Advanced Search

Citation: HUI Yu-Chen, MA Xiao-Yan, CHEN Zhi-Qun, ZHANG Gao, SONG Ying, HOU Xiu-Zhang. Preparation of Quaternary Ammonium Salt Modified Graphene Oxide and Its Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 922-928. doi: 10.3969/j.issn.1001-4861.2013.00.084 shu

Preparation of Quaternary Ammonium Salt Modified Graphene Oxide and Its Properties

  • 1.

    1. Key Laboratory of Space Applied Physics and Chemistry, Ministry of Education and The Key Laboratory of Polymer Science and Technology, Shaanxi Province, School of Science, Northwestern Polytechnical University, Xian 710129, China;

  • Corresponding author: MA Xiao-Yan, 
  • Received Date: 17 September 2012
    Available Online: 12 November 2012

    Fund Project: 陕西省自然科学研究计划重点项目(No.2009JZ004)资助项目。 (No.2009JZ004)

  • Graphene oxide(GO) was prepared by the modified Hummers method,and modified by dodecyl dimethyl benzyl ammonium chloride (1227) to produce 1227 non-covalent modified graphene oxide(GO-1227). Raman spectrum, Diffuse reflection infrared spectroscopy and X-ray photoelectron spectroscopy were used to characterize the chemical structure of GO-1227. X-ray diffraction was used to observe the exfoliated morphology of GO-1227. It is found that the layers of GO became more complete disordered and exfoliated after modified by 1227. Scanning electron microscope and Transmission electron microscope was used to characterize the micro structure of GO-1227. The results show that GO-1227 presented curling and folded layer structure. The disperse property of GO-1227 was measured and thermal stability of GO and GO-1227 was compared by thermogravimetry analysis. The solubility of GO-1227 was enhanced in the relatively weak polar solvent since the 1227 cations surround the layers of GO, and thermal stability of GO was improved due to the thermolysis of oxidation group was prevented by 1227 cations. Finally, nano-filler of the GO-1227 was mixed with gel polyelectrolyte based on polymethylmethacrylate and polystyrene block copolymer(PMMA-b-PS) to prepare the nanocomposited gel polymer electrolytes (NGPE). The result of alternating-current impedance shows that the improvement of ionic conductivity is 8.6 times when the mixed ratio of GO-1227 is two over one thousand.
  • 加载中
    1. [1]

      [1] Artiles M S, Rout C S, Fisher T S, et al. Adv. Drug Deliv. Rev., 2011,63:1352-1360

    2. [2]

      [2] Kuila T, Bose S, Khanra P, et al. Biosens. Bioelectron., 2011,26:4637-4648

    3. [3]

      [3] Brownson D A, Kampouris D K, Banks C E. J. Power Sources, 2011,196:4873-4885

    4. [4]

      [4] Grande L, Chundi V T, Weib D, et al. Particuology, 2012, 10:1-8

    5. [5]

      [5] HU Yao-Juan(胡耀娟), JIN Juan(金娟), ZHANG Hui(张卉), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2010,26 (8):2073-2086

    6. [6]

      [6] Soldano C, Mahmood A, Production D E. Carbon, 2010,48: 2127-2135

    7. [7]

      [7] MA Wen-Shi(马文石), ZHOU Jun-Wen(周俊文). Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2010,31(10):1982-1986

    8. [8]

      [8] HUANG Yi(黄毅), CHEN Yong-Sheng(陈永胜). Sci. China B: Chem.(Zhongguo Kexue B: Huaxue), 2009,39(9):887-896

    9. [9]

      [9] LV Peng(吕鹏), FENG Yi-Yu(冯奕钰), ZHANG Xue-Quan (张学全), et al. Sci China Technol. Sci(Zhongguo Kexue: Jishu Kexue), 2010,40(11):1247-1256

    10. [10]

      [10] MA Wen-Shi(马文石), ZHOU Jun-Wen(周俊文), LIN Xiao- Dan(林晓丹). Acta Chim. Sin.(Huaxue Xuebao), 2011,69 (12):1463-1468

    11. [11]

