Advanced Search

Citation: WANG Zi-Qing, LIN Jian-Xin, WANG Rong, WEI Ke-Mei. Ru-Based Catalysts Supported on Perovskite Type BaZrO3 for Ammonia Synthesis[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 493-499. doi: 10.3969/j.issn.1001-4861.2013.00.018 shu

Ru-Based Catalysts Supported on Perovskite Type BaZrO3 for Ammonia Synthesis

  • 1.

    National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, China

  • Received Date: 14 May 2012
    Available Online: 16 July 2012

    Fund Project: 中国石油科技创新基金(No.2010D-5006-0502) (No.2010D-5006-0502)国家科技支撑计划(2007BAE08B02)资助项目。 (2007BAE08B02)

  • The BaZrO3 material was synthesized by the citric acid method. A series of Ru/BaZrO3 catalyst samples were prepared using the above BaZrO3 calcined at different temperatures as the support. The support materials and catalyst samples were characterized by X-ray diffraction (XRD), H2 temperature programmed reduction (H2-TPR), CO2 temperature programmed desorption (CO2-TPD), N2 adsorption-desorption isotherms and scanning electron microscopy (SEM). The results show that the catalytic performance is greatly influenced by the calcination temperature of the BaZrO3 support. The highest catalytic activity for ammonia synthesis is obtained on the Ru-based catalyst with the support calcined at 750 ℃. The ammonia concentration of RBZ-750 can achieve to 9.12% under the condition of 425 ℃, 5 MPa and 10 000 h-1. The strong mental-support interaction and electron conductivity of the support may be the key factors for the high activity at low reaction temperature.
  • 加载中
    1. [1]

      [1] WANG Zi-Qing (王自庆), ZHANG Liu-Ming(张留明), LIN Jian-Xin(林建新), et al. Chin. J. Catal. (Cuihua Xuebao), 2012,33:377-388

    2. [2]

      [2] Zheng X, Zhang S, Xu J, et al. Carbon, 2002,40:2597-2603

    3. [3]

      [3] Li Y, Pan C, Han W, et al. Catal. Today, 2011,174:97-105

    4. [4]

      [4] Liang C, Li Z, Qiu J, et al. J. Catal., 2002,211:278-282

    5. [5]

      [5] WU Shan(吴山), ZHENG Chun-Ming(郑春明), CHEN Ji-Xin (陈继新), et al. Chin. J. Catal. (Cuihua Xuebao), 2004,25: 873-877

    6. [6]

      [6] ZHENG Yong(郑勇), ZHENG Ying(郑瑛), YU Wei-Peng (于伟鹏), et al. Chinese. J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1007-1011

    7. [7]

      [7] HUO Chao(霍超), LIU Hua-Zhang(刘化章), YAN Gang (宴刚) . CN101053835. 2007-05-23

    8. [8]

      [8] LIN Jian-Xin (林建新), ZHANG Liu-Ming (张留明), NI Jun (倪军), et al. Acta Chimica Sinica (Huaxue Xuebao), 2012, 70:137-142

    9. [9]

      [9] Ma G, Matsumoto H, Iwahara H. Solid State Ionics, 1999, 122:237-247

    10. [10]

      [10] Marnellos G, Stoukides M. Seience, 1998,282:98-99

    11. [11]

      [11] MA Gui-Lin(马桂林), QIU Li-Gan (仇立干), CHEN Rong (陈蓉). Acta Chimica Sinica (Huaxue Xuebao), 2002,12: 2135-2140

    12. [12]

      [12] KANG Xin-Hua (康新华), YU Jie (于玠), MA Gui-Lin (马桂林). Chinese. J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22:738-742

    13. [13]

      [13] Yin J, Wang X, Xu J, et al. Solid State Ionics, 2011,185: 6-10

    14. [14]

      [14] Li Z, Liu R, Xie Y, et al. Solid State Ionics, 2005,176:1063-1066

    15. [15]

      [15] SU Xin-Tai (宿新泰), LIU Rui-Quan (刘瑞泉), WANG Ji-De (王吉德). Acta Chimica Sinica (Huaxue Xuebao), 2003, 61:505-509.

    16. [16]

      [16] Yang X L, Zhang W Q, Xia C G, et al. Catal. Commun., 2010,11:867-870

    17. [17]

      [17] Yiokari C G, Pitselis G E, Polydoros D G, et al. J. Phys. Chem. A, 2000,104:10600-10602

    18. [18]

      [18] YANG Xiao-Long(杨晓龙), TANG Li-Ping(唐立平), XIA Chun-Gu(夏春谷). et al. Chin. J. Catal. (Cuihua Xuebao), 2012,33:447-453

    19. [19]

      [19] YANG Xiao-Long(杨晓龙),XIA Chun-Gu(夏春谷),TANG Li-Ping(唐立平), et al. Chinese. J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:1541-1549

    20. [20]

      [20] Yu X, Lin B, Gong B, et al. Catal. Lett., 2008,124:168-173

    21. [21]

      [21] YANG Xiao-Long(杨晓龙), TANG Li-Ping(唐立平), XIA Chung-Gu(夏春谷). et al. J. Molec. Catal. (Fenzhi Cuihua), 2012,26:1-9

    22. [22]

      [22] GAO Wei-Jie(高伟洁), GUO Shu-Jing(郭淑静), ZHANG Hong-Bo(张洪波), et al. Chin. J. Catal.(Cuihua Xuebao), 2011,32:1418-1423

    23. [23]

