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Citation: WANG Jianhui, GUO Liqin, RUAN Wenjuan, ZHU Zhiang. Synthesis and Electrochemical Properties of Salen-type Copper(Ⅱ) and Nickel(Ⅱ) Complexes[J]. Chinese Journal of Applied Chemistry, ;2014, 31(3): 303-309. doi: 10.3724/SP.J.1095.2014.30166 shu

Synthesis and Electrochemical Properties of Salen-type Copper(Ⅱ) and Nickel(Ⅱ) Complexes

1.
College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: RUAN Wenjuan,
Received Date: 7 April 2013
Available Online: 14 May 2013
Fund Project: 国家自然科学基金(20671053)资助项目 (20671053)

Two salen-type ligands and their metal complexes(ML¹ and ML²,M=Cu or Ni,L¹=N,N'-bis(4-hydroxysalicylidene)-2,2'-biphenyldiamine,L²=N,N'-bis(3,5-di-tert-butyl-salicylidene)-2,2'-biphenyldiamine) with tetradentate N2O2 coordinate mode were synthesized.These complexes were characterized with ¹H-nuclear magnetic resonance(¹H NMR),ultraviolet-visible absorption spectroscopy(UV-Vis),Fourier transform infrared spectroscopy(FT-IR),mass spectrometry(MS),and elemental analyses.The electrochemical properties of the synthesized complexes were also studied by cyclic voltammetry(CV).The CV curves of CuL² and NiL¹ only contained a one-electron quasi-reversible redox peak in the range of -1.5~+1.5 V.In contrast,two redox peaks were observed in the CV curve of NiL².
- salen-type ligand,
- copper(Ⅱ) and nickel(Ⅱ) complexes,
- synthesis and characterization,
- cyclic voltammetry,
- electrochemical property
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