Home

Citation: HUANG Man, LI Meirong, TIAN lanlan, HUANG Yin, MA Baodong, LIU Kun. Effect of Ferrous Ion on Reducing the Viscosity of Oil Flooding Polymer Solution and Its Mechanism[J]. Chinese Journal of Applied Chemistry, ;2013, 30(12): 1399-1403. doi: 10.3724/SP.J.1095.2013.30169 shu

Effect of Ferrous Ion on Reducing the Viscosity of Oil Flooding Polymer Solution and Its Mechanism

HUANG Man ^a, ,
LI Meirong ^a ,
TIAN lanlan ^a ,
HUANG Yin ^a ,
MA Baodong ^b ,
LIU Kun ^b

a. College of Science, China University of Petroleum, Qingdao 266580, China;
b. Geological Scientific Research Institute Shengli Oilfield, SINOPEC, Dongying 257015, China

Received Date: 9 April 2013
Revised Date: 30 May 2013

The viscosity of prepared polymer solution was increased by the precipitation of Fe²⁺ with NaOH from the sewage of the T28 district,Shengtuo oilfiled. The mechanism of reduced viscosity introduced by Fe²⁺ was studied by IR,fluorescence spectroscopy and SEM. The viscosity of polymer solution was elevated from 19.17 mPa·s to 92.50 mPa·s when treating the sewage containing 5.9 mg/L of Fe²⁺ with NaOH at pH 9. Fe²⁺ was found to split the polymer chain,weaken the association,destroy the spatial network structure of macromolecules,and lead to decreasing viscosity of the polymer solution. The precipitation of ferrous hydroxides from the polymer solution promotes the formation of compact spatial network structure of the polymer chains.
- polymer,
- ferrous ion,
- viscosity,
- mechanism
1. [1]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
2. [2]
  Shu'e Song , Xiaokui Wang , Yongmei Liu , Wanchun Zhu , Hong Yuan , Fuping Tian , Yunshan Bai , Yunchao Li , Li Wang , Zhongyun Wu , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Viscosity, Density and Optical Properties. University Chemistry, 2025, 40(5): 148-156. doi: 10.12461/PKU.DXHX202503026
3. [3]
  Chengyi Xiao , Xiaoli Sun , Chen Zhang , Weiwei Li . An In-Depth Analysis of the Scientific Connotations, Testing Methods, and Applications of Free Volume in Polymer Physics. University Chemistry, 2025, 40(4): 33-45. doi: 10.12461/PKU.DXHX202403069
4. [4]
  Jiahong WANG , Zekun XU , Tianjiao LU , Jinming HUANG . Performance of N, Mn doped semi-coke activated carbon catalyzed ozone oxidation for the degradation of tetracycline hydrochloride in water. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2549-2560. doi: 10.11862/CJIC.20250120
5. [5]
  Xiaoyi Sun , Duohang Bi , Hankun Qiao , Yijing Liu , Jintao Zhu . Painless Injection: Microneedles Revolutionizing Beauty and Health Brought. University Chemistry, 2025, 40(10): 166-174. doi: 10.12461/PKU.DXHX202411006
6. [6]
  Zhen FAN , Jiayan WANG , Wenhao ZHU , Xiuchun ZHANG , Yang WANG , Hao LI , Zeyuan WANG , Songzhi ZHENG , Weihai SUN . Fabrication of CsPbBr₃ perovskite solar cells using buried polyvinylidene fluorideinterface modification method. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2464-2478. doi: 10.11862/CJIC.20250191
7. [7]
  Wenjun Zhu , Chenbin Ai , Kaiqiang Xu , Yatai Zhou , Xidong Zhang , Yong Zhang . WO₃@TP inorganic@organic S-scheme photocatalyst for boosting H₂O₂ production. Acta Physico-Chimica Sinica, 2026, 42(3): 100184-0. doi: 10.1016/j.actphy.2025.100184
8. [8]
  Chunyuan Kang , Xiaoyu Li , Fan Yang , Bai Yang . Ionic-bond crosslinked carbonized polymer dots for tunable and enhanced room temperature phosphorescence. Acta Physico-Chimica Sinica, 2026, 42(1): 100156-0. doi: 10.1016/j.actphy.2025.100156
9. [9]
  Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125
10. [10]
  Yao Xie , Shuangjun Li , Chao Chen , Siyu Fan , Ying Tao , Qitao Zhang . Ionic polarization engineering of polymeric carbon nitride toward efficient H₂O₂ photosynthesis. Acta Physico-Chimica Sinica, 2026, 42(5): 100183-0. doi: 10.1016/j.actphy.2025.100183
11. [11]
  Yuxia Luo , Xiaoyu Xie , Fangfang Chen . 药物递送魔法师——分子印迹聚合物. University Chemistry, 2025, 40(8): 202-210. doi: 10.12461/PKU.DXHX202409129
12. [12]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
13. [13]
  Kaimin WANG , Na HE , Shiyi LI , Xuling BAI , Weiqing SUN , Yanqing YE , Yulu MA . Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 55-64. doi: 10.11862/CJIC.20250178
14. [14]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
15. [15]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
16. [16]
  Xuefei Leng , Yanshai Wang , Hai Wang , Shengyang Tao . The In-Depth integration of “Industry-University-Research” in the Exploration and Practice of “Comprehensive Training in Polymer Engineering”. University Chemistry, 2025, 40(4): 66-71. doi: 10.12461/PKU.DXHX202405105
17. [17]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
18. [18]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
19. [19]
  Minghui Wu , Markus Mühlinghaus , Xuechao Li , Chaojie Xu , Qiang Chen , Haiming Zhang , Klaus Müllen , Lifeng Chi . On-Surface Synthesis of Chevron-Shaped Conjugated Ladder Polymers Consisting of Benzo[a]azulene Units. Acta Physico-Chimica Sinica, 2024, 40(8): 2307024-0. doi: 10.3866/PKU.WHXB202307024
20. [20]
  Heng Zhang , Ying Ma , Shiling Yuan . Machine Learning-based Prediction of Antifouling Performance in Polymer Materials: An Integrated Molecular Simulation Experiment. University Chemistry, 2026, 41(1): 346-353. doi: 10.12461/PKU.DXHX202506015

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(695)
HTML views(70)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return