Citation: DONG Li-Na, MA Xue, CHA Yu-e, LI Xia. Synthesis and Crystal Structure of Eu(Ⅲ)/Dy(Ⅲ) Coordination Polymers with Benzimidazole-5,6-dicarboxylate Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 516-522. doi: 10.3969/j.issn.1001-4861.2013.00.029 shu

Synthesis and Crystal Structure of Eu(Ⅲ)/Dy(Ⅲ) Coordination Polymers with Benzimidazole-5,6-dicarboxylate Acid

1.
Departmentment of Chemistry, Capital Normal University, Beijing 100048, China

Received Date: 16 June 2012
Available Online: 15 September 2012
Fund Project: 国家自然科学基金(No．21071101)资助项目。 (No．21071101)

The complexes {[Ln(Hbidc)(bidc)(H₂O)₃]·3H₂O}_n (Ln=Eu 1, Dy 2; H₂bidc=benzimidazole-5,6-dicarboxylic acid)have been obtained by hydrothermal method and characterized by X-ray single-crystal diffraction. The two complexes belong to monoclinic system, P2₁/c space group. Complexes 1 and 2 have similar 1D chain structures. Ln³⁺ ion is nine-coordinated by six oxygen atoms of carboxylate groups and three oxygen atom of water molecules. Ln³⁺ ions are linked by bmdc ligands to form a 1D helical chain. The right- and left-handed chains are further connected to form 3D network via interchain hydrogen bonds and π-π stacking interactions. The two complexes behave characteristic fluorescence of Eu³⁺ and Dy³⁺ ions, respectively. CCDC: 883519, 1; 883518, 2.
- rare earth complex;benzimidazole-5,6-dicarboxylate acid;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142