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Citation: ZHAO Yisha, HUANG Jie, SONG Jirong, HE Jianyun, MA Cong, XU Kangzhen. Preparation and Crystal Structure of a New Cu(Ⅱ) Complex Derived from the Desulfurization of N-(2,4-Dichlorophenyl)-N'-(benzoyl)-thiourea[J]. Chinese Journal of Applied Chemistry, ;2013, 30(8): 897-902. doi: 10.3724/SP.J.1095.2013.20456 shu

Preparation and Crystal Structure of a New Cu(Ⅱ) Complex Derived from the Desulfurization of N-(2,4-Dichlorophenyl)-N'-(benzoyl)-thiourea

ZHAO Yisha ^a, ,
HUANG Jie ^a ,
SONG Jirong ^a,b ,
HE Jianyun ^a ,
MA Cong ^a ,
XU Kangzhen ^a

1.
a. Department of Chemical Engineering/Shanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an 710069, China;
b. Conservation Technology Department, Palace Museum, Beijing 100009, China

Received Date: 12 October 2012
Revised Date: 21 January 2013

In CH₃OH the reaction of CuCl₂ with N-(2,4-dichlorophenyl)-N'-(benzoyl)-thiourea gave a new copper(Ⅱ) complex,CuL₂(HL=N-benzoyl-N'-(2,4-dichlorophenyl)-O-methyl-isourea),which was derived from the desulfurated hydrogen of N-(2,4-dichlorophenyl)-N'-(benzoyl)-thiourea(H₂met). Single crystal was obtained by slowly evaporating solvent at the room temperature,and the molecule structure was determined with X-ray diffractions. The copper(Ⅱ) ion is coordinated by two N atoms and two carbonyl O atoms of two ligand molecules and forms a complex with two six-membered chelate rings[N(1A)-Cu-N(1)=180.0°,O(1A)-Cu(1)-O(1)=180.0°].
- N-(dichlorophenyl)-N'-(benzoyl)-thiourea,
- Cu(Ⅱ) complex,
- crystal structure
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