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Citation: FENG Fu, CUI Zhicai, DUAN Zhengchao, HU Weibing. Synthesis of 1, 1-Bibenzyl-1, 1-bimercaptoacetyl-hydrazonemethane under Microwave Irradiation[J]. Chinese Journal of Applied Chemistry, ;2012, 29(11): 1251-1255. doi: 10.3724/SP.J.1095.2012.00547 shu

Synthesis of 1, 1-Bibenzyl-1, 1-bimercaptoacetyl-hydrazonemethane under Microwave Irradiation

1.
School of Chemistry and Environmental Engineering, Hubei Institute for Nationalities, Enshi 445000, China

Corresponding author: HU Weibing,
Received Date: 8 December 2011
Available Online: 13 January 2012
Fund Project: 教育部重点项目(211111) (211111)湖北省教育厅中青年项目(Q2011902)资助 (Q2011902)

Using 1,3-diphenylacetone as precursor,bibenzyldithiolmethane(1) was prepared through reacting 1,3-diphenylacetone with dry hydrogen sulfide and hydrogen chloride.Under microwave irradiation,compound 1 was subjected to esterification and hydrazinolysis to yield 1,1-bibenzyl-1,1-bimercaptoacetyl-hydrazine(3).The condensation reactions between compound 3 and aromatic aldehyde led to the production of a series of 1,1-bibenzyl-1,1-bimercaptoacetylhydrazone(4a~4n).Their structures were confirmed by IR,¹H NMR,MS and elemental analysis.
- microwave irradiation,
- acetylhydrazone,
- synthesis
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