      [11] SHI Jing-Jing(时镜镜), MA Wen-Shi(马文石), LIN Xiao- Dan(林晓丹). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):131-136

    12. [12]

      [12] Timothy M S. ACS Macro Lett., 2012,1:3-5

    13. [13]

      [13] Huang Y, Ma X Y, Liang G Z, et al. Polymer, 2008,49:2085 -2094

    14. [14]

      [14] Zhang Q L, Ma X Y, Wang Y F, et al. J. Phys. Chem. B, 2009,113:11898-11905

    15. [15]

      [15] Stankovich S, Dikin D A, Piner R D, et al. Carbon, 2007, 45:1558-1565

    16. [16]

      [16] WAN Chen(万臣), PENG Tong-Jiang(彭同江), SUN Hong- Juan(孙红娟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(5):915-921

    17. [17]

      [17] GENG Jing-Yi(耿静漪), ZHU Xin-Sheng(朱新生), DU Yu- Kou(杜玉扣). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(2):357-361

    18. [18]

      [18] SONG Ying(宋颖), MA Xiao-Yan(马晓燕), TANG Lin(唐 林), et al. J. Funct. Polym.(Gongneng Gaofenzi Xuebao), 2011,24(4):335-339

    19. [19]

      [19] Zhu Y, Murali S, Cai W, et al. Adv. Mater., 2010,22:3906- 3924

    20. [20]

      [20] HU Jie-Han(胡皆汉), ZHENG Xue-Fang(郑学仿). Practical Infrared Spectroscopy(实用红外光谱学). Beijing: Science Press, 2011.

    21. [21]

      [21] WENG Shi-Fu(翁诗甫). Fourier Transformation Infrared Spectroscopic Analysis. 2nd Ed.(傅里叶变换红外光谱分析. 2版). Beijing: Chemical Industry Press, 2010.

    22. [22]

      [22] Schniepp H C, Li J L, McAllister M J, et al. J. Phys. Chem. B, 2006,110:8535-8539

    23. [23]

      [23] HAN Kun-Ming(韩坤明), LU Dao-Rong(鲁道荣). Acta Mater. Compos. Sin.(Fuhe Cailiao Xuebao), 2008,25(3):57-62

  • 加载中
    1. [1]

      Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    2. [2]

      Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO2/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189

    3. [3]

      Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099

    4. [4]

      Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030

    5. [5]

      Xuejiao Wang ,  Suiying Dong ,  Kezhen Qi ,  Vadim Popkov ,  Xianglin Xiang . Photocatalytic CO2 Reduction by Modified g-C3N4. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005

    6. [6]

      Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260

    7. [7]

      Yunting Shang ,  Yue Dai ,  Jianxin Zhang ,  Nan Zhu ,  Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050

    8. [8]

      Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

    9. [9]

      Bao Jia ,  Yunzhe Ke ,  Shiyue Sun ,  Dongxue Yu ,  Ying Liu ,  Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121

    10. [10]

      Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

    11. [11]

      Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158

    12. [12]

      Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    13. [13]

      Mingyang Men ,  Jinghua Wu ,  Gaozhan Liu ,  Jing Zhang ,  Nini Zhang ,  Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019

    14. [14]

      Jiandong Liu ,  Zhijia Zhang ,  Mikhail Kamenskii ,  Filipp Volkov ,  Svetlana Eliseeva ,  Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048

    15. [15]

      . 

      南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

      . CCS Chemistry, 2025, 7(0): -.

    16. [16]

      Tao Jiang ,  Yuting Wang ,  Lüjin Gao ,  Yi Zou ,  Bowen Zhu ,  Li Chen ,  Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057

    17. [17]

      Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304

    18. [18]

      Zhenlin Zhou ,  Siyuan Chen ,  Yi Liu ,  Chengguo Hu ,  Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049

    19. [19]

      Tianqi Bai ,  Kun Huang ,  Fachen Liu ,  Ruochen Shi ,  Wencai Ren ,  Songfeng Pei ,  Peng Gao ,  Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024

    20. [20]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

Get Citation
PDF
XML
Metrics
  • PDF Downloads(328)
  • Abstract views(807)
  • HTML views(142)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return