Citation: WEI Xia, ZHOU Yuan-Lin, LI Yin-Tao, CHENG Ya-Fei. A Multi-quaternary Ammonium Induced Synthesis of Bi₂WO₆ Sheet-Like Cluster Microspheres and Photoluminescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 583-588. doi: 10.3969/j.issn.1001-4861.2013.00.097 shu

A Multi-quaternary Ammonium Induced Synthesis of Bi₂WO₆ Sheet-Like Cluster Microspheres and Photoluminescence Properties

WEI Xia ^1,2 ,
ZHOU Yuan-Lin ^1,2 ,
LI Yin-Tao ^1,2 ,
CHENG Ya-Fei ^1,2

1.
1. State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China;

Received Date: 12 October 2012
Available Online: 21 November 2012
Fund Project: 国家自然科学基金委员会-中国工程物理研究院联合基金(No.11176026)资助项目。 (No.11176026)

By using a Gemini quaternary ammonium as surfactant synthesized in laboratory and adjusting the different pH values, in this study, using the hydrothermal method, the different sheet-like cluster microspheres was self-assembled by Bi₂WO₆ nano-sheets. This study analyzed and characterized the effect of pH value on synthesis of Bi₂WO₆ sheet-like cluster microspheres, phase structure, composition, crystal morphology and photoluminescence properties, and explore its possible growth mechanism. The results show that different pH values caused a significant impact in Bi₂WO₆ sheet-like cluster microspheres phase structure, morphology and photoluminescence properties, when A multi-quaternary ammonium cationic dispersant as structure directing agents in the growth stage of Bi₂WO₆ Microspheres. With the increasing of pH value, sheet- like clusters Bi₂WO₆ microspheres showed obvious trend growth in the (131) direction, when pH=5, Bi₂WO₆ microspheres can reach a maximum luminous intensity.
- Bi₂WO₆;hydrothermal method;cluster microspheres;pH value;photoluminescence
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沈阳化工大学材料科学与工程学院沈阳 110142

A Multi-quaternary Ammonium Induced Synthesis of Bi2WO6 Sheet-Like Cluster Microspheres and Photoluminescence Properties

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通讯作者: 陈斌, bchen63@163.com

A Multi-quaternary Ammonium Induced Synthesis of Bi₂WO₆ Sheet-Like Cluster Microspheres and Photoluminescence Properties