Citation: LUO Yi, XIA Zhi-Guo. Host Polyhedral Substitution and the Modification of the Luminescence Properties of Y₂SiO₅:Ce³⁺ Phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 665-670. doi: 10.3969/j.issn.1001-4861.2013.00.064 shu

Host Polyhedral Substitution and the Modification of the Luminescence Properties of Y₂SiO₅:Ce³⁺ Phosphor

LUO Yi ,
XIA Zhi-Guo

1.
School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China

Received Date: 24 August 2012
Available Online: 1 October 2012
Fund Project: 国家自然科学基金(No.51002146, No.51272242)资助项目。 (No.51002146, No.51272242)

Structural modification of the phosphor host plays a key role in the optimization of the luminescence properties of the optical materials, and it becomes the important research field for the exploration of the relationship between the solid structure and its property. The Y₂SiO₅ host is selected as the model to be substituted by the Si/Al or Si/P, and the [AlO₄] and [PO₄] tetragons are used to replace the [SiO₄], so that a series of compounds with the chemical formula of Y_1.95SiO₅:0.05Ce³⁺, Y_1.95Si_1-xAl_xO_5-xF_x:0.05Ce³⁺ (x=0.05, x=0.1, x=0.2, x=0.4, and x=1), Y_1.95-yCa_ySi_1-yP_yO₅:0.05Ce³⁺ (y=0, y=0.02, y=0.04, y=0.06, y=0.08, and y=0.2) phosphors were designed and successfully obtained. XRD patterns showed that the diffraction peaks of both Y_1.95Si_1-xAl_xO_5-xF_x:0.05Ce³⁺ and Y_1.95-yCa_ySi_1-yP_yO₅:0.05Ce³⁺ matched well with the standard patterns of Y₂SiO₅. Photoluminescence investigations indicated that the emission intensities had been increased to a great extent compared with that of Y₂SiO₅. A slight blue-shift was also observed in the emission spectra of Y_1.95Si_1-xAl_xO_5-xF_x:0.05Ce³⁺ and Y_1.95-yCa_ySi_1-yP_yO₅:0.05Ce³⁺. Moreover, decay curves of Y_1.95Si_1-xAl_xO_5-xF_x:0.05Ce³⁺ and Y_1.95-yCa_ySi_1-yP_yO₅:0.05Ce³⁺ confirmed that there are similar chemical environment for the Ce³⁺ luminescence.
- Y₂SiO₅;polyhedral substitution;luminescent properties
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Host Polyhedral Substitution and the Modification of the Luminescence Properties of Y2SiO5:Ce3+ Phosphor

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Host Polyhedral Substitution and the Modification of the Luminescence Properties of Y₂SiO₅:Ce³⁺ Phosphor