Citation: GONG Ya-Qiong, ZHANG He-Nan, ZHAN Huan, WEI Zeng-Yan, SU Wei. Biotemplating Fabrication of CdS Embedded Bionanowires at Room Temperature[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 635-641. doi: 10.3969/j.issn.1001-4861.2013.00.094 shu

Biotemplating Fabrication of CdS Embedded Bionanowires at Room Temperature

1.
1. Chemical Industry and Ecology Institute, North University of China, Shanxi, Taiyuan 030051 China;

Received Date: 9 June 2012
Available Online: 24 September 2012
Fund Project: 山西省青年科技研究基金(No．20120210005-2)资助项目。 (No．20120210005-2)

Cadmium Sulfide (CdS) nanowires (NWs) were synthesized by templating bionanotubes self-assembled from bis(N-amido-glycylglycine)-1,7-heptane dicarboxylate using cadmium chloride (CdCl₂) and sodium sulfide (Na₂S) as Cd and S precursors. The-COOH groups from the bionanotube surface act as chelating agents to coordinate Cd²⁺ ions and facilitate further growth of CdS nanocrystals on the bionanotube. The morphology, structure and composition of CdS embedded bionanowires were characterized by Transmission Electron Microscopy (TEM), High Resolution Transmission Electron Microscopy (HRTEM), Selected Area Electron Diffraction (SAED), UV, steady state Photoluminescence (PL) and Energy-dispersive X-ray spectroscopy (EDS) techniques. The results show that the resulting CdS embedded bionanowires, (4±0.6) μm in length and (400±55) nm in diameter, are coated by CdS nanoparticles with diameter of (5.5±0.3) nm. This work presents an effective direct-growth strategy on biomolecular templates to synthesize monodispersed QD-coated nanowires at room temperature by using coordination between -COOH and Cd²⁺, which has not accomplished previously by any other non-biotemplating synthetic methods.
- CdS;nanowire;bionanotube;templating;room temperature
1. [1]
  [1] Niemeyer C M, Angew. Chem. Int. Ed. Eng., 2003,42(47): 5796-5800
2. [2]
  [2] Zhao H Y, Douglas E P, Harrison B S, et al. Langmuir, 2001, 17(26):8428-8433
3. [3]
  [3] Henglein A. Chem. Rev., 1989,89(8):1861-1873
4. [4]
  [4] Mondal S P, Das K, Dhar A, et al. Nanotechnology, 2007, 18(9):095606, DOI:10.1088/0957-4484/18/9/095606
5. [5]
  [5] Wu X C, Tao Y R. J. Cryst. Growth, 2002,242(3/4):309-312
6. [6]
  [6] Zhou Y, Kogiso M, He C, et al. Adv. Mater., 2007,19(8): 1055-1058
7. [7]
  [7] Jang J S, Joshi U A, Lee J S. J. Phys. Chem. C, 2007,111 (35):13280-13287
8. [8]
  [8] Yang L, Xing R, Shen Q, et al. J. Phys. Chem. B, 2006,110 (21):10534-10539
9. [9]
  [9] Ge C, Xu M, Fang J, et al. J. Phys. Chem. C, 2008,112(29), 10602-10608
10. [10]
  [10] Mao C, Flynn C E, Hayhurst A, et al. PNAS, 2003,100(12): 6946-6951
11. [11]
  [11] Su H, Han J, Dong Q, et al. Nanotechnology, 2008(19): 025601(6pp), DOI:10.1088/0957-4484/19/02/025601
12. [12]
  [12] Duan X, Huang Y, Cui Y, et al. Nature, 2001,409:66-69
13. [13]
  [13] Wang X, Summers C J, Wang Z. Nano Lett., 2004,4(3):423-426
14. [14]
  [14] Matsui H, Gologan B. J. Phys. Chem. B, 2000,104(15):3383-3386
15. [15]
  [15] Douberly G J, Pan S, Walters D, et al. J. Phys. Chem. B, 2001,105:7612-7618
16. [16]
  [16] Matsui H, MacCuspie R. Nano Lett., 2001,1(12):671-675
17. [17]
  [17] Djalali R, Chen Y F, Matsui H. J. Am. Chem. Soc., 2002, 124(46):13660-13661
18. [18]
  [18] Kogiso M, Ohnishi S, Yase K, et al. Langmuir, 1998,14(18): 4978-4986
19. [19]
  [19] Spanhel L, Haase M, Weller H, et al. J. Am. Chem. Soc., 1987,109(19):5649-5655
20. [20]
  [20] Gao T, Wang T. J. Phys. Chem. B, 2004,108(52):20045-20049
1. [1]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
2. [2]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Wenli FENG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress on ultralong room temperature phosphorescent carbon dots. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 833-846. doi: 10.11862/CJIC.20240308
7. [7]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
8. [8]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
9. [9]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
10. [10]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
11. [11]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
12. [12]
  Xiaogang Liu , Mengyu Chen , Yanyan Li , Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007
13. [13]
  Gaofeng Zeng , Shuyu Liu , Manle Jiang , Yu Wang , Ping Xu , Lei Wang . Micro/Nanorobots for Pollution Detection and Toxic Removal. University Chemistry, 2024, 39(9): 229-234. doi: 10.12461/PKU.DXHX202311055
14. [14]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
15. [15]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
16. [16]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
17. [17]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
18. [18]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
19. [19]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
20. [20]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(386)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142