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Citation: SUN Yinghua, YANG Meiling, GUO Qingfang, CHEN Di, JIANG Xiaoyu. Synthesis,Structure Characterization and Magnetic Property of a New Molybdenum-vanadium Polyoxometalate[J]. Chinese Journal of Applied Chemistry, ;2014, 31(10): 1210-1215. doi: 10.3724/SP.J.1095.2014.30648 shu

Synthesis,Structure Characterization and Magnetic Property of a New Molybdenum-vanadium Polyoxometalate

1.
a Department of Chemistry, Baicheng Normal College, Baicheng 137000, China;
2.
b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China;
3.
c Group of Chemistry, Baicheng Second Middle School, Baicheng 137000, China

Corresponding author: SUN Yinghua,
Received Date: 20 December 2013
Available Online: 21 February 2014
Fund Project: 吉林大学无机合成与制备化学国家重点实验室资助项目(2011-4) (2011-4)吉林省教育厅十二五科学技术研究项目(2013-389) (2013-389)

A new molybdenum-vanadium polyoxometalate[P^ⅤMo₇^ⅥMo^ⅤV₈^ⅣO₄₄][Ni(Phen)₂OH]₄·3H₂O(1) was prepared under hydrothermal conditions, and characterized by elemental analysis, IR and single crystal X-ray diffraction analysis. The title compound crystallized in a triclinic system, P-1 space group, a=1.51300(11) nm, b=1.74813(15) nm, c=2.58896(18) nm, α=72.842(4)°, β=89.240(5)°, γ=72.627(5)°, V=6.2233(8) nm³, Z=1, R₁=0.0962, wR₂=0.2572. Compound 1 is composed of a highly reduced tetra-capped pseudo-Keggin polyoxoanion supporting four transition metal complexes. There are many hydrogen bond among polyoxoanion and water molecules, which enable the formation of three dimensional supramolecular array.
- molybvanudates,
- supramolecular,
- hydrothermal synthesis,
- magnetic properties
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