Citation:
TANG Yan, FANG Wei-Mao, ZHONG Ben-He, LIU Heng, GUO Xiao-Dong. Synthesis and Electrochemical Performance of Nano-Structure Li3V2(PO4)3/C by Sol-Spray Drying Method[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(5): 915-921.
doi:
10.3969/j.issn.1001-4861.2013.00.070
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Li3V2(PO4)3/C samples were successfully synthesized by sol-spray drying method, with LiOH·H2O, NH4VO3, H3PO4 and critic acid as raw materials, comparing the effect of mechamicalactivation before calcinations and direct calcination on the structure, morphology and electrochemical properties of the samples. The structure and morphology were characterized by XRD, SEM, BET and tap density test, and the electrochemical performance was studied by galvanostatic charge-discharge test, CV and EIS. The results show the samples are hollow spherical shell shape, which is composed of nano-sheet about 100nm and still keep the structure after mechamicalactivation. However, the crystallinity and tap density have improved a lot, so is the electrochemical performance. The discharge capacity is 123.6 mAh·g-1 at 0.1C, maintaining 107.8 and 106.0 mAh·g-1 even at high discharge rate of 10C and 20C. The EIS results indicate the samples prepared by the method have a smaller charge transfer resistance.
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[1]
[1] ZHAO Hao-Chuan(赵浩川), SONG Yang(宋杨), GUO Xiao- Dong(郭孝东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(10):2347-2352
-
[2]
[2] TANG Hong(唐红), GUO Xiao-Dong(郭孝东), TANG Yan(唐 艳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(4):809-814
-
[3]
[3] WU Yu-Ling(武玉玲), PU Wei-Hua(蒲薇华), REN Jian-Guo (任建国), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2012, 27(4):422-426
-
[4]
[4] TAGN Yan(唐艳), ZHONG Ben-He(钟本和), GUO Xiao- Dong(郭孝东), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2011,27(4):869-874
-
[5]
[5] Zhang B, Zheng J C. Electrochim. Acta, 2012,67(0):55-61
-
[6]
[6] Ko Y N, Koo H Y, Kim J H, et al. J. Power Sources, 2011, 196(16):6682-6687
-
[7]
[7] Nagamine K, Honma T, Komatsu T. J. Power Sources, 2011, 196(22):9618-9624
-
[8]
[8] ZHAI Jing(翟静), ZHAO Min-Shou(赵敏寿), SHA Ou(沙鸥), et al. Rare Metal Mater. Eng.(Xiyou Jinshu Cailiao Yu Gongcheng), 2010,39(7):1310-1316
-
[9]
[9] Rui X H, Li C, Chen C H. Electrochim. Acta, 2009,54(12): 3374-3380
-
[10]
[10] Qiao Y Q, Tu J P, Mai Y J, et al. J. Alloys Compd., 2011, 509(25):7181-7185
-
[11]
[11] Bini M, Ferrari S, Capsoni D, et al. Electrochim. Acta, 2011,56(6):2648-2655
-
[12]
[12] Xia Y, Zhang W K, Huang H, et al. Materials Science and Engineering B, 2011,176(8):633-639
-
[13]
[13] Pan A Q, Liu J, Zhang J G, et al. Electrochem. Commun., 2010,12(12):1674-1677
-
[14]
[14] Liu H W, Cheng C X, Huang X T, et al. Electrochim. Acta, 2010,55(28):8461-8465
-
[15]
[15] Wang L J, Zhou X C, Guo Y L. J. Power Sources, 2010,195 (9):2844-2850
-
[16]
[16] Fu P, Zhao Y M, Dong Y Z, et al. J. Phys. Chem. Solid, 2010,71(3):394-399
-
[17]
[17] CHEN Quan-Qi(陈权启), HE Wei-Chun(何伟春), WANG Jian-Ming(王建明), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(2):181-190
-
[18]
[18] Wang L J, Tang Z Y, Ma L, et al. Electrochem. Commun., 2011,13(11):1233-1235
-
[19]
[19] YU Feng(于锋), ZHANG Jing-Jie(张敬杰), YANG Yan-Feng (杨岩峰), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2009, 24(2):349-352
-
[20]
[20] MA Ping-Ping(马平平), LIU Zhi-Jian(刘志坚), XIA Jian- Hua(夏建华), et al. Chin. J. Rare Metals(Xiyou Jinshu), 2012,36(1):104-108
-
[21]
[21] Yin S C, Grondey H, Strobel P, et al. J. Am. Chem. Soc., 2003,125:10402-10411
-
[22]
[22] Ai D J, Liu K Y, Lu Z G, et al. J. Electrochim. Acta, 2011, 56(7):2823-2827
-
[23]
[23] Qiao Y Q, Tu J P, Wang X L, et al. J. Power Sources, 2011, 196(18):7715-7720
-
[24]
[24] Qiao Y Q, Wang X L, Xiang J Y, et al. Electrochim. Acta, 2011,56(5):2269-2275
-
[25]
[25] Tang A P, Wang X Y, Xu G R, et al. Mater. Lett., 2009,63 (27):2396-2398
-
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