property of complexes have been investigated. CCDC: 865659.
- dicyclohexyltin quinoline-2-carboxylate;crystal structure;synthesis;quantum chemistry
1. [1]
  [1] Chandrasekhar V, Thirumoorthi R, Metre R K, et al. J. Organomet. Chem., 2011,696:600-606
2. [2]
  [2] Effendy, Marchetti F, Marinelli A, et al. J. Inorg. Chem. Acta, 2011,366:388-393
3. [3]
  [3] Hanif M, Hussain M, Ali S, et al. Polyhedron, 2010,29:613-619
4. [4]
  [4] ZHANG Xiao-Yan(张晓燕), YANG Guang(杨光), ZHANG Jun(张俊), et al. Chem. J. Chinsese Univ. (Gaodeng Xuexiao Huaxue Xuebao), 2010,31(6):1162-1166
5. [5]
  [5] Siddiqi Z A, Shahid M, Kumar S, et al. J. Organomet. Chem., 2009,694:3768-3774
6. [6]
  [6] Ruan B F, Tian Y U, Zhou H P, et al. Inorg. Chim. Acta, 2011,365:302-308
7. [7]
  [7] YIN Han-Dong(尹汉东), WANG Chuan-Hua(王传华), WANG Yong (王勇), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2002,18(2):201-204
8. [8]
  [8] YAN Wen-Hua(闫文华), KANG Wan-Li(康万利), LI Jin-Huan(李金环). Chinese J. Appl. Chem.(Yingyong Huaxue), 2007,24(6):660-664
9. [9]
  [9] Shujha S, Shah A, Rehman Z U, et al. Eur. J. Med. Chem., 2010,45:2902-2911
10. [10]
  [10] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), WANG Jian-Qiu(王剑秋), et al. Chinese J. Org. Chem. (Youji Huaxue), 2008,28(8):1457-1461
11. [11]
  [11] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), WANG Jian-Qiu(王剑秋), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22(7):1321-1326
12. [12]
  [12] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), WANG Jian-Qiu(王剑秋), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22(1):7-12
13. [13]
  [13] CHEN Zhi-Min(陈志敏), ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22(3):488-502
14. [14]
  [14] WANG Jian-Qiu(王剑秋), ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004,20(12):1489-1492
15. [15]
  [15] YIN Han-Dong(尹汉东), WANG Chuan-Hua(王传华), MA Chun-Lin(马春林), et al. Chem. J. Chinsese Univ.(Gaodeng Xuexiao Huaxue Xuebao), 2003,24(6):958-963
16. [16]
  [16] YU Jiang-Xi(庾江喜), FENG Yong-Lan(冯泳兰), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(2):279-286
17. [17]
  [17] JIANG Wu-Jiu(蒋伍玖), YANG Nian-Fa(阳年发), KUANG Dai-Zhi(邝代治), et al. Chinese J. Struct. Chem.(Jiegou Huaxue), 2011,30(9):1327-1311
18. [18]
  [18] FENG Yong-Lan (冯泳兰), YU Jiang-Xi(庾江喜), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,27(9):1793-1797
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沈阳化工大学材料科学与工程学院沈阳 110142