      [23] Truszkiewicz E, Raróg-Pilecka W, Schmidt-Szaowski K, et al. J. Catal., 2009,265:181-190

    24. [24]

      [24] Zheng Y, Zheng Y, Li Z, et al. J. Molec. Catal. A, 2009, 301:79-83

    25. [25]

      [25] Tanaka H, Misono M. Curr. Opin. Solid. State. Mater. Sci., 2001,5:381-387

    26. [26]

      [26] Kumar S, Teraoka Y, Joshi A G, et al. J. Molec. Catal. A, 2011,348:42-54

    27. [27]

      [27] Seetharamulu P, Hari Prasad Reddy K, Padmasri A H, et al. Catal. Today, 2009,141:94-98

    28. [28]

      [28] HU Quan-Hong(胡全红), LI Xian-Cai(黎先财), YANG Ai-Jun(杨爱军). Nature Gas Chemical Industry(Tianranqi Huagong), 2009,34:1-5

    29. [29]

      [29] Li X C, Wu M, Lai Z H, et al. Appl. Catal. A, 2005,290: 81-86

    30. [30]

      [30] Huo H, Xu Q H, Pan M H, et al. Catal. Lett., 2011,141: 1275-1281

    31. [31]

      [31] Ishikawa H, Kondo J N, Domen K. J. Phys. Chem. B, 1999,103:3229-3234

    32. [32]

      [32] Lin B, Wang R, Lin J, et al. Catal. Commun., 2007,8:1838-1842

    33. [33]

      [33] Lin B, Wang R, Lin J, et al. Catal. Commun., 2011,12:553-558

    34. [34]

      [34] Lin B, Wang R, Lin J, et al. Catal. Commun., 2011,12: 1452-1457

    35. [35]

      [35] Zhang L, Lin J, Ni J, et al. Catal. Commun., 2011,15:23-26

    36. [36]

      [36] LIN Jian-Xin(林建新), ZHANG Liu-Ming(张留明), WANG Rong(王榕), et al. Chinese. J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:1377-1382

    37. [37]

      [37] Izumi Y, Aika K. J. Phys. Chem., 1995,99:10346-10353

    38. [38]

      [38] Izumi Y, Aika K. J. Phys. Chem., 1995,99:10336-10345

    39. [39]

      [39] Iwamoto J, Itoh M, Kajita Y, et al. Catal. Commun., 2007,8: 941-944

    40. [40]

      [40] Tauster S J, Fung S C, Baker R T K. et al. Science, 1981,211:1121-1125

    41. [41]

      [41] Guo S J, Pan X L, Gao H L, et al. Chem. Eur. J., 2010,16: 5379-5384

    42. [42]

      [42] Izumi Y, IwataY, Aika K. J. Phys. Chem., 1996,100:9421-9428

    43. [43]

      [43] Yue C Y, Trudeau M, Antonelli D. Chem. Commun., 2006,18:1918-1920

  • 加载中
    1. [1]

      Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

    2. [2]

      Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004

    3. [3]

      Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two SmⅢ4 complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258

    4. [4]

      Jiaxun Wu ,  Mingde Li ,  Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098

    5. [5]

      Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360

    6. [6]

      Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO2 Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046

    7. [7]

      Jia Wang , Qing Qin , Zhe Wang , Xuhao Zhao , Yunfei Chen , Liqiang Hou , Shangguo Liu , Xien Liu . P-Doped Carbon-Supported ZnxPyOz for Efficient Ammonia Electrosynthesis under Ambient Conditions. Acta Physico-Chimica Sinica, 2024, 40(3): 2304044-0. doi: 10.3866/PKU.WHXB202304044

    8. [8]

      Huiying Xu ,  Minghui Liang ,  Zhi Zhou ,  Hui Gao ,  Wei Yi . Application of Quantum Chemistry Computation and Visual Analysis in Teaching of Weak Interactions. University Chemistry, 2025, 40(3): 199-205. doi: 10.12461/PKU.DXHX202407011

    9. [9]

      Jinghua Wang ,  Yanxin Yu ,  Yanbiao Ren ,  Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057

    10. [10]

      Fa Wang ,  Yu Chen ,  Hui Chao . Ruthenium(II) Complexes as Photoactivated Chemo-Prodrugs for Hypoxic Tumor Therapy. University Chemistry, 2025, 40(7): 200-212. doi: 10.12461/PKU.DXHX202410024

    11. [11]

      Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382

    12. [12]

      Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265

    13. [13]

      Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398

    14. [14]

      Qingying Gao ,  Tao Luo ,  Jianyuan Su ,  Chaofan Yu ,  Jiazhu Li ,  Bingfei Yan ,  Wenzuo Li ,  Zhen Zhang ,  Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074

    15. [15]

      Jiapei Zou ,  Junyang Zhang ,  Xuming Wu ,  Cong Wei ,  Simin Fang ,  Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081

    16. [16]

      Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161

    17. [17]

      Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291

    18. [18]

      Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . Atomically Precise (AgPd)27 Nanoclusters for Nitrate Electroreduction to NH3: Modulating the Metal Core by a Ligand Induced Strategy. Acta Physico-Chimica Sinica, 2025, 41(1): 100008-0. doi: 10.3866/PKU.WHXB202403008

    19. [19]

      Ping Song ,  Nan Zhang ,  Jie Wang ,  Rui Yan ,  Zhiqiang Wang ,  Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087

    20. [20]

      Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080

Get Citation
PDF
XML
Metrics
  • PDF Downloads(544)
  • Abstract views(756)
  • HTML views(23)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return