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Citation: WAN Lijuan, XING Na, WAN Liying, ZHANG Caishun, SHAN Hui, XING Yongheng, BAI Fengying. Synthesis, Structure and Properties of the Cadmium Complex Using Bisphenyl-pyrazolyl-pyridine Derivative and Oxalate as Mixed Ligands[J]. Chinese Journal of Applied Chemistry, ;2012, 29(11): 1266-1271. doi: 10.3724/SP.J.1095.2012.00558 shu

Synthesis, Structure and Properties of the Cadmium Complex Using Bisphenyl-pyrazolyl-pyridine Derivative and Oxalate as Mixed Ligands

WAN Lijuan ^a ,
XING Na ^a ,
WAN Liying ^b ,
ZHANG Caishun ^a ,
SHAN Hui ^a ,
XING Yongheng ^a,, ,
BAI Fengying ^c,,

1.
a College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China;
2.
b School of Software, Dalian University of Foreign Languages, Dalian 116044, China;
3.
c School of Life Science, Liaoning Normal University, Dalian 116029, China

Corresponding author: XING Yongheng, BAI Fengying,
Received Date: 16 December 2011
Available Online: 19 March 2012
Fund Project: 国家自然科学基金资助项目(21071071) (21071071)辽宁省科技厅博士科研启动基金资助项目(20111067) (20111067)

[Cd₂(HL)₂(ox)]·1.5H₂O was synthesized hydrothermally from Cd(NO₃)₂·4H₂O,pyrazolyl derivative(H₂L=2,6-di-(5-phenyl-1H-pyrazol-3-yl)pyridine) and oxalate(H₂ox=oxalic acid).Structural analysis revealed that the complex crystallized in the triclinic system with P-1 space group.The Cd took a distorted octahedral geometry and was coordinated by two oxygen atoms from one ox ligand and four N atoms from two HL^- ligands.Adjacent Cd atoms(Cd1/Cd₂) were connected through bridging ox ligand and N atoms from HL^- to generate two separate 1D chains structure.The complex was further characterized by elemental analysis,IR,UV-Vis spectroscopy and powder X-ray diffraction(PXRD).In addition,the complex displayed ideal thermal stability and photoluminescent properties,and exhibited some catalytic activity toward the oxidation of cyclohexane.
- bisphenyl-pyrazolyl-pyridine-oxalate cadmium complex,
- crystal structure,
- fluorescence and catalytic property
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