Citation: CHEN Xiao-Yun, LU Dong-Fang, CHEN Yan, TAN Fei. Synthesis and Photocatalytic Activity of Mesoporous TiO₂ Using Nano-Cellulose Template Prepared by Acid Method[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 528-536. doi: 10.3969/j.issn.1001-4861.2013.00.055 shu

Synthesis and Photocatalytic Activity of Mesoporous TiO₂ Using Nano-Cellulose Template Prepared by Acid Method

1.
1. College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, China;

Received Date: 11 September 2012
Available Online: 8 November 2012
Fund Project: 国家自然科学基金(No.31000269) (No.31000269) 福建省高等学校杰出青年科研人才培育计划(No.JA11072) (No.JA11072) 福建省教育厅基金(No.JA00121)资助项目。 (No.JA00121)

Mesoporous TiO₂ was synthesized by a hydrolysis-precipitation method using a renewable biological resource of nano-cellulose as the template and TiCl₄ as the precursor. The photocatalytic activity of TiO₂ was evaluated using the degradation of methyl orange under ultraviolet light irradiation as a model reaction. N₂ adsorption- desorption, transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetry-differential Scanning Calorimetry (TG/DSC), fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were used for catalyst characterization. The results show that TiO₂ synthesized with acid nano-cellulose template exhibits high activity under UV irradiation. The material exhibits mesoporous structure with specific area of 192 m²·g^-1, average pore size of 5.03 nm, and pore volume of 0.35 cm³·g^-1. The addition of acid nano-cellulose template can reduce the amount of surface OH^- of TiO₂, hydroxyl groups of long-chain cellulose and surface hydroxyl groups of TiO₂ bonding can inhibit the TiO₂ precursor growth and aggregation, and inhibit the phase transformation from anatase to rutile.
- titania;nano-cellulose;template;mesoporous;photocatalysis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Photocatalytic Activity of Mesoporous TiO2 Using Nano-Cellulose Template Prepared by Acid Method

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Photocatalytic Activity of Mesoporous TiO₂ Using Nano-Cellulose Template Prepared by Acid Method