Citation: GONG Ya-Qiong, ZHANG He-Nan, ZHAN Huan, WEI Zeng-Yan, SU Wei. Biotemplating Fabrication of CdS Embedded Bionanowires at Room Temperature[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 635-641. doi: 10.3969/j.issn.1001-4861.2013.00.094 shu

Biotemplating Fabrication of CdS Embedded Bionanowires at Room Temperature

1.
1. Chemical Industry and Ecology Institute, North University of China, Shanxi, Taiyuan 030051 China;

Received Date: 9 June 2012
Available Online: 24 September 2012
Fund Project: 山西省青年科技研究基金(No．20120210005-2)资助项目。 (No．20120210005-2)

Cadmium Sulfide (CdS) nanowires (NWs) were synthesized by templating bionanotubes self-assembled from bis(N-amido-glycylglycine)-1,7-heptane dicarboxylate using cadmium chloride (CdCl₂) and sodium sulfide (Na₂S) as Cd and S precursors. The-COOH groups from the bionanotube surface act as chelating agents to coordinate Cd²⁺ ions and facilitate further growth of CdS nanocrystals on the bionanotube. The morphology, structure and composition of CdS embedded bionanowires were characterized by Transmission Electron Microscopy (TEM), High Resolution Transmission Electron Microscopy (HRTEM), Selected Area Electron Diffraction (SAED), UV, steady state Photoluminescence (PL) and Energy-dispersive X-ray spectroscopy (EDS) techniques. The results show that the resulting CdS embedded bionanowires, (4±0.6) μm in length and (400±55) nm in diameter, are coated by CdS nanoparticles with diameter of (5.5±0.3) nm. This work presents an effective direct-growth strategy on biomolecular templates to synthesize monodispersed QD-coated nanowires at room temperature by using coordination between -COOH and Cd²⁺, which has not accomplished previously by any other non-biotemplating synthetic methods.
- CdS;nanowire;bionanotube;templating;room temperature
1. [1]
  [1] Niemeyer C M, Angew. Chem. Int. Ed. Eng., 2003,42(47): 5796-5800
2. [2]
  [2] Zhao H Y, Douglas E P, Harrison B S, et al. Langmuir, 2001, 17(26):8428-8433
3. [3]
  [3] Henglein A. Chem. Rev., 1989,89(8):1861-1873
4. [4]
  [4] Mondal S P, Das K, Dhar A, et al. Nanotechnology, 2007, 18(9):095606, DOI:10.1088/0957-4484/18/9/095606
5. [5]
  [5] Wu X C, Tao Y R. J. Cryst. Growth, 2002,242(3/4):309-312
6. [6]
  [6] Zhou Y, Kogiso M, He C, et al. Adv. Mater., 2007,19(8): 1055-1058
7. [7]
  [7] Jang J S, Joshi U A, Lee J S. J. Phys. Chem. C, 2007,111 (35):13280-13287
8. [8]
  [8] Yang L, Xing R, Shen Q, et al. J. Phys. Chem. B, 2006,110 (21):10534-10539
9. [9]
  [9] Ge C, Xu M, Fang J, et al. J. Phys. Chem. C, 2008,112(29), 10602-10608
10. [10]
  [10] Mao C, Flynn C E, Hayhurst A, et al. PNAS, 2003,100(12): 6946-6951
11. [11]
  [11] Su H, Han J, Dong Q, et al. Nanotechnology, 2008(19): 025601(6pp), DOI:10.1088/0957-4484/19/02/025601
12. [12]
  [12] Duan X, Huang Y, Cui Y, et al. Nature, 2001,409:66-69
13. [13]
  [13] Wang X, Summers C J, Wang Z. Nano Lett., 2004,4(3):423-426
14. [14]
  [14] Matsui H, Gologan B. J. Phys. Chem. B, 2000,104(15):3383-3386
15. [15]
  [15] Douberly G J, Pan S, Walters D, et al. J. Phys. Chem. B, 2001,105:7612-7618
16. [16]
  [16] Matsui H, MacCuspie R. Nano Lett., 2001,1(12):671-675
17. [17]
  [17] Djalali R, Chen Y F, Matsui H. J. Am. Chem. Soc., 2002, 124(46):13660-13661
18. [18]
  [18] Kogiso M, Ohnishi S, Yase K, et al. Langmuir, 1998,14(18): 4978-4986
19. [19]
  [19] Spanhel L, Haase M, Weller H, et al. J. Am. Chem. Soc., 1987,109(19):5649-5655
20. [20]
  [20] Gao T, Wang T. J. Phys. Chem. B, 2004,108(52):20045-20049
1. [1]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
4. [4]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
5. [5]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
6. [6]
  Gaofeng Zeng , Shuyu Liu , Manle Jiang , Yu Wang , Ping Xu , Lei Wang . Micro/Nanorobots for Pollution Detection and Toxic Removal. University Chemistry, 2024, 39(9): 229-234. doi: 10.12461/PKU.DXHX202311055
7. [7]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
8. [8]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
9. [9]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
10. [10]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
11. [11]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
12. [12]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
13. [13]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
14. [14]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
15. [15]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
16. [16]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
17. [17]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
18. [18]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
19. [19]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
20. [20]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(189)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142