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Citation: XIE Mingyu, LI Ruofei, JIA Xue, TIAN Lili, XIA Xiannian. Synthesis of Bisphenol F Catalyzed by Aluminum-grafted MCM-41 Mesoporous Molecular Sieve[J]. Chinese Journal of Applied Chemistry, ;2014, 31(2): 153-158. doi: 10.3724/SP.J.1095.2014.30235 shu

Synthesis of Bisphenol F Catalyzed by Aluminum-grafted MCM-41 Mesoporous Molecular Sieve

1.
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

Corresponding author: XIA Xiannian,
Received Date: 13 May 2013
Available Online: 20 June 2013
Fund Project: 化石能源低碳化清洁利用-教育部创新团队(湖南大学)支助计划(IRT1238) (湖南大学)支助计划(IRT1238)湖南大学理科化学基地-科研训练及科研能力提高项目(J1210040) (J1210040)湖南省科技厅项目(2011WK3010) (2011WK3010)

Cetyltrimethylammonium bromide(CTAB) and tetraethylorthosilicate(TEOS) were selected as raw materials for the synthesis of pure silicon MCM-41.Using Al(NO₃)₃·9H₂O as aluminum source to modify pure silicon MCM-41 by grafting method.The AlMCM-41 was characterized by NH₃-TPD.The results show that AlMCM-41 produced mild acid after grafting.The synthesis of bisphenol F was catalyzed by AlMCM-41 with different silicon/aluminium.The optimized reaction conditions are:n(phenol)/n(formaldehyde)=30,reaction time of 5 h,reaction temperature of 90℃,m(formaldehyde)/m(AlMCM-41)=7.In a certain range,the yield of bisphenol F increases with the increase of Al.When the n(Si)/n(Al) is less than 50,the yield of bisphenol F tends to decrease.While n(Si)/n(Al)=50,the yield of bisphenol F can reach its highest value of 42.28%.
- aluminum nitrate,
- grafting,
- bisphenol F,
- MCM-41 molecular sieve
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