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Citation: LI Junfen, LI Jinzeng, ZHANG Caihong, HAN Yuying, QIN Xi, DONG Chuan. Synthesis and Luminescence Behavior of a Novel Charge Transfer Compound Containing Carbazole Phenylhydrazone[J]. Chinese Journal of Applied Chemistry, ;2013, 30(10): 1139-1143. doi: 10.3724/SP.J.1095.2013.20571 shu

Synthesis and Luminescence Behavior of a Novel Charge Transfer Compound Containing Carbazole Phenylhydrazone

LI Junfen ^a, ,
LI Jinzeng ^a ,
ZHANG Caihong ^a ,
HAN Yuying ^a ,
QIN Xi ^a ,
DONG Chuan ^b

a. School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China;
b. Research Center of Environmental Science and Engineering, Shanxi University, Taiyuan 030006, China

Received Date: 10 December 2012
Revised Date: 22 January 2013

A novel compound,containing a strong electron donor and a strong electron acceptor,3-((2-(2,4-dinitrophenyl) hydrazono) methyl)-9-ethyl-9H-carbazole,was synthesized. Its spectral property and photophysical behavior were studied. Intermolecular charge transfer occurred from N-ethylcarbazole to NO₂-with the increase of the solvent polarity. Double fluorescence emission was observed in strong polarity solvent. Change of dipole moment between the ground state and the excitation state was 4.53 D. Dimmer or polymer was formed at high concentration and the emission wavelength was red shifted.
- carbazole hydrazone compounds,
- intramolecular charge transfer,
- solvent polarity
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