Citation: CAO Ping, YANG Xian-Gui, XIN Yang, WANG Gong-Ying. Mo-Ti Composite Oxide Catalyst for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 747-752. doi: 10.3969/j.issn.1001-4861.2013.00.047 shu

Mo-Ti Composite Oxide Catalyst for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate

CAO Ping ^1,2 ,
YANG Xian-Gui ^1,3 ,
XIN Yang ^1,3 ,
WANG Gong-Ying ^1,3

1.
1 Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China;

Received Date: 28 June 2012
Available Online: 13 August 2012
Fund Project: 国家“十一五”科技支撑计划(2006BAE02B03) (2006BAE02B03)江苏省常州市工业科技攻关计划(CE2008091) (CE2008091)重庆市教育委员会科学技术研究项目 (KJ110815) (KJ110815)重庆理工大学科研启动基金(2010ZD29)资助项目。 (2010ZD29)

The Mo-Ti composite oxide catalyst was prepared by sol-gel method and used for the transesterification of dimethyl carbonate (DMC) and phenyl acetate (PA) to diphenyl carbonate (DPC). The effect of the molar ratio of Mo/Ti and reaction conditions on the catalytic performance was investigated. The catalyst with a Mo/Ti molar ratio of 2.5 shows the highest activity. When the reaction is carried out at 180℃, with a molar ratio of PA to DMC of 2:1, the reaction time of 4 h, a catalyst amount of 0.08 (weight ratio to PA), the conversion of DMC is 74.0%, and the selectivity of DPC and MPC is 45.5% and 51.0%, respectively. According to the surface and X-ray diffraction results, lager specific areas result in improved catalytic performance by the addition of TiO₂. The Mo-Ti composite oxide is composed of α-MoO₃ and highly dispersed amorphous titania and/or new crystal phase of Mo-Ti composite oxide.
- molybdenum;titanium;composite oxide;dimethyl carbonate;phenyl acetate;diphenyl carbonate
1. [1]
  [1] Tundo P, Selva M. Acc. Chem. Res., 2002,35(9):706-716
2. [2]
  [2] Kim W B, Joshi U A, Lee J S. Ind. Eng. Chem. Res., 2004, 43(9):1897-1914
3. [3]
  [3] Gong J L, Ma X B, Wang S P. Appl. Catal. A, 2007,316(1): 1-21
4. [4]
  [4] Toniolo L. J. Mol. Catal. A, 1999,139(2/3):109-119
5. [5]
  [5] Ishii H, Goyal M, Ueda M, et al. Catal. Lett., 2000,65(1/2/3): 57-60
6. [6]
  [6] CAO Ping(曹平), YANG Xian-Gui(杨先贵), WANG Gong- Ying(王公应), et al. Nat. Gas Chem. Ind. (Tianranqi Huagong), 2008,33:43-46
7. [7]
  [7] Illuminati G, Romano U, Tesei R. US 4182726.1980
8. [8]
  [8] CAO Ping(曹平), SHI Wei-Bing(石卫兵), WANG Gong-Ying (王公应). Petrochem. Tech. (Shiyou Huagong), 2010,39(3): 346-351
9. [9]
  [9] CAO Ping(曹平), YANG Jian(杨建), WANG Gong-Ying (王公应), et al. Chin. J. Catal. (Cuihua Xuebao), 2009,30 (9):65-68
10. [10]
  [10] CAO Ping(曹平), YANG Xian-Gui(杨先贵), WANG Gong-Ying(王公应), et al. Petrochem. Tech. (Shiyou Huagong), 2011,40(10):1037-1041
11. [11]
  [11] HAN Wei-Ping(韩维屏), YIN Xi-Lin(尹喜林), LI Yong-Zhan(李永战). Chin. J. Catal. (Cuihua Xuebao), 1992,13(1): 19-24
12. [12]
  [12] ZHAN She-Xia(湛社霞), FAN Shan-Hu(范山湖), LIN Zuo- Mei(林作梅). Acta Scientiarum Naturalium Universitis Sunyatseni (Zhongshan Daxue Xuebao), 2001,40(2):125-126
13. [13]
  [13] YANG Ying(杨莹), LI Xin-Jun(李新军), CHEN Jun-Tao (陈俊涛). Chin. J. Nonfer. Metals (Zhongguo Youse Jinshu Xuebao), 2004,14(3):509-514
14. [14]
  [14] WANG Yu-Ping(王玉萍), WANG Lian-Jun(王连军), YUAN Jun-Xiu(袁俊秀). Appl. Chem. (Yingyong Huaxue), 2007,24 (1):53-57
15. [15]
  [15] CAI Bin-Xin(蔡炳新), ZHAN Yong-Gong(詹拥共), YANG Ying-Ying(杨莹莹). J. Chem. Ind. Eng. (Huagong Xuebao), 2007,58(6):1451-1456
16. [16]
  [16] CHEN Gui-Hua(陈桂华), YAN Rui-Qiang(闫瑞强), LIANG Hua-Ding(梁华定). Bull. Chin. Ceram. Soc. (Guisuanyan Tongbao), 2009,28(5):944-950
1. [1]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
2. [2]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
3. [3]
  Shuying Zhu , Shuting Wu , Ou Zheng . Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate. University Chemistry, 2024, 39(4): 107-113. doi: 10.3866/PKU.DXHX202310117
4. [4]
  Ruitong Zhang , Zhiqiang Zeng , Xiaoguang Zhang . Improvement of Ethyl Acetate Saponification Reaction and Iodine Clock Reaction Experiments. University Chemistry, 2024, 39(8): 197-203. doi: 10.3866/PKU.DXHX202312004
5. [5]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
6. [6]
  Jiaojiao Yu , Bo Sun , Na Li , Cong Wen , Wei Li . Improvement of Classical Organic Experiment Based on the “Reverse-Step Optimization Method”: Taking Synthesis of Ethyl Acetate as an Example. University Chemistry, 2025, 40(3): 333-341. doi: 10.12461/PKU.DXHX202405177
7. [7]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
8. [8]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
11. [11]
  Tao Cao , Fang Fang , Nianguang Li , Yinan Zhang , Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098
12. [12]
  Yufan Pan , Xue Ding , Jiayu Lin , Haiting Wu , Hairong Huang , Cuixue Chen , Meiling Ye . Oil Cosmetics, Charming Chemistry: A Gradient Science Popularization Scheme for Cream Cosmetic Preparation. University Chemistry, 2025, 40(4): 382-389. doi: 10.12461/PKU.DXHX202406078
13. [13]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
14. [14]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
15. [15]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
16. [16]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
17. [17]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
18. [18]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
19. [19]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
20. [20]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

Get Citation

PDF

XML

Metrics

PDF Downloads(216)
Abstract views(713)
HTML views(104)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142