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Citation: WU Jinming, TANG Yanfeng, SHEN Aibao. Synthesis of 5-Nitrosalicylaldehyde Catalyzed by H₆PMo₉V₃O₄₀ Supported on Silica Gel[J]. Chinese Journal of Applied Chemistry, ;2012, 29(5): 545-550. doi: 10.3724/SP.J.1095.2012.00263 shu

Synthesis of 5-Nitrosalicylaldehyde Catalyzed by H₆PMo₉V₃O₄₀ Supported on Silica Gel

1.
School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019

Corresponding author: SHEN Aibao,
Received Date: 20 June 2011
Available Online: 24 August 2011
Fund Project: 国家自然科学基金(21006054) (21006054)南通市科技计划(K2010021) (K2010021)南通大学自然科学基金(10Z013)资助项目 (10Z013)

5-Nitrosalicylaldehyde was synthesized by the nitration of salicylaldehyde with nitric acid over H₆PMo₉V₃O₄₀ supported on silica gel.The effects of parameters were investigated,such as H₆PMo₉V₃O₄₀ loading,reaction time,temperature,solvent,and so on.Under the optimal conditions:m(salicylaldehyde):m(65%HNO₃):m(20% H₆PMo₉V₃O₄₀/SiO₂)=2.44:3.00:3.00,in petroleum ether at 45℃ for 2.5 h,the conversion of salicylaldehyde was 98%,the selectivity of 5-nitrosalicylaldehyde was up to 96.8%.The catalyst could be recovered easily and reused for five times without noticeable drop in activity.
- nitrosalicylaldehyde,
- H₆PMo₉V₃O₄₀ supported on silica gel,
- nitration,
- salicylaldehyde
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Synthesis of 5-Nitrosalicylaldehyde Catalyzed by H₆PMo₉V₃O₄₀ Supported on Silica Gel