Citation: GONG Ya-Qiong, ZHANG He-Nan, ZHAN Huan, WEI Zeng-Yan, SU Wei. Biotemplating Fabrication of CdS Embedded Bionanowires at Room Temperature[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 635-641. doi: 10.3969/j.issn.1001-4861.2013.00.094 shu

Biotemplating Fabrication of CdS Embedded Bionanowires at Room Temperature

1.
1. Chemical Industry and Ecology Institute, North University of China, Shanxi, Taiyuan 030051 China;

Received Date: 9 June 2012
Available Online: 24 September 2012
Fund Project: 山西省青年科技研究基金(No．20120210005-2)资助项目。 (No．20120210005-2)

Cadmium Sulfide (CdS) nanowires (NWs) were synthesized by templating bionanotubes self-assembled from bis(N-amido-glycylglycine)-1,7-heptane dicarboxylate using cadmium chloride (CdCl₂) and sodium sulfide (Na₂S) as Cd and S precursors. The-COOH groups from the bionanotube surface act as chelating agents to coordinate Cd²⁺ ions and facilitate further growth of CdS nanocrystals on the bionanotube. The morphology, structure and composition of CdS embedded bionanowires were characterized by Transmission Electron Microscopy (TEM), High Resolution Transmission Electron Microscopy (HRTEM), Selected Area Electron Diffraction (SAED), UV, steady state Photoluminescence (PL) and Energy-dispersive X-ray spectroscopy (EDS) techniques. The results show that the resulting CdS embedded bionanowires, (4±0.6) μm in length and (400±55) nm in diameter, are coated by CdS nanoparticles with diameter of (5.5±0.3) nm. This work presents an effective direct-growth strategy on biomolecular templates to synthesize monodispersed QD-coated nanowires at room temperature by using coordination between -COOH and Cd²⁺, which has not accomplished previously by any other non-biotemplating synthetic methods.
- CdS;nanowire;bionanotube;templating;room temperature
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沈阳化工大学材料科学与工程学院沈阳 110142