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Citation: LI Guanjun, JIA Chunmei, YUAN Wenbing. Mechanochemical Reactions Between Nicotinic Acid and Zinc Oxide,or Basic Zinc Carbonate[J]. Chinese Journal of Applied Chemistry, ;2013, 30(11): 1372-1374. doi: 10.3724/SP.J.1095.2013.20597 shu

Mechanochemical Reactions Between Nicotinic Acid and Zinc Oxide,or Basic Zinc Carbonate

Key Laboratory of Tropical Biological Resources of Ministry Education, School of Materials and Chemical Engineering, Hainan University, Haikou 570228, China

Received Date: 21 December 2012
Revised Date: 15 March 2013

In a planetary or a shaking ball milling machine,when H₂O (50 μL) or DMF (50 μL) or methanol (150 μL) were added as assisting liquids in ball milling processes,the mechanochemical reactions between nicotinic acid and zinc oxide or basic zinc carbonate have been studied.The results show that ball milling the starting materials in the presence of H₂O or DMF in the planetary (at 45 Hz) or shaking (at 20 Hz) ball milling machine,a zero-dimensional coordination compound,[Zn(NA)₂(H₂O)₄] could be obtained after 30 min reactions. With the absence of DMF and methanol,the target compound could not be synthesized in a planetary ball milling process at lower frequency of 15 Hz. However,the similar reaction could be initiated once prolonging the reaction time to 60 min under similar conditions.
- mechanochemistry,
- ball milling,
- coordination compounds,
- nicotinic acid
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