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Citation: LIU Changhui, WEN Ruiming, YE Xiaoqin, YI Xianwen, FANG Lei. Synthesis and Characterization of Ionone-containing Chalcones[J]. Chinese Journal of Applied Chemistry, ;2012, 29(7): 780-783. doi: 10.3724/SP.J.1095.2012.00336 shu

Synthesis and Characterization of Ionone-containing Chalcones

1.
Department of Chemistry and Environmental Engineering, Hunan City University, Yiyang 413000, China

Corresponding author: WEN Ruiming,
Received Date: 28 July 2011
Available Online: 2 September 2011
Fund Project: 国家自然科学基金资助项目(51074069) (51074069)湖南省科技计划项目(2010GK3161) (2010GK3161)益阳市科技计划项目(2011JZ36) (2011JZ36)

Condensation of β-ionone and 5,6-epoxyl-β-ionone with aromatic aldehydes by sodium carbonate and sodium hydroxide was carried out to afford eight novel ionone-containing chalcones at room temperature for 1~15 min by grinding,and their structures were characterized by ¹H NMR,MS,IR and elemental analysis.The effects of substituents,the types and amounts of catalysts on the reaction were studied.The results show that the yield is 87.1%~94.8% when the molar ratio of β-ionone,benzalaldehyde,sodium carbonate and sodium hydroxide is 20: 20: 5: 15,and electron withdrawing group promotes the condensation.
- chalcone,
- β-ionone,
- epoxyl-β-ionone,
- condensation,
- synthesis
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