Citation: Yildiz E, Karadeniz B, Yildiz A M, Rencuzogullari E. Bivalent and Trivalent Transition Metal Complexes of Azo Compounds Derived from Anthraquinone and Their Mutagenic-Teratogenic Effects[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 595-604. doi: 10.3969/j.issn.1001-4861.2013.00.033 shu

Bivalent and Trivalent Transition Metal Complexes of Azo Compounds Derived from Anthraquinone and Their Mutagenic-Teratogenic Effects

1.
1. Department of Chemistry, Arts and Science Faculty, Cukurova University, Balcali 01330, Adana, Turkiye;

Received Date: 25 May 2012
Available Online: 6 September 2012
Fund Project:

4-(5'-aminonaphtalene-3'-sulfonic acid)azo-(2″-N-(4''', 6'''-dichloro-S-triazine) benzene-5″-(β-sulfatoethyl sulfonyl)-2-methyl anthraquinone (2a), 4-(2'-aminobenzenesulfonic acid)azo-(2″-N-(4''', 6'''-dichloro-S-triazine)-3″-benzensulfonic acid)-2-methyl anthraquinone, 4-(5'-aminonaphtalene-3'-sulfonic acid)azo-(2″-N-(4''', 6'''-dichloro-S-triazine)benzen-5″-(β-sulfatoethyl sulfonyl)-2-methyl anthraquinone and 4-(p-(β-sulfatoethyl sulfonyl) azo-(2″-N-(4''', 6'''-dichloro-S-triazine) naphtalene-5″sulfonic acid)-2-methyl anthraquinone with Fe^Ⅲ,Co^Ⅱ metal complexes were prepared and used for determination of mutagenic and teratogenic effects in Ames/Salmonella/Microsome Test and in embryos of rats. 2a-Fe and 2a-Co were not mutagenic for both TA98 and TA100 strains with and without metabolic activator S9mix.
- anthraquinone;azo;metal complex;mutagenicity;teratogenicity
1. [1]
  [1] Park H, Kim, E R et al. Bull. Chem. Soc. Jpn. 2002,75: 2067-2070
2. [2]
  [2] Gregory P. High-Technology Applications of Organic Colorants, New York and London Plenum Press, 1991:1-3
3. [3]
  [3] Sheng Y, Zhenghua Z. Dyes Pigments, 1996,36:27～34
4. [4]
  [4] Yildiz E, Bozok N. E-J Chem, 2008,5:997-1007
5. [5]
  [5] Yazdanbakhsh M R, Giahi M, Mohammadi A. J. Mol. Liq., 2009,144:145-148
6. [6]
  [6] Hedge V L, Venkatesh Y P. Clin. Exp. Allergy, 2004,34: 1602-1609
7. [7]
  [7] Romyhr O, Nyfors A, Leira H L, Smedbold H T. Contact Dermatitis, 2006,55:167-172
8. [8]
  [8] Birhanli A, Ozmen M. Drug Chem. Toxicol., 2005,28:51-65
9. [9]
  [9] Yildiz E, Keles T. Synth. React. Inorg. Met.-Org. Chem., 2009,39:455-461
10. [10]
  [10] Yildiz E, Cetinkol T, Serindag O. Synth. React. Inorg. Met.-Org. Chem., 2009,40:19-26
11. [11]
  [11] Maron D M, Ames B N. Mutat. Res., 1983,113:173-215
12. [12]
  [12] OECD, Guideline for the Testing of Chemicals 414, Prenatal Developmental Toxicity Study. Adopted: 2001.
13. [13]
  [13] Okada A, Kurihara H, Fujiwara M, et al. Birth Defects Res B Dev Reprod Toxicol., 2004,71:47～53
14. [14]
  [14] Menegola E, Broccia L M, Giavini E. Teratology, 2001,64: 125-133
15. [15]
  [15] Ashok K, Mishra J, Jacob K M. Dyes Pigments, 2007,75: 1-10
16. [16]
  [16] Baqi Y, Weyler S, Muller C E, et al. Purinergic Signalling 2008,48:1120-1130
17. [17]
  [17] Huang F, Wu Y, Gu D, et al. Spectrochim. Acta, Part A, 2005,61:2856-2860
18. [18]
  [18] Gup R, Giziroglu E, Krkan B. Dyes Pigments, 2007,73:40-46
19. [19]
  [19] Erdik E. Organik Kimyada Spektroskopik Yntemler. Ankara, Gazi Kitabevi, 1998:531
20. [20]
  [20] Refat M S, El-Korashy S A, Ahmed A S, et al. Spectrochim. Acta, Part A, 2008,70:898-906
21. [21]
  [21] Gaber M, Mansour I A, El-Sayed Y S Y. Spectrochim. Acta, Part A, 2007,68:305-311
22. [22]
  [22] Wang S, Shen S, Xu H. Dyes Pigments, 2000,44:195-198
23. [23]
  [23] Jaglicic Z, Segedin P, Zlatic J. J. Magn. Magn. Mater., 2007, 310:1444-1446
24. [24]
  [24] Baligar R S, Revankar V K. Transition Met. Chem., 2008, 33:361-366
25. [25]
  [25] Georgousis Z D, Christidis P C, Bolos C A, et al. J. Mol. Struct., 2007,837:30-37
26. [26]
  [26] Ruiz R, Lloret F, Solans X, et al. Inorg. Chim. Acta, 1993, 213～261
1. [1]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
2. [2]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
3. [3]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
4. [4]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
5. [5]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
6. [6]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
7. [7]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
8. [8]
  Shuang Meng , Haixin Long , Zhou Zhou , Meizhu Rong . Inorganic Chemistry Curriculum Design and Implementation of Based on “Stepped-Task Driven + Multi-Dimensional Output” Model: A Case Study on Intermolecular Forces. University Chemistry, 2024, 39(3): 122-131. doi: 10.3866/PKU.DXHX202309008
9. [9]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
10. [10]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
11. [11]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
12. [12]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
13. [13]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
14. [14]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
15. [15]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
16. [16]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
17. [17]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
18. [18]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
19. [19]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
20. [20]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(197)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142