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Citation: WANG Wenge, ZHANG Dechun, XIE Heping, HE Xiaomei. Synthesis and Extraction Properties Toward Metal Cations of 4,6-Dialkoxy-benzene-1,3-disulfonic Acid Bis-dimethylamide[J]. Chinese Journal of Applied Chemistry, ;2013, 30(4): 427-430. doi: 10.3724/SP.J.1095.2013.20265 shu

Synthesis and Extraction Properties Toward Metal Cations of 4,6-Dialkoxy-benzene-1,3-disulfonic Acid Bis-dimethylamide

Department of Materials & Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Received Date: 14 June 2012
Revised Date: 8 October 2012

N,N-disubstituted sulfonamide between sulfonyl chlorides and tertiary amines was discovered.Four aromatic sulfonamides were synthesized in dichloromethane or acetone by using 4,6-dialkoxy-benzene-1,3-disulfonyl dichlorides and 2,4,6-tris(dimethylaminomethyl)phenol as the starting materials.The purified products were characterized by IR,¹H NMR,elemental analysis and MS.Aromatic sulfonamides were then applied as the extraction reagents for Ca²⁺,Pb²⁺ and some transition metal cations.The primary results showed that the aromatic sulfonamides have better extraction capability for Ca²⁺.
- synthesis,
- selective extraction,
- dialkoxybenzene disulfonic acid bis-dialkylamide,
- sulfonamide
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