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Citation: WEI Xia, ZHOU Yuan-Lin, LI Yin-Tao, CHENG Ya-Fei. A Multi-quaternary Ammonium Induced Synthesis of Bi2WO6 Sheet-Like Cluster Microspheres and Photoluminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 583-588. doi: 10.3969/j.issn.1001-4861.2013.00.097 shu

A Multi-quaternary Ammonium Induced Synthesis of Bi2WO6 Sheet-Like Cluster Microspheres and Photoluminescence Properties

  • 1.

    1. State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China;

  • Received Date: 12 October 2012
    Available Online: 21 November 2012

    Fund Project: 国家自然科学基金委员会-中国工程物理研究院联合基金(No.11176026)资助项目。 (No.11176026)

  • By using a Gemini quaternary ammonium as surfactant synthesized in laboratory and adjusting the different pH values, in this study, using the hydrothermal method, the different sheet-like cluster microspheres was self-assembled by Bi2WO6 nano-sheets. This study analyzed and characterized the effect of pH value on synthesis of Bi2WO6 sheet-like cluster microspheres, phase structure, composition, crystal morphology and photoluminescence properties, and explore its possible growth mechanism. The results show that different pH values caused a significant impact in Bi2WO6 sheet-like cluster microspheres phase structure, morphology and photoluminescence properties, when A multi-quaternary ammonium cationic dispersant as structure directing agents in the growth stage of Bi2WO6 Microspheres. With the increasing of pH value, sheet- like clusters Bi2WO6 microspheres showed obvious trend growth in the (131) direction, when pH=5, Bi2WO6 microspheres can reach a maximum luminous intensity.
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