Citation: HOU Xiang-Yu, HOU Chun-Yang, FENG Jing, WANG Wei-Zhen, ZHANG Zheng. A Simple Seed-Assisted Solid State Method for Synthesis of Special Shaped Ferrites[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 855-860. doi: 10.3969/j.issn.1001-4861.2013.00.059 shu

A Simple Seed-Assisted Solid State Method for Synthesis of Special Shaped Ferrites

1.
1 College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong 266100, China;

Received Date: 2 September 2012
Available Online: 30 October 2012
Fund Project: 中国博士后基金(No.2011M500511)国家海洋局青年海洋科学基金(No.2012547)资助项目。 (No.2011M500511)国家海洋局青年海洋科学基金(No.2012547)

CuFe₂O₄ olivary particle and NiFe₂O₄ nanowire were synthesized by a simple seed-assisted solid state method, without any templates and surfactant assistants. The crystal structures, morphologies and magnetic properties were investigated. The results indicate that the seeds can provide crystal nucleus for generating new ferrite phase. At the same time, the seeds are beneficial for improving the purity and for realizing the shape control. The CuFe₂O₄ olivary particle, covered with irregular hollows, is about 0.4 μm in width and 0.8 μm in length. The diameter of the NiFe₂O₄ nanowire is about 10 nm, and the ratio of length to diameter could be up to 50:1. Both CuFe₂O₄ olivary particle and NiFe₂O₄ nanowire show typical superparamagnetic property at room temperature. However, the ferrites synthesized by traditional solid state method at the same condition as the title method show particle morphologies, low purity and ferromagnetic properties. These results suggest seed-assisted solid state method is an effective way to synthesize high purity ferrites with special shape.
- ferrite;solid state method;seed;special shape;superparamagnetism
1. [1]
  [1] Sharbati A, Khani J M V, Amiri G R. Solid State Commun., 2012,152:199-203
2. [2]
  [2] Lu J, Ma S L, Sun J Y, et al. Biomaterials, 2009,30:2919- 2928
3. [3]
  [3] Ji X M, Li M L, Zhao Y X, et al. Solid State Sci., 2009,11: 1170-1175
4. [4]
  [4] Chu Y Q, Fu Z W, Qin Q Z. Electrochim. Acta, 2004,49: 4915-4921
5. [5]
  [5] Suzuki T, Tanaka T. J. Magn. Magn. Mater., 2002,242-245: 328-330
6. [6]
  [6] Zhang D G, Tong Z W, Xu G Y, et al. Solid State Sci., 2009, 11:113-117
7. [7]
  [7] Zhen L, He K, Xu C Y, et al. J. Magn. Magn. Mater., 2008,320:2672-2675
8. [8]
  [8] Shen Y, Zhao Q D, Li X Y, et al. Colloids Surf. A, 2012, 403:305-40
9. [9]
  [9] Zhang D E, Zhang X J, Ni X M, et al. J. Magn. Magn. Mater., 2005,292:79-82
10. [10]
  [10] Hou X Y, Feng J, Liu X H, et al. J. Colloid Interface Sci., 2011,353:524-529
11. [11]
  [11] Feng S J, Yang W, Wang Z B. Mater. Sci. Eng. B, 2011,176: 1509-1512[12] Mu G H, Chen N, Pan X F, et al. Mater. Lett., 2008,62:840-842
12. [12]
  [13] Wang H, Tang H Z, He J H, et al. Mater. Res. Bull., 2009,44:1676-1680
13. [13]
  [14] Nam J H, Joo Y H, Lee J H, et al. J. Magn. Magn. Mater., 2009,321:1389-1392
14. [14]
  [15] Zhang J G, Chen J F, Wang Z X, et al. Mater. Lett., 2007, 61:1629-1632
15. [15]
  [16] Huang Z B, Yin G F, Liao X M, et al. J. Colloid Interface Sci., 2008,317:530-535
16. [16]
  [17] Zhang C Y, Shen X Q, Zhou J X, et al. Rare Metal Mat. Eng., 2008,37:180-184
17. [17]
  [18] Lü S, Suo H, Zhao X, et al. Solid State Commun., 2009,149: 1755-1759
18. [18]
  [19] Kang S K, Kim Y, Hahn M S, et al. Curr. Appl. Phys., 2006,6:e114-e120
19. [19]
  [20] Kumar R S, Sudhagar P, Matheswaran P, et al. Mater. Sci. Eng. B, 2010,172:283-288
20. [20]
  [21] Wang H, Quan X, Yu H T, et al. Carbon, 2008,46:1126-1132
21. [21]
  [22] Hou X Y, Feng J, Xu X D, et al. J. Alloys Compd., 2010, 491:258-263
22. [22]
  [23] HOU Xiang-Yu(侯相钰), FENGg Jing(冯静), WANG Zhi- Qiang(王志强), et al. J. Funct. Mater.(Gongneng Cailiao), 2010,41:35-40
23. [23]
  [24] Zhang Y Q, Huang Z B, Tang F Q, et al. Solid State Commun., 2006,138:132135
24. [24]
  [25] Wang J Y, Ren F L, Yi R, et al. J. Alloys Compd., 2009, 479:791-796
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沈阳化工大学材料科学与工程学院沈阳 110142