Citation: HUI Yu-Chen, MA Xiao-Yan, CHEN Zhi-Qun, ZHANG Gao, SONG Ying, HOU Xiu-Zhang. Preparation of Quaternary Ammonium Salt Modified Graphene Oxide and Its Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 922-928. doi: 10.3969/j.issn.1001-4861.2013.00.084 shu

Preparation of Quaternary Ammonium Salt Modified Graphene Oxide and Its Properties

1.
1. Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education and The Key Laboratory of Polymer Science and Technology, Shaanxi Province, School of Science, Northwestern Polytechnical University, Xian 710129, China;

Corresponding author: MA Xiao-Yan,
Received Date: 17 September 2012
Available Online: 12 November 2012
Fund Project: 陕西省自然科学研究计划重点项目(No.2009JZ004)资助项目。 (No.2009JZ004)

Graphene oxide(GO) was prepared by the modified Hummers method,and modified by dodecyl dimethyl benzyl ammonium chloride (1227) to produce 1227 non-covalent modified graphene oxide(GO-1227). Raman spectrum, Diffuse reflection infrared spectroscopy and X-ray photoelectron spectroscopy were used to characterize the chemical structure of GO-1227. X-ray diffraction was used to observe the exfoliated morphology of GO-1227. It is found that the layers of GO became more complete disordered and exfoliated after modified by 1227. Scanning electron microscope and Transmission electron microscope was used to characterize the micro structure of GO-1227. The results show that GO-1227 presented curling and folded layer structure. The disperse property of GO-1227 was measured and thermal stability of GO and GO-1227 was compared by thermogravimetry analysis. The solubility of GO-1227 was enhanced in the relatively weak polar solvent since the 1227 cations surround the layers of GO, and thermal stability of GO was improved due to the thermolysis of oxidation group was prevented by 1227 cations. Finally, nano-filler of the GO-1227 was mixed with gel polyelectrolyte based on polymethylmethacrylate and polystyrene block copolymer(PMMA-b-PS) to prepare the nanocomposited gel polymer electrolytes (NGPE). The result of alternating-current impedance shows that the improvement of ionic conductivity is 8.6 times when the mixed ratio of GO-1227 is two over one thousand.
- graphene oxide;modified;dodecyl dimethyl benzyl ammonium chloride;gel polymer electrolyte;ionic conductivity
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