Citation:
LUO Yi, XIA Zhi-Guo. Host Polyhedral Substitution and the Modification of the Luminescence Properties of Y2SiO5:Ce3+ Phosphor[J]. Chinese Journal of Inorganic Chemistry,
;2013, 29(4): 665-670.
doi:
10.3969/j.issn.1001-4861.2013.00.064
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Structural modification of the phosphor host plays a key role in the optimization of the luminescence properties of the optical materials, and it becomes the important research field for the exploration of the relationship between the solid structure and its property. The Y2SiO5 host is selected as the model to be substituted by the Si/Al or Si/P, and the [AlO4] and [PO4] tetragons are used to replace the [SiO4], so that a series of compounds with the chemical formula of Y1.95SiO5:0.05Ce3+, Y1.95Si1-xAlxO5-xFx:0.05Ce3+ (x=0.05, x=0.1, x=0.2, x=0.4, and x=1), Y1.95-yCaySi1-yPyO5:0.05Ce3+ (y=0, y=0.02, y=0.04, y=0.06, y=0.08, and y=0.2) phosphors were designed and successfully obtained. XRD patterns showed that the diffraction peaks of both Y1.95Si1-xAlxO5-xFx:0.05Ce3+ and Y1.95-yCaySi1-yPyO5:0.05Ce3+ matched well with the standard patterns of Y2SiO5. Photoluminescence investigations indicated that the emission intensities had been increased to a great extent compared with that of Y2SiO5. A slight blue-shift was also observed in the emission spectra of Y1.95Si1-xAlxO5-xFx:0.05Ce3+ and Y1.95-yCaySi1-yPyO5:0.05Ce3+. Moreover, decay curves of Y1.95Si1-xAlxO5-xFx:0.05Ce3+ and Y1.95-yCaySi1-yPyO5:0.05Ce3+ confirmed that there are similar chemical environment for the Ce3+ luminescence.
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[1]
[1] GUANG Shan-Yi(光善仪), ZHANG Chao(张超), XU Hong-Yao(徐洪耀), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2007,23(6):999-1004
-
[2]
[2] Cark C, Marina M, Anna M et al. Opt. Mater., 2007,29:585-592
-
[3]
[3] Felshe J. Struct. Bonding, 1973,13:99-197
-
[4]
[4] Gonzalez-Ortega J A, Tejeda E M, Perea N, et al. Opt. Mater., 2005,27:1221-1227
-
[5]
[5] Ricci P C, Carbonaro C M, Corpino R, et al. J. Phys. Chem., 2011,115:16630-16636
-
[6]
[6] Won B I, Nathan G, Joshua K, et al. Adv. Mater., 2011,23: 2300-2305
-
[7]
[7] WANG Fei(王飞), TIAN Yi-Guang(田一光), ZHANG Qiao (张乔) et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(12):2170-2174
-
[8]
[8] Xia Z G, Liu R S, Huang K W, et al. J. Mater. Chem., 2012, 22:15183-15189
-
[9]
[9] Guo Y Z, Yu X B, Liu J, et al. J. Rare Earth, 2010,28(1):34-36
-
[10]
[10] Han J Y, Im W B, Kim D, et al. J. Mater. Chem., 2012,22 (12):5374-5381
-
[11]
[11] Han J Y, Im W B, Lee G Y, et al. J. Mater. Chem., 2012,22 (18):8793-8798
-
[12]
[12] Hiroshi Y, Masato Y, Hiroyuki I, et al. J. Alloys Compds, 2010,495:162-166
-
[13]
[13] Takayuki H, Yuki K. J. Phys. Chem., 2007,111:168-174
-
[14]
[14] ZHU Guo-Xian(朱国贤), CHEN Yi-Zhao(陈毅昭), LIAN Hong-Zhou(连洪州), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):8-12
-
[15]
[15] Liu W R, Huang C H, Wu C P, et al. J. Mater. Chem., 2011,21:6869-6874
-
[16]
[16] Kristin A D, Nathan C G, Sara R P, et al. J. Mater. Chem., 2012,22:18204-18213
-
[17]
[17] Makhov V N, Kirm M, Stryganyuk G, et al. J. Lumin., 2012,132:418-424
-
[18]
[18] Gonzalez-Ortega J A, Tejeda E M, Perea N, et al. Opt. Mater., 2005,27:1221-1227
-
[19]
[19] Dorenbos P. J. Lumin., 2000,91:155-176
-
[20]
[20] SUN Jia-Yue(孙家跃), DU Hai-Yan(杜海燕). Solid-State Luminescence Materials(固体发光材料). Beijing: Chemical Industry Press, 2003.
-
[21]
[21] Xia Z G, Wang X M, Wang Y X, et al. Inorg. Chem., 2011, 50:10134-10142
-
[22]
[22] Wu W W, Xia Z G, Zhuang J Q, et al. ECS J. Solid State Sci. Technol., 2012,1(1):R46-R49
-
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