Citation:
CAO Weili, YANG Fengke. Epoxidation Technology of Safflower Seed Oil[J]. Chinese Journal of Applied Chemistry,
;2013, 30(6): 638-642.
doi:
10.3724/SP.J.1095.2013.20331
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Epoxidized safflower seed oil was prepared using hydrogen peroxide as oxidant,formic acid as oxygen carrier,and strong acidic cation exchange resin as catalyst. The optimized reaction conditions are:with the presence of ethylene diamine tetraacetic acid as stabilizer,the precursor ratio for m(safflower seed oil):m(88% formic acid):m(H2O230%):m(cation exchange resin) is 1:0.244:1.665:0.035,the reaction temperature is 60℃,the reaction time is 6 h and the stirring rate is 400 r/min,the epoxy value is above 7.0.
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