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Citation: YAO Yuanyong, WU Lanyan, SHU Hua, TANG Bangcheng, XUE Wei. Synthesis of α-Aminophosphonates by Brønsted Acid Catalysis[J]. Chinese Journal of Applied Chemistry, ;2014, 31(12): 1428-1433. doi: 10.3724/SP.J.1095.2014.40052 shu

Synthesis of α-Aminophosphonates by Brønsted Acid Catalysis

YAO Yuanyong ^a,b ,
WU Lanyan ^a ,
SHU Hua ^a ,
TANG Bangcheng ^a,, ,
XUE Wei ^b,,

1.
a Department of Biological and Chemical Engineering, Fanjing Mountain Key Laboratory of Special Animal and Plant Resource, Tongren University, Tongren 554300, China;
2.
b Center for Research & Development of Fine Chemicals, Guizhou University, Guiyang 550025, China

Corresponding author: TANG Bangcheng, XUE Wei,
Received Date: 25 February 2014
Available Online: 23 June 2014
Fund Project: 贵州省教育厅"125"重大科技专项([2012]018) ([2012]018)

Electrophilic aromatic imines synthesized by the condensation of aromatic amines with cinnamyl aldehyde were allowed to react with diethyl phosphite or triethyl phosphite as nucleophile in the presence of 10% molar fraction of phosphoric acid(Brønsted acid).The α-aminophosphonate derivatives were obtained through binary or single hydrogen bonding interaction of catalyst with nucleophiles and electrophiles in up to 79%~85% yields.
- Brønsted acid,
- α-aminophosphonate,
- hydrogen bonding interaction,
- catalysis,
- hydrophosphonylation
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