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Citation: HU Jing, LIU Yanqin, HAN Shitian. Syntheses of Meso-tetra[4-(5-fluorouracil-1-yl acetoxyl) phenyl]porphyrin and Its Zn Complex[J]. Chinese Journal of Applied Chemistry, ;2012, 29(5): 608-610. doi: 10.3724/SP.J.1095.2012.00298 shu

Syntheses of Meso-tetra[4-(5-fluorouracil-1-yl acetoxyl) phenyl]porphyrin and Its Zn Complex

1.
College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, China

Corresponding author: LIU Yanqin,
Received Date: 11 July 2011
Available Online: 5 September 2011
Fund Project: 河北省自然科学基金资助项目(203147) (203147)

A new meso-tetra[4-(5-fluorouracil-1-yl acetoxyl)phenyl]porphyrin compound(A) was synthesized from meso-tetra(4-hydroxyphenyl) porphyrin with 5-fluorouracil-1-yl acetic acid by using N,N'-dicyclohexylcarbdiimide as dehydration agent with a yield of 12.7%.The zinc complex(B) of the compound was prepared by the reaction of porphyrin(A) with Zn(OAc)₂ with a yield of 30.8%.The structures of the products were characterized by UV-Vis,IR,¹H NMR,MS and elemental analysis.
- porphyrin,
- zinc porphyrin,
- fluorouracil,
- synthesis